Phosphoric acid, ethyl ester

Guidance on Safe Use

First-aid measures

· Description of first aid measures

· General information Instantly remove any clothing soiled by the product.

· After inhalation Supply fresh air; consult doctor in case of symptoms.

· After skin contact Instantly wash with water and soap and rinse thoroughly.

· After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.

· After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor.

· Most important symptoms and effects, both acute and delayed

No further relevant information available.

· Indication of any immediate medical attention and special treatment needed

No further relevant information available.

Fire-fighting measures

Extinguishing media

· Suitable extinguishing agents CO2, extinguishing powder or water jet. Fight larger fires with water jet.

· Special hazards arising from the substance or mixture

No further relevant information available.

· Advice for firefighters

· Protective equipment: Wear self-contained breathing apparatus.

Accidental release measures

Personal precautions, protective equipment and emergency procedures Wear protective clothing.

· Environmental precautions: Do not allow product to reach sewage system or water bodies.

· Methods and material for containment and cleaning up:

Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).

Use neutralising agent.

Dispose of contaminated material as waste according to section "Disposal considerations".

Ensure adequate ventilation.

Handling and storage

Precautions for safe handling No special measures required.

· Information about protection against explosions and fires: No special measures required.

· Conditions for safe storage, including any incompatibilities

· Requirements to be met by storerooms and containers: No special requirements.

· Information about storage in one common storage facility: Not required.

· Further information about storage conditions: Protect from humidity and keep away from water.

· Specific end use(s) No further relevant information available.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

UN3265

Shipping

Labels:

8

Special provisions / remarks

Special provisions:

Limited quantities (LQ) 1L
· Excepted quantities (EQ) Code: E2
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 500 ml
· Transport category 2
· Tunnel restriction code E

Inland waterway transport (UN RTDG/ADN(R))

UN number:

UN3265

Shipping

Labels:

8

Remarks

Marine transport (UN RTDG/IMDG)

UN number:

UN3265

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(Phosphoric acid ethyl ester)

Chemical name:

Phosphoric acid ethyl ester

Labels:

8

Special provisions / remarks

Remarks:

Limited quantities (LQ) 5L
· Excepted quantities (EQ) Code: E1
Maximum net quantity per inner packaging: 30 ml
Maximum net quantity per outer packaging: 1000 ml

Air transport (UN RTDG/ICAO/IATA)

UN number:

UN3265

Shipping information

Proper shipping name and description:

CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(Phosphoric acid ethyl ester)

Chemical name:

Phosphoric acid ethyl ester

Labels:

8

Remarks

Additional transport information

Additional information

Special provisions / remarks / other:

Special precautions for user Warning: Corrosive substances.
· Kemler Number: 80
· EMS Number: F-A,S-B
· Segregation groups Acids
· Stowage Category A
· Stowage Code SW2 Clear of living quarters.
UN "Model Regulation": UN3265, CORROSIVE LIQUID, ACIDIC, ORGANIC,
N.O.S., 8, III

Exposure controls / personal protection

Control parameters

· Components with critical values that require monitoring at the workplace:

64-17-5 ethanol (< 2.5%)

WEL Long-term value: 1920 mg/m³, 1000 ppm

· Additional information: The lists that were valid during the compilation were used as basis.

·  Exposure controls

· Personal protective equipment

· General protective and hygienic measures

The usual precautionary measures should be adhered to in handling the chemicals.

Keep away from foodstuffs, beverages and food.

Instantly remove any soiled and impregnated garments.

Avoid contact with the eyes and skin.

· Breathing equipment: Not required.

· Protection of hands: Protective gloves.

· Material of gloves Nitrile rubber, NBR

· Penetration time of glove material

The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be

observed.

· Eye protection: Tightly sealed safety glasses.

· Body protection: Protective work clothing.

Stability and reactivity

Reactivity No further relevant information available.

· Chemical stability

· Conditions to be avoided: No decomposition if used according to specifications.

· Possibility of hazardous reactions No dangerous reactions known

· Conditions to avoid No further relevant information available.

· Incompatible materials: No further relevant information available.

· Hazardous decomposition products: None

Disposal considerations

Waste treatment methods

· Recommendation

Must not be disposed of together with household waste. Do not allow product to reach sewage system.

Must be specially treated under adherence to official regulations.

· Uncleaned packagings:

· Recommendation: Packaging can be reused or recycled after cleaning.

· Recommended cleaning agent: Water, if necessary with cleaning agent.