Registration Dossier
Registration Dossier
Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.
The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
Use of this information is subject to copyright laws and may require the permission of the owner of the information, as described in the ECHA Legal Notice.
EC number: 226-724-9 | CAS number: 5459-04-1
Vapour pressure
Administrative data
- Endpoint:
- vapour pressure
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 2010
- Reliability:
- 1 (reliable without restriction)
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 010
- Report date:
- 2010
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.4 (Vapour Pressure)
- Deviations:
- not specified
- GLP compliance:
- no
- Type of method:
- effusion method: vapour pressure balance
Test material
- Reference substance name:
- Ethylene diacetoacetate
- EC Number:
- 226-724-9
- EC Name:
- Ethylene diacetoacetate
- Cas Number:
- 5459-04-1
- Molecular formula:
- C10H14O6
- IUPAC Name:
- ethane-1,2-diyl bis(3-oxobutanoate)
Constituent 1
Results and discussion
Vapour pressureopen allclose all
- Temp.:
- 20 °C
- Vapour pressure:
- 0.004 Pa
- Temp.:
- 25 °C
- Vapour pressure:
- 0.008 Pa
- Temp.:
- 50 °C
- Vapour pressure:
- 0.27 Pa
Any other information on results incl. tables
The vapour pressure was measured in the temperature range of 20 °C to 106 °C. Above 55 °C a reasonable vapour pressure could be measured. The measured vapour pressures at the corresponding temperatures are listed in the following table:
Temperature / °C |
Vapour pressure / hPa |
15.8 |
1.8× 10-5 |
21.1 |
4.6× 10-5 |
26.3 |
1.0× 10-4 |
31.0 |
2.0× 10-4 |
35.7 |
4.5× 10-4 |
40.1 |
7.5× 10-4 |
45.2 |
1.5× 10-3 |
50.3 |
2.5× 10-3 |
The values for 20, 25 and 50 °C are calculated, using the Antoine constants A, B and C as shown.
T / °C |
p / hPa |
|
|
log (p/hPa) = A + B/(C+T[°C]) |
|
20 |
3.81E-05 |
|
|
A = |
15.57926 |
25 |
8.24E-05 |
|
|
B = |
-5862.63 |
50 |
2.74E-03 |
|
|
C = |
273.15 |
Applicant's summary and conclusion
- Conclusions:
- The following vapour pressure values for the test item were extrapolated from the experimental data:
T / °C p / hPa p / Pa
20 3.8 × 10-5 3.8 × 10-3
25 8.2 × 10-5 8.2 × 10-3
50 2.7 × 10-3 2.7 × 10-1 - Executive summary:
The vapour pressure of the test item was determined according to theEuropeanCommission Regulation (EC) No. 440/2008, A.4 Vapour pressure:Vapour pressure balance (effudion method). The vapour pressure was measured in the range from 20°C to 106°C. Above 55 °C a reasonable vapour pressure could be measured. The results were included into a plot an the required vapour pressures were calulated out of it.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
