Registration Dossier
Registration Dossier
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EC number: 217-022-3 | CAS number: 1722-26-5
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
1 Description of first aid measures
General notes:
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give anything by mouth.
Following inhalation:
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of respiratory tract irritation, consult a physician. Provide fresh air.
Following skin contact:
Wash with plenty of soap and water.
Following eye contact:
Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart.
Following ingestion:
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
2 Most important symptoms and effects, both acute and delayed
Symptoms and effects are not known to date.
3 Indication of any immediate medical attention and special treatment needed
None.
General notes:
Do not leave affected person unattended. Remove victim out of the danger area. Keep affected person warm, still and covered. Take off immediately all contaminated clothing. In all cases of doubt, or when symptoms persist, seek medical advice. In case of unconsciousness place person in the recovery position. Never give anything by mouth.
Following inhalation:
If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions. In case of respiratory tract irritation, consult a physician. Provide fresh air.
Following skin contact:
Wash with plenty of soap and water.
Following eye contact:
Remove contact lenses, if present and easy to do. Continue rinsing. Irrigate copiously with clean, fresh water for at least 10 minutes, holding the eyelids apart.
Following ingestion:
Rinse mouth with water (only if the person is conscious). Do NOT induce vomiting.
2 Most important symptoms and effects, both acute and delayed
Symptoms and effects are not known to date.
3 Indication of any immediate medical attention and special treatment needed
None.
Fire-fighting measures
1 Extinguishing media
Suitable extinguishing media:
Excess of water, Water spray, Water mist, Foam, Alcohol resistant foam, Dry extinguishing powder, Fire extinguishing powder, BC-powder, ABC-powder, Carbon dioxide (CO2), Sand
2 Special hazards arising from the substance or mixture
Hazardous combustion products:
Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2), Borate
3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surroundings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight fire with normal precautions from a reasonable distance. Wear self-contained breathing apparatus.
Suitable extinguishing media:
Excess of water, Water spray, Water mist, Foam, Alcohol resistant foam, Dry extinguishing powder, Fire extinguishing powder, BC-powder, ABC-powder, Carbon dioxide (CO2), Sand
2 Special hazards arising from the substance or mixture
Hazardous combustion products:
Nitrogen oxides (NOx), Carbon monoxide (CO), Carbon dioxide (CO2), Borate
3 Advice for firefighters
In case of fire and/or explosion do not breathe fumes. Co-ordinate firefighting measures to the fire surroundings. Do not allow firefighting water to enter drains or water courses. Collect contaminated firefighting water separately. Fight fire with normal precautions from a reasonable distance. Wear self-contained breathing apparatus.
Accidental release measures
1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel:
Remove persons to safety.
For emergency responders:
Wear breathing apparatus if exposed to vapours/dust/spray/gases.
2 Environmental precautions
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. If substance has entered a water course or sewer, inform the responsible authority.
3 Methods and material for containment and cleaning up
Advices on how to contain a spill:
Covering of drains
Advices on how to clean up a spill:
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binder
Appropriate containment techniques:
Use of adsorbent materials.
Other information relating to spills and releases:
Place in appropriate containers for disposal. Ventilate affected area.
For non-emergency personnel:
Remove persons to safety.
For emergency responders:
Wear breathing apparatus if exposed to vapours/dust/spray/gases.
2 Environmental precautions
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose of it. If substance has entered a water course or sewer, inform the responsible authority.
3 Methods and material for containment and cleaning up
Advices on how to contain a spill:
Covering of drains
Advices on how to clean up a spill:
Wipe up with absorbent material (e.g. cloth, fleece). Collect spillage: sawdust, kieselgur (diatomite), sand, universal binder
Appropriate containment techniques:
Use of adsorbent materials.
Other information relating to spills and releases:
Place in appropriate containers for disposal. Ventilate affected area.
Handling and storage
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site. See section 13 (RMMs report) for further information.
1 Precautions for safe handling
Recommendations:
Measures to prevent fire as well as aerosol and dust generation:
Use local and general ventilation. Use only in well-ventilated areas.
Advice on general occupational hygiene:
Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.
2 Conditions for safe storage, including any incompatibilities
Packaging compatibilities:
Only packagings which are approved (e.g. acc. to the Dangerous Goods Regulations) may be used.
Shelf-life:
Production date + 48 months.
1 Precautions for safe handling
Recommendations:
Measures to prevent fire as well as aerosol and dust generation:
Use local and general ventilation. Use only in well-ventilated areas.
