Registration Dossier
Registration Dossier
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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 222-012-7 | CAS number: 3317-67-7
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
· General information:
In case of exposure take initial precautionary measures mentioned below and if uneasiness persist, immediately
consult a doctor.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Generally the product does not irritate the skin.
Wash with water and acidic soap.
Remove contaminated clothes.
· After eye contact:
Remove any contact lenses. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Drink plenty of water and provide fresh air. Call for a doctor immediately.
Induce vomiting only, if affected person is fully conscious.
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
· General information:
In case of exposure take initial precautionary measures mentioned below and if uneasiness persist, immediately
consult a doctor.
· After inhalation: Supply fresh air; consult doctor in case of complaints.
· After skin contact:
Generally the product does not irritate the skin.
Wash with water and acidic soap.
Remove contaminated clothes.
· After eye contact:
Remove any contact lenses. Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
· After swallowing:
Drink plenty of water and provide fresh air. Call for a doctor immediately.
Induce vomiting only, if affected person is fully conscious.
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Fire-fighting measures
Extinguishing media
· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
· For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards arising from the substance or mixture
Powders in suspension may form a flammable dust cloud. In case of fire, the following can be released:
Carbon oxides (COx)
Metal oxide fume.
Nitrogen oxides (NOx)
Hydrogen cyanide (HCN)
Advice for firefighters
· Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear fully protective suit.
· Suitable extinguishing agents: Use fire extinguishing methods suitable to surrounding conditions.
· For safety reasons unsuitable extinguishing agents: Water with full jet
Special hazards arising from the substance or mixture
Powders in suspension may form a flammable dust cloud. In case of fire, the following can be released:
Carbon oxides (COx)
Metal oxide fume.
Nitrogen oxides (NOx)
Hydrogen cyanide (HCN)
Advice for firefighters
· Protective equipment:
Do not inhale explosion gases or combustion gases.
Wear fully protective suit.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow product to reach sewage system or any water course.
Methods and material for containment and cleaning up:
Pick up mechanically.
Absorb liquid components with liquid-binding material.
Wear protective equipment. Keep unprotected persons away.
Ensure adequate ventilation
Environmental precautions: Do not allow product to reach sewage system or any water course.
Methods and material for containment and cleaning up:
Pick up mechanically.
Absorb liquid components with liquid-binding material.
Handling and storage
Precautions for safe handling
Thorough dedusting.
Keep receptacles tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
This product should be used only in a closed system, if not possible, ensure a sufficient protection of workers (see “Exposure controls/personal protection” section).
Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Store only a limited quantity of product at the workplace.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Protect from heat and direct sunlight. The product should be maintained in a clean area with adequate ventilation.
Specific end use(s) No further relevant information available.
Thorough dedusting.
Keep receptacles tightly sealed.
Ensure good ventilation/exhaustion at the workplace.
This product should be used only in a closed system, if not possible, ensure a sufficient protection of workers (see “Exposure controls/personal protection” section).
Conditions for safe storage, including any incompatibilities
· Storage:
· Requirements to be met by storerooms and receptacles: Store only in the original receptacle. Store only a limited quantity of product at the workplace.
· Information about storage in one common storage facility: Not required.
· Further information about storage conditions: Protect from heat and direct sunlight. The product should be maintained in a clean area with adequate ventilation.
Specific end use(s) No further relevant information available.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
· Ingredients with limit values that require monitoring at the workplace: Exposure limit values to dust (R.4222-10):
Total dust: 10 mg/m3 (8h)
Respirable dust 5 mg/m3 (8h)
· Additional information: The lists valid during the making were used as basis.
· DNELs: Not required.
· PNECs: Not required.
Exposure controls
Restrict the access to the product only to few authorized professionals. Only trained workers should handle the substance. Do not smoke, eat or drink close to the work area.
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals. A suitable individual protection equipment should be wear during the use of the product. Protection equipment and street clothes should be stored at different place. Protection equipment should be checked and washed after each use. Defective equipment have to be repaired or replaced before further use. Do not eat, drink or smoke while handling the product.
· Respiratory protection: Suitable respiratory protective device recommended.
· Eye protection: Safety glasses
· Skin protection:
· Hand protection
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
Rubber gloves
Plastic gloves
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to
be observed.
- Body protection: Use protective suit.
· Respiratory protection
Suitable respiratory protective device recommended.
· Thermal hazards
Not applicable.
· Ingredients with limit values that require monitoring at the workplace: Exposure limit values to dust (R.4222-10):
Total dust: 10 mg/m3 (8h)
Respirable dust 5 mg/m3 (8h)
· Additional information: The lists valid during the making were used as basis.
· DNELs: Not required.
· PNECs: Not required.
Exposure controls
Restrict the access to the product only to few authorized professionals. Only trained workers should handle the substance. Do not smoke, eat or drink close to the work area.
· Personal protective equipment:
· General protective and hygienic measures:
The usual precautionary measures are to be adhered to when handling chemicals. A suitable individual protection equipment should be wear during the use of the product. Protection equipment and street clothes should be stored at different place. Protection equipment should be checked and washed after each use. Defective equipment have to be repaired or replaced before further use. Do not eat, drink or smoke while handling the product.
· Respiratory protection: Suitable respiratory protective device recommended.
· Eye protection: Safety glasses
· Skin protection:
· Hand protection
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
Rubber gloves
Plastic gloves
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to
be observed.
- Body protection: Use protective suit.
· Respiratory protection
Suitable respiratory protective device recommended.
· Thermal hazards
Not applicable.
Stability and reactivity
Reactivity No further relevant information available.
Chemical stability
Stable under the recommended handling and storage conditions.
Possibility of hazardous reactions No hazardous reactions known other than dust explosion hazard and thermal decomposition.
Conditions to avoid
Ignition sources (mechanical, electrostatic, sparks…)
Avoid contact with incompatible materials, dust generation, strong oxidants.
Incompatible materials: No further relevant information available.
Hazardous decomposition products:
Carbon oxides (COx)
Nitrogen oxides (NOx)
Metal oxide fumes.
Hydrogen cyanide (HCN)
Chemical stability
Stable under the recommended handling and storage conditions.
Possibility of hazardous reactions No hazardous reactions known other than dust explosion hazard and thermal decomposition.
Conditions to avoid
Ignition sources (mechanical, electrostatic, sparks…)
Avoid contact with incompatible materials, dust generation, strong oxidants.
Incompatible materials: No further relevant information available.
Hazardous decomposition products:
Carbon oxides (COx)
Nitrogen oxides (NOx)
Metal oxide fumes.
Hydrogen cyanide (HCN)
Disposal considerations
Waste treatment methods
· Recommendation Smaller quantities can be disposed of with household waste.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
· Recommendation Smaller quantities can be disposed of with household waste.
· Uncleaned packaging:
· Recommendation: Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
