Registration Dossier
Registration Dossier
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EC number: 223-020-3 | CAS number: 3695-77-0
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
- 4.1 Description of first aid measures
- General information
Instantly remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
- After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness bring patient into stable side position for transport.
- After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek medical treatment.
- After eye contact
Rinse opened eye for several minutes (10 - 15) under running water. Then consult doctor.
Use eye protection.
- After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor.
- 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
- 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
- General information
Instantly remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
- After inhalation
Supply fresh air. If required, provide artificial respiration. Keep patient warm. Consult doctor if symptoms
persist.
In case of unconsciousness bring patient into stable side position for transport.
- After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek medical treatment.
- After eye contact
Rinse opened eye for several minutes (10 - 15) under running water. Then consult doctor.
Use eye protection.
- After swallowing Drink copious amounts of water and provide fresh air. Instantly call for doctor.
- 4.2 Most important symptoms and effects, both acute and delayed No further relevant information available.
- 4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Fire-fighting measures
- 5.1 Extinguishing media
- Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
- For safety reasons unsuitable extinguishing agents Do not use a heavy water stream.
- 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
Can be released in case of fire
Sulphur dioxide (SO2)
- 5.3 Advice for firefighters
- Protective equipment:
Wear self-contained breathing apparatus.
Do not inhale explosion gases or combustion gases.
Wear full protective suit.
- Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
- Suitable extinguishing agents
CO2, extinguishing powder or water jet. Fight larger fires with water jet or alcohol-resistant foam.
- For safety reasons unsuitable extinguishing agents Do not use a heavy water stream.
- 5.2 Special hazards arising from the substance or mixture
Formation of toxic gases is possible during heating or in case of fire.
Can be released in case of fire
Sulphur dioxide (SO2)
- 5.3 Advice for firefighters
- Protective equipment:
Wear self-contained breathing apparatus.
Do not inhale explosion gases or combustion gases.
Wear full protective suit.
- Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Accidental release measures
- 6.1 Personal precautions, protective equipment and emergency procedures
Wear protective equipment (described in section 8). Keep unprotected persons away.
Avoid causing dust.
Do not inhale dust.
Avoid contact with substance.
- 6.2 Environmental precautions: Do not allow to enter drainage system, surface or ground water.
- 6.3 Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to item 13.
Collect mechanically.
Ensure adequate ventilation.
Send for recovery or disposal in suitable containers.
Wear protective equipment (described in section 8). Keep unprotected persons away.
Avoid causing dust.
Do not inhale dust.
Avoid contact with substance.
- 6.2 Environmental precautions: Do not allow to enter drainage system, surface or ground water.
- 6.3 Methods and material for containment and cleaning up:
Dispose of contaminated material as waste according to item 13.
Collect mechanically.
Ensure adequate ventilation.
Send for recovery or disposal in suitable containers.
Handling and storage
- 7.1 Precautions for safe handling
Thorough dedusting.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of dust.
- Information about protection against explosions and fires: No special measures required.
- 7.2 Conditions for safe storage, including any incompatibilities
- Storage
- Requirements to be met by storerooms and containers: No special requirements.
- Information about storage in one common storage facility: Not required.
- Further information about storage conditions:
Keep container tightly closed.
Store in cool, dry conditions in well sealed containers.
- 7.3 Specific end use(s) No further relevant information available.
Thorough dedusting.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of dust.
- Information about protection against explosions and fires: No special measures required.
- 7.2 Conditions for safe storage, including any incompatibilities
- Storage
- Requirements to be met by storerooms and containers: No special requirements.
- Information about storage in one common storage facility: Not required.
- Further information about storage conditions:
Keep container tightly closed.
Store in cool, dry conditions in well sealed containers.
- 7.3 Specific end use(s) No further relevant information available.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
- Additional information about design of technical systems: No further data; see item 7.
- 8.1 Control parameters
- Components with limit values that require monitoring at the workplace: Not required.