Advice on general occupational hygiene:
Wash hands after use. Do not eat, drink and smoke in work areas. Remove contaminated clothing and protective equipment before entering eating areas. Never keep food or drink in the vicinity of chemicals. Never place chemicals in containers that are normally used for food or drink. Keep away from food, drink and animal feedingstuffs.
2 Conditions for safe storage, including any incompatibilities
Packaging compatibilities:
Only packagings which are approved (e.g. acc. to the Dangerous Goods Regulations) may be used.
Shelf-life:
Production date + 48 months.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- 2924
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, CORROSIVE, N.O.S.
- Chemical name:
- Triethylamine-borane, triethylamine
- Language:
- English
- Labels:
- 3+8, fish and tree
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- 2924
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, CORROSIVE, N.O.S.
- Chemical name:
- Triethylamine-borane, triethylamine
- Language:
- English
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- 2924
Shipping information
- Proper shipping name and description:
- FLAMMABLE LIQUID, CORROSIVE, N.O.S.
- Chemical name:
- Triethylamine-borane, triethylamine
- Labels:
- 3+8, fish and tree
Special provisions / remarks
- Remarks:
- Stowage category A
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- 2924
Shipping information
- Proper shipping name and description:
- Flammable liquid, corrosive, n.o.s.
- Chemical name:
- Triethylamine-borane, triethylamine
- Labels:
- 3+8, fish and tree
Special provisions / remarks
- Remarks:
- Special provisions (SP) A3
Excepted quantities (EQ) E1
Limited quantities (LQ) 1 L
Additional transport information
Additional information
- Special provisions / remarks / other:
- Transport in bulk according to Annex II of MARPOL and the IBC Code: The cargo is not intended to be carried in bulk.
Special provisions (SP) 223, 274 (UN RTDG)
Excepted quantities (EQ) E1 (UN RTDG)
Limited quantities (LQ) 5 L (UN RTDG)
Exposure controls / personal protection
This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 17(3) for on-site isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4). Site documentation to support safe handling arrangements including the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based management systems is available at each manufacturing site. See section 13 (RMMs report) for further information.
1 Control parameters
Triethylamine, EU, IOELV:
TWA: 2 ppm, 8.4 mg/m3
STEL: 3 ppm; 12.6 mg/m3
2 Exposure controls
Appropriate engineering controls:
General ventilation.
Individual protection measures (personal protective equipment):
Eye/face protection:
Wear eye/face protection.
Skin protection:
Hand protection:
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/ impermeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
Other protection measures:
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended.
Wash hands thoroughly after handling.
Respiratory protection:
In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls:
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.
1 Control parameters
Triethylamine, EU, IOELV:
TWA: 2 ppm, 8.4 mg/m3
STEL: 3 ppm; 12.6 mg/m3
2 Exposure controls
Appropriate engineering controls:
General ventilation.
Individual protection measures (personal protective equipment):
Eye/face protection:
Wear eye/face protection.
Skin protection:
Hand protection:
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/ impermeability prior to use. In the case of wanting to use the gloves again, clean them before taking off and air them well. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves.
Other protection measures:
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended.
Wash hands thoroughly after handling.
Respiratory protection:
In case of inadequate ventilation wear respiratory protection.
Environmental exposure controls:
Use appropriate container to avoid environmental contamination. Keep away from drains, surface and ground water.
Stability and reactivity
1 Reactivity
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".
2 Chemical stability
See below "Conditions to avoid".
3 Possibility of hazardous reactions
No known hazardous reactions.
4 Conditions to avoid
There are no specific conditions known which have to be avoided.
5 Incompatible materials
Water, Acids, Bases, Oxidisers
6 Hazardous decomposition products
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known.
Concerning incompatibility: see below "Conditions to avoid" and "Incompatible materials".
2 Chemical stability
See below "Conditions to avoid".
3 Possibility of hazardous reactions
No known hazardous reactions.
4 Conditions to avoid
There are no specific conditions known which have to be avoided.
5 Incompatible materials
Water, Acids, Bases, Oxidisers
6 Hazardous decomposition products
Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill and heating are not known.
Disposal considerations
Waste treatment-relevant information:
Incineration.
Sewage disposal-relevant information:
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Waste treatment of containers/packagings:
Only packagings which are approved (e.g. acc. to the Dangerous Goods Regulations) may be used. Completely emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself.
Remarks:
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities.
Incineration.
Sewage disposal-relevant information:
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data sheets.
Waste treatment of containers/packagings:
Only packagings which are approved (e.g. acc. to the Dangerous Goods Regulations) may be used. Completely emptied packages can be recycled. Handle contaminated packages in the same way as the substance itself.
Remarks:
Please consider the relevant national or regional provisions. Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
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