Registration Dossier
Registration Dossier
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EC number: 266-737-7 | CAS number: 67584-59-2
Guidance on Safe Use
Administrative data
First-aid measures
Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.
Skin Contact:
Immediately wash with soap and water. Remove contaminated clothing and wash before reuse. If signs/symptoms develop, get medical attention.
Eye Contact:
No need for first aid is anticipated.
If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.
Most important symptoms and effects, both acute and delayed
See SDS Section 11.1. Information on toxicological effects.
Indication of any immediate medical attention and special treatment required
Not applicable.
Fire-fighting measures
Extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.
Special hazards arising from the substance or mixture
Exposure to extreme heat can give rise to thermal decomposition.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Fluoride During Combustion
Oxides of Nitrogen During Combustion
Oxides of Sulfur During Combustion
Advice for fire-fighters
Wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Refer to other sections of this SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.
Environmental precautions
Avoid release to the environment. For larger spills, cover drains and build dikes to prevent entry into sewer systems or bodies of water.
Methods and material for containment and cleaning up
Contain spill. Working from around the edges of the spill inward, cover with bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry. Remember, adding an absorbent material does not remove a physical, health, or environmental hazard. Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue with an appropriate solvent selected by a qualified and authorized person. Ventilate the area with fresh air. Read and follow safety precautions on the solvent label and SDS. Seal the container. Dispose of collected material as soon as possible in accordance with applicable local/regional/national/international regulations.
Reference to SDS sections
Refer to SDS Section 8 and Section 13 for more information
Handling and storage
Precautions for safe handling
Do not breathe thermal decomposition products. Avoid breathing dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Contaminated work clothing should not be allowed out of the workplace. Avoid release to the environment. Wash contaminated clothing before reuse. Avoid contact with oxidizing agents (eg. chlorine, chromic acid etc.)
Conditions for safe storage including any incompatibilities
Store away from heat. Store away from acids. Store away from strong bases. Store away from oxidizing agents.
Specific end use(s)
See information in SDS section 7.1 and 7.2 for handling and storage recommendations. See Section 8 for exposure controls and personal protection recommendations.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
1. Engineering controls
Provide appropriate local exhaust when product is heated. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapours/spray. If ventilation is not adequate, use respiratory protection equipment. Use explosion-proof ventilation equipment.
2. Personal protective equipment (PPE)
Eye/face protection
Select and use eye/face protection to prevent contact based on the results of an exposure assessment. The following eye/face protection(s) are recommended:
Indirect vented goggles.
Applicable Norms/Standards
Use eye protection conforming to EN 166
Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions.
Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended:
Material Thickness (mm) Breakthrough Time
Polymer laminate No data available No data available
Applicable Norms/Standards
Use gloves tested to EN 374
If this product is used in a manner that presents a higher potential for exposure (eg. spraying, high splash potential etc.), then use of protective coveralls may be necessary. Select and use body protection to prevent contact based on the results of an exposure assessment. The following protective clothing material(s) are recommended: Apron - polymer laminate
Respiratory protection
An exposure assessment may be needed to decide if a respirator is required. If a respirator is needed, use respirators as part of a full respiratory protection program. Based on the results of the exposure assessment, select from the following respirator type(s) to reduce inhalation exposure:
During heating:
Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection.
Half facepiece or full facepiece air-purifying respirator suitable for organic vapours and particulates
For questions about suitability for a specific application, consult with your respirator manufacturer.
Applicable Norms/Standards
Use a respirator conforming to EN 140 or EN 136: filter types A & P
Stability and reactivity
1 Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section
2 Chemical stability
Stable.
3 Possibility of hazardous reactions
Hazardous polymerisation will not occur.
4 Conditions to avoid
Heat.
5 Incompatible materials
Strong acids.
Strong bases.
Strong oxidising agents.
6 Hazardous decomposition products
Substance Condition
None known.
Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product.
Disposal considerations
Dispose of contents/ container in accordance with the local/regional/national/international regulations.
Incinerate in a permitted waste incineration facility. Combustion products will include HF. Facility must be capable of handling halogenated materials. As a disposal alternative, utilize an acceptable permitted waste disposal facility. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
