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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Ecotoxicological information

Long-term toxicity to fish

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Administrative data

Link to relevant study record(s)

Description of key information

Since dipotassium hexafluorozirconate rapidly dissociates into fluoride, potassium and zirconium ions upon dissolution in the environment, and only fluoride but not zirconium ions will remain in solution, it can be assumed that toxicity (if any) will be driven by the fluoride anion. Therefore, full read-across of chronic toxicity data for fish of potassium fluoride (CAS #7789-23-3) and other fluorides based upon a molecular weight conversion is justified. The LC5 of 4 mg F/L derived for Oncoryhychus mykiss in a 21-d test with sodium fluoride (LC5 = 4 mg F/L ), results in an LC5 of 9.9 mg/L dipotassium hexafluorozirconate. 

Key value for chemical safety assessment

Fresh water fish

Fresh water fish
Effect concentration:
9.9 mg/L

Additional information

Dipotassium hexafluorozirconate

Since dipotassium hexafluorozirconate rapidly dissociates into fluoride, potassium and zirconium ions upon dissolution in the environment, and only fluoride but not zirconium ions will remain in solution, it can be assumed that toxicity (if any) will be driven by the fluoride anion. Therefore, full read-across of chronic toxicity data for fish of potassium fluoride (CAS #7789-23-3) and other fluorides based upon a molecular weight conversion is justified (see below).

Potassium fluoride

In a 21 day test with Oncorhynchus mykiss, an LC5 value of 4 mg F/L was reported (actual concentration). This value is considered to be equivalent to the NOEC for mortality. The test was conducted in very soft (12 mg CaCO3/L) natural water with daily renewal of the test water.