Registration Dossier
Registration Dossier
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EC number: 294-470-6 | CAS number: 91722-69-9 Extractives and their physically modified derivatives such as tinctures, concretes, absolutes, essential oils, oleoresins, terpenes, terpene-free fractions, distillates, residues, etc., obtained from Lavandula hybrida, Labiatae.
Flash point
Administrative data
Link to relevant study record(s)
- Endpoint:
- flash point of flammable liquids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- March-April 2016
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
- Justification for type of information:
- The study was conducted according to an internationally recognised method, and under GLP. The substance is considered to be adequately characterised. Therefore full validation applies.
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.9 (Flash-Point)
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- EPA OPPTS 830.6315 (Flammability)
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- ISO 2719 (Determination of flash point - Pensky-Martens closed cup method)
- Deviations:
- no
- Principles of method if other than guideline:
- Not applicable
- GLP compliance:
- yes (incl. QA statement)
- Remarks:
- inspected on October 13 and 14, 2014 / signed on April 08, 2015
- Type of method:
- non-equilibrium method closed cup
- Flash point apparatus:
- Pensky-Martens apparatus
- Key result
- Flash point:
- ca. 80 °C
- Atm. press.:
- ca. 101 325 Pa
- Interpretation of results:
- Category 4 (combustible liquids) based on GHS criteria
- Conclusions:
- The flash point of the test item has been determined to be 80.0°C (353.2 K).
- Executive summary:
The flash point of the test substance was determined under GLP according toEU Method A.9 (Flash-Point), using a non-equilibrium closed cup method (ISO2719 -Part B). The flash point of the test item has been determined to be 80.0°C (353.2 K), which is the mean value of two independent valid determinations.
The flash point of test substance is above the classification thresholds of 60°C of the Regulation (EC) No. 1272/2008 (CLP criteria) and lower than 93°C, the threshold of the UN Globally Harmonised System (GHS).
Therefore the test substance is NOT classified as a flammable liquid according to CLP criteria but is classified as a Flammable Liquid Category 4 according to UN Globally Harmonised System (GHS).
Reference
Findings
Pre-Test for Safety
A bubble chain was observed at 150 °C and the chain broke at 140 °C. The tinge of yellow was more intense after cooling down. No signs of polymerization were visible.
Determination of the Flash Point
The results of the determinations are presented in the following tables.
Table 4.11 -2 Findings
Program |
Heating rate (°C/min) |
Expected flash point (setting) in °C |
Flash point (found) |
Notes |
Search |
8.5 |
140 |
Up to 120.9°Cno flash point detected but a small flame at the lid of vessel was observed |
The plash point tester was stopped |
Search |
8.5 |
140 |
80.6 |
not used for calculation(pre-test) |
EN ISO 2719-B |
1.3 |
80 |
No flash point found up to100°C |
Stop overflow Relative |
EN ISO 2719-B |
1.3 |
80 |
80.0 |
FP ok |
EN ISO 2719-B |
1.3 |
80 |
No flash point found up to100°C |
Stop overflow Relative |
EN ISO 2719-B |
1.3 |
90 |
No flash point found up to110°C |
Stop overflow Relative |
Evaluation and Result
For safety reasons, the lowest value of the quadruplicate determination is given as the flash point. The measured flash point is therefore 80.0°C (corresponding to 353.2 K).
Discussion
The determinations in the main test gave only one value with 80.0 °C. This is attributed to the test item’s properties as a UVCB. Possibly, vaporisation of the single components is poorly detectable, and therefore, just one value for the flash point is measured in the main test but it was similar to the value in the pre-test (80.6°C).
For safety reasons, the lowest measured value (80.0 °C = 353.2 K) is stated as the flash point of the test item.
The determination was considered valid.
Description of key information
The substance is NOT classified as a flammable liquid according to Regulation (EC) N°1272/2008 (CLP criteria).
The substance is classified as Flammable Liquid Category 4 according to UN Globally Harmonized System (GHS criteria).
Key value for chemical safety assessment
- Flash point at 101 325 Pa:
- 80 °C
Additional information
The flash point of the test substance was determined under GLP according to EU Method A.9 (Flash-Point), using a non-equilibrium closed cup method
(ISO2719 -Part B).
It is considered as a key study. The result is retained as key data for purpose of CSA.
This study is relevant for the classification regarding flammable properties.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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