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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Physical & Chemical properties

Flammability

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Administrative data

Link to relevant study record(s)

Reference
Endpoint:
flammable gases
Type of information:
experimental study
Adequacy of study:
weight of evidence
Study period:
1989
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Publication in well acknowledged scientific journal
Qualifier:
no guideline followed
Principles of method if other than guideline:
Experiments were done in a closed cylindrical vessel at atmospheric pressure. Mixtures were ignited by fusing a nichrome wire by electric current at the centre of the vessel. Occurrence of explosion was determined from pressure history after ignition.
GLP compliance:
not specified
Parameter:
lower explosion limit
Value:
5.1 % (not further specified)
Parameter:
upper explosion limit
Value:
78 % (not further specified)
Interpretation of results:
Category 1 (flammable gases) based on GHS criteria
Conclusions:
The flammability limit of arsine in air is 5.1%–78%.
Executive summary:

Flammability limits of the substance in air and the dilution effect of nitrogen on the flammability limits were investigated experimentally. Experiments were done in a closed cylindrical vessel at atmospheric pressure. Mixtures were ignited by fusing a nichrome wire by electric current at the center of the vessel. Occurrence of explosion was determined from pressure history after ignition. Solid power deposit on the inner wall was also useful for the decision in the case of arsine test. The flammability limits were determined as follows. The flammability limit of arsine in air is 5.1–78% (Ohtani, 1989).

Description of key information

The flammability was determined experimentally and reported in a published article.

Key value for chemical safety assessment

Flammability:
flammable

Additional information

The flammability limit of arsine in air is 5.1 - 78%.

Justification for classification or non-classification

Arsine is classified as a flammable gas 1A (H220: extremely flammable gas) under the EU CLP regulation (EC) 1272/2008.