Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Study period:
November 30, 2009 - February 16, 2010
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
other: Study was performed in accordance with the OECD Guideline 104, and EU Method A.4.
Cross-reference
Reason / purpose for cross-reference:
reference to same study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2010
Report date:
2010

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Deviations:
no
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Deviations:
no
Principles of method if other than guideline:
Not applicable.
GLP compliance:
no
Remarks:
Not required by the authority
Type of method:
dynamic method

Test material

Constituent 1
Chemical structure
Reference substance name:
Nitrosylsulphuric acid
EC Number:
231-964-2
EC Name:
Nitrosylsulphuric acid
Cas Number:
7782-78-7
Molecular formula:
HNO5S
IUPAC Name:
hydroxy(nitrosooxy)sulfane dioxide
Test material form:
other: liquid
Details on test material:
Identity: Confirmed by density
Storage: RT, dry
Expiry Date: November 20, 2011

Results and discussion

Vapour pressureopen allclose all
Temp.:
20 °C
Vapour pressure:
0.026 hPa
Remarks on result:
other: Calculated value (Antoine constants)
Temp.:
25 °C
Vapour pressure:
0.041 hPa
Remarks on result:
other: Calculated value (Antoine constants)
Temp.:
50 °C
Vapour pressure:
0.3 hPa
Remarks on result:
other: Calculated value (Antoine constants)

Any other information on results incl. tables

The DSC-measurements in a closed glass crucible with the test item showed na exothermal effect in the temperature range 25 — 500 °C.

The vapour pressure was measured with the dynamic method in the temperature range of 115 °C to 205 °C. The measured vapour pressures at the corresponding temperatures are listed in the following table:

Temperature / °C              Vapour pressure / hPa

114.9                                   10.1

147.8                                   52.8

170.5                                   100.5

203.3                                   200.5

205.0                                   293.0

Applicant's summary and conclusion

Conclusions:
The values for 20, 25 and 50 °C are calculated, using the Antoine constants A, B and C.
Executive summary:

The study was performed in accordance with the OECD Guideline 104, and EU Method A.4 in year 2009/2010.

The Antoine constants from the regression of the data from the dynamic method were used to calculate the vapour pressure for 20, 25 and 50 °C:

T /°C              p/hPa              p/Pa

20              2.6 x 10-2        2.6 x 10.0

25              4.1 x 10-2       4.1 x 10.0

50             3.0 x 10-1       3.0 x 10.1