- DNELs (Derived no-effect level) No information available
- PNECs (predicted no effect concentration) No information available
- Additional information: The lists that were valid during the compilation were used as basis.
- 8.2 Exposure controls
- Personal protective equipment
- General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals.
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Do not inhale dust
- Breathing equipment: Use breathing protection only if dust is formed.
- Recommended filter device for short term use:
Combination filter ABEK (DIN 3181)
- Protection of hands:
Protective gloves (EN 374).
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
To avoid skin problems reduce the wearing of gloves to the required minimum.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
- Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
- Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
The times listed are suggested by measurements taken at 22 degree C and constant contact. Temperatures
raised by warmed substances, body heat, etc. and a weakening of the effective layer thickness caused by
expansion can lead to a significantly shorter breakthrough time.
In case of doubt contact the gloves' manufacturer.
A 1.5-times increase / decrease in the layer thickness doubles / halves the breakthrough time. This data only
applies to the pure substance. Transferred to mixtures of substances, these figures should only be taken as an
aid to orientation.
- Eye protection:
Tightly sealed safety glasses.
- Body protection: Protective work clothing.
- 8.1 Control parameters
- Components with limit values that require monitoring at the workplace: Not required.
- DNELs (Derived no-effect level) No information available
- PNECs (predicted no effect concentration) No information available
- Additional information: The lists that were valid during the compilation were used as basis.
- 8.2 Exposure controls
- Personal protective equipment
- General protective and hygienic measures
The usual precautionary measures should be adhered to general rules for handling chemicals.
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Do not inhale gases / fumes / aerosols.
Avoid contact with the eyes.
Avoid contact with the eyes and skin.
Do not inhale dust
- Breathing equipment: Use breathing protection only if dust is formed.
- Recommended filter device for short term use:
Combination filter ABEK (DIN 3181)
- Protection of hands:
Protective gloves (EN 374).
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
To avoid skin problems reduce the wearing of gloves to the required minimum.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
- Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer.
- Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
The times listed are suggested by measurements taken at 22 degree C and constant contact. Temperatures
raised by warmed substances, body heat, etc. and a weakening of the effective layer thickness caused by
expansion can lead to a significantly shorter breakthrough time.
In case of doubt contact the gloves' manufacturer.
A 1.5-times increase / decrease in the layer thickness doubles / halves the breakthrough time. This data only
applies to the pure substance. Transferred to mixtures of substances, these figures should only be taken as an
aid to orientation.
- Eye protection:
Tightly sealed safety glasses.
- Body protection: Protective work clothing.
Stability and reactivity
- 10.1 Reactivity No further relevant information available.
- 10.2 Chemical stability
- Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
- 10.3 Possibility of hazardous reactions No dangerous reactions known
- 10.4 Conditions to avoid No further relevant information available.
- 10.5 Incompatible materials: Strong oxidizing materials
- 10.6 Hazardous decomposition products:
No dangerous decomposition products known
Sulphur dioxide
Sulphur oxides (SOx)
- 10.2 Chemical stability
- Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
- 10.3 Possibility of hazardous reactions No dangerous reactions known
- 10.4 Conditions to avoid No further relevant information available.
- 10.5 Incompatible materials: Strong oxidizing materials
- 10.6 Hazardous decomposition products:
No dangerous decomposition products known
Sulphur dioxide
Sulphur oxides (SOx)
Disposal considerations
- 13.1 Waste treatment methods
- Recommendation
Hand over to disposers of hazardous waste.
Chemicals must be disposed of in compliance with restrictive national regulations.
- Uncleaned packagings:
- Recommendation:
Disposal must be made according to official regulations.
Packaging must be disposed of in compliance with country-specific regulations or must be passed to a
packaging return system.
- Recommendation
Hand over to disposers of hazardous waste.
Chemicals must be disposed of in compliance with restrictive national regulations.
- Uncleaned packagings:
- Recommendation:
Disposal must be made according to official regulations.
Packaging must be disposed of in compliance with country-specific regulations or must be passed to a
packaging return system.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
