Registration Dossier
Registration Dossier
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EC number: 257-522-9 | CAS number: 51931-66-9
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
- 4.1 Description of first aid measures
- General information
Personal protection for the First Aider.
Instantly remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
- After inhalation Supply fresh air or oxygen; call for doctor.
- After skin contact Instantly wash with water and soap and rinse thoroughly.
- After eye contact Rinse opened eye for several minutes (10 - 15)under running water.
- After swallowing
Instantly call for doctor.
Administer medicinal carbon
Rinse out mouth and then drink plenty of water (200 - 300 ml).
- 4.2 Most important symptoms and effects, both acute and delayed
CNS depression
Dizziness
Dyspnoea, wheezing, respiratory depression
Drowsiness/fatigue
Restlessness, irritability
Agitation/excitement
Nausea, vomiting
Irritating in the respiratory tract.
Bronchospasmus
Harnwege: Ureterspasmen, Miktionsstörungen
- Information for doctor Pharmacological group:
- Danger Der Reinstoff unterliegt den Richtlinien des BtMG.
- 4.3 Indication of any immediate medical attention and special treatment needed
If swallowed, gastric irrigation with added, activated carbon.
Possibly oxygen respiration treatment
- General information
Personal protection for the First Aider.
Instantly remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
- After inhalation Supply fresh air or oxygen; call for doctor.
- After skin contact Instantly wash with water and soap and rinse thoroughly.
- After eye contact Rinse opened eye for several minutes (10 - 15)under running water.
- After swallowing
Instantly call for doctor.
Administer medicinal carbon
Rinse out mouth and then drink plenty of water (200 - 300 ml).
- 4.2 Most important symptoms and effects, both acute and delayed
CNS depression
Dizziness
Dyspnoea, wheezing, respiratory depression
Drowsiness/fatigue
Restlessness, irritability
Agitation/excitement
Nausea, vomiting
Irritating in the respiratory tract.
Bronchospasmus
Harnwege: Ureterspasmen, Miktionsstörungen
- Information for doctor Pharmacological group:
- Danger Der Reinstoff unterliegt den Richtlinien des BtMG.
- 4.3 Indication of any immediate medical attention and special treatment needed
If swallowed, gastric irrigation with added, activated carbon.
Possibly oxygen respiration treatment
Fire-fighting measures
- 5.1 Extinguishing media
- Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
- For safety reasons unsuitable extinguishing agents Do not use a heavy water stream.
- 5.2 Special hazards arising from the substance or mixture
Can be released in case of fire
Nitrogen oxides (NOx)
Vapours heavier than air.
- 5.3 Advice for firefighters
- Protective equipment:
Wear self-contained breathing apparatus.
Do not inhale explosion gases or combustion gases.
Wear full protective suit.
- Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
- Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
- For safety reasons unsuitable extinguishing agents Do not use a heavy water stream.
- 5.2 Special hazards arising from the substance or mixture
Can be released in case of fire
Nitrogen oxides (NOx)
Vapours heavier than air.
- 5.3 Advice for firefighters
- Protective equipment:
Wear self-contained breathing apparatus.
Do not inhale explosion gases or combustion gases.
Wear full protective suit.
- Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Accidental release measures
- 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment (described in section 8). Keep unprotected persons away.
Do not inhale fumes/aerosol.
Avoid contact with substance.
- 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies.
- 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders).
Dispose of contaminated material as waste according to item 13.
Wear protective equipment (described in section 8). Keep unprotected persons away.
Do not inhale fumes/aerosol.
Avoid contact with substance.
- 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies.
- 6.3 Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders).
Dispose of contaminated material as waste according to item 13.
Handling and storage
- 7.1 Precautions for safe handling
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
- Information about protection against explosions and fires: No special measures required.
- 7.2 Conditions for safe storage, including any incompatibilities
- Storage
- Requirements to be met by storerooms and containers: No special requirements.
- Information about storage in one common storage facility: Not required.
- Further information about storage conditions:
Keep container tightly closed.
Store in cool, dry conditions in well sealed containers.
Store in a locked cabinet or with access restricted to technical experts or their assistants.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
- Information about protection against explosions and fires: No special measures required.
- 7.2 Conditions for safe storage, including any incompatibilities
- Storage
- Requirements to be met by storerooms and containers: No special requirements.
- Information about storage in one common storage facility: Not required.
- Further information about storage conditions:
Keep container tightly closed.
Store in cool, dry conditions in well sealed containers.
Store in a locked cabinet or with access restricted to technical experts or their assistants.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
- 8.1 Control parameters
- Components with limit values that require monitoring at the workplace: Not required.
- DNELs (Derived no-effect level) No information available
- PNECs (predicted no effect concentration) No information available
- Additional information: OEL (Pfizer): 50 ug/m³ (-)
- 8.2 Exposure controls
- Personal protective equipment
- General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals.
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
Do not inhale fumes
- Breathing equipment: Use breathing protection if fumes/aerosols are formed.
- Recommended filter device for short term use:Combination filter ABEK (DIN 3181)
- Protection of hands:Protective gloves (EN 374).
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
- Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
- Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
- Eye protection:Safety glasses
- Components with limit values that require monitoring at the workplace: Not required.
- DNELs (Derived no-effect level) No information available
- PNECs (predicted no effect concentration) No information available
- Additional information: OEL (Pfizer): 50 ug/m³ (-)
- 8.2 Exposure controls
- Personal protective equipment
- General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals.
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
Do not inhale fumes
- Breathing equipment: Use breathing protection if fumes/aerosols are formed.
- Recommended filter device for short term use:Combination filter ABEK (DIN 3181)
- Protection of hands:Protective gloves (EN 374).
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
- Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
- Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
- Eye protection:Safety glasses
Stability and reactivity
- 10.1 Reactivity No further relevant information available.
- 10.2 Chemical stability
- Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
- 10.3 Possibility of hazardous reactions No dangerous reactions known
- 10.4 Conditions to avoid No further relevant information available.
- 10.5 Incompatible materials: No further relevant information available.
- 10.6 Hazardous decomposition products: No dangerous decomposition products known
- 10.2 Chemical stability
- Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
- 10.3 Possibility of hazardous reactions No dangerous reactions known
- 10.4 Conditions to avoid No further relevant information available.
- 10.5 Incompatible materials: No further relevant information available.
- 10.6 Hazardous decomposition products: No dangerous decomposition products known
Disposal considerations
- 13.1 Waste treatment methods
- Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Hand over to disposers of hazardous waste.
Der Reinstoff unterliegt den Richtlinien des BtMG.
- Uncleaned packagings:
- Recommendation:
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
15 01 10: packaging containing residues of or contaminated by dangerous substances
Disposal must be made according to official regulations.
Packaging must be disposed of in compliance with country-specific regulations or must be passed to a
packaging return system.
- Recommendation
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Hand over to disposers of hazardous waste.
Der Reinstoff unterliegt den Richtlinien des BtMG.
- Uncleaned packagings:
- Recommendation:
Empty contaminated packagings thoroughly. They can be recycled after thorough and proper cleaning.
Packagings that cannot be cleaned are to be disposed of in the same manner as the product.
15 01 10: packaging containing residues of or contaminated by dangerous substances
Disposal must be made according to official regulations.
Packaging must be disposed of in compliance with country-specific regulations or must be passed to a
packaging return system.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
