Registration Dossier
Registration Dossier
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EC number: 207-313-3 | CAS number: 461-72-3
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures:
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim
warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Inhalation is possible if aerosols, mists, dusts, or smoke form.
Move victims into fresh air.
With labored breathing: Provide with oxygen. Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
In case of persistent discomfort: Consult an ophthalmologist.
Ingestion:
Rinse mouth.
Immediately give large quantities of water to drink.
Obtain medical attention.
Most important symptoms and effects, both acute and delayed:
Symptoms:
None known
Hazards:
Other dangerous properties can not be excluded.
Indication of any immediate medical attention and special treatment needed:
This product has not been completely analyzed yet and all health hazards might not be known.
Pay attention to self-protection.
Remove victims from hazardous area. Immediately remove soiled or soaked clothing and remove it to a safe distance. Keep victim
warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Inhalation:
Inhalation is possible if aerosols, mists, dusts, or smoke form.
Move victims into fresh air.
With labored breathing: Provide with oxygen. Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin contact:
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
In case of persistent discomfort: Consult an ophthalmologist.
Ingestion:
Rinse mouth.
Immediately give large quantities of water to drink.
Obtain medical attention.
Most important symptoms and effects, both acute and delayed:
Symptoms:
None known
Hazards:
Other dangerous properties can not be excluded.
Indication of any immediate medical attention and special treatment needed:
This product has not been completely analyzed yet and all health hazards might not be known.
Fire-fighting measures
Extinguishing media:
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
Hazard-determining flue gases might develop in case of fire:
Carbon monoxide
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
Use water spray to cool unopened containers.
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
Fire residues should be disposed of in accordance with the regulations.
Keep out unprotected persons.
Wear personal protective equipment.
In the event of fire, wear self-contained breathing apparatus.
Suitable extinguishing media: Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Unsuitable extinguishing media: Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
Hazard-determining flue gases might develop in case of fire:
Carbon monoxide
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Advice for firefighters:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
Use water spray to cool unopened containers.
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
Fire residues should be disposed of in accordance with the regulations.
Keep out unprotected persons.
Wear personal protective equipment.
In the event of fire, wear self-contained breathing apparatus.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Use personal protective equipment.
Keep unauthorized persons away.
Environmental precautions:
Observe regulations on prevention of water pollution (check, dam up, cover up).
Do not allow entrance in sewage water, soil, stretches of water, drainage systems, surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Pick up mechanically. Collect in suitable containers.
To absorb spilled substance an approved industrial vacuum cleaner is recommended. If necessary, the spilled substance should
be moistened.
Clean contaminated surface thoroughly.
Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.
Disposal according to local authority regulations.
Reference to other sections:
Wear personal protective equipment; see Exposure controls / personal protection.
Use personal protective equipment.
Keep unauthorized persons away.
Environmental precautions:
Observe regulations on prevention of water pollution (check, dam up, cover up).
Do not allow entrance in sewage water, soil, stretches of water, drainage systems, surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Pick up mechanically. Collect in suitable containers.
To absorb spilled substance an approved industrial vacuum cleaner is recommended. If necessary, the spilled substance should
be moistened.
Clean contaminated surface thoroughly.
Pack and label wastes like the pure substance. Do not detach label from the delivery containers prior to disposal.
Disposal according to local authority regulations.
Reference to other sections:
Wear personal protective equipment; see Exposure controls / personal protection.
Handling and storage
Precautions for safe handling:
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Ensure that apparatus and pipelines are free from leaks. Do not ventilate into the open.
Dedicated loading/unloading stations required.
Conditions for safe storage, including any incompatibilities:
Advice on protection against fire and explosion
Normal measures for preventive fire protection.
Take precautionary measures against static discharges.
Keep away from flames / sparks, no smoking.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Further information: VDI 2263 "Dust fires and dust explosions; dangers, evaluation, preventive measures."
Storage:
Keep container tightly closed in a dry and well-ventilated place.
Store at room temperature.
Further information:
Protect from sunlight, warmth and heat.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as
not to fall off, and labelled according to the regulations.
In the event of internal transportation, already-opened containers are to be kept closed in order to avoid spillage.
German storage class:
13 - Non Combustible Solids
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Ensure that apparatus and pipelines are free from leaks. Do not ventilate into the open.
Dedicated loading/unloading stations required.
Conditions for safe storage, including any incompatibilities:
Advice on protection against fire and explosion
Normal measures for preventive fire protection.
Take precautionary measures against static discharges.
Keep away from flames / sparks, no smoking.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Further information: VDI 2263 "Dust fires and dust explosions; dangers, evaluation, preventive measures."
Storage:
Keep container tightly closed in a dry and well-ventilated place.
Store at room temperature.
Further information:
Protect from sunlight, warmth and heat.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as
not to fall off, and labelled according to the regulations.
In the event of internal transportation, already-opened containers are to be kept closed in order to avoid spillage.
German storage class:
13 - Non Combustible Solids
Transport information
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Marine transport (UN RTDG/IMDG)
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Additional transport information
Additional information
- Special provisions / remarks / other:
- Not dangerous according to transport regulations.
Exposure controls / personal protection
Control parameters:
Other information:
Contains no substances with occupational exposure limit values.
DNEL/DMEL values:
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.
PNEC values:
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.
Exposure controls:
Engineering measures:
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Do not lead exhaust air back to workplace areas unfiltered.
Exhaust filter or scrubber.
exhaust air filter (HEPA-filter)
Do not add wastewater to a biological wastewater treatment plant
In case of dissolved solids:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation
of vapours.
Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a
manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).
All precautionary measures indicated have to be observed.
Exposure controls:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation
of vapours.
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.
Personal protective equipment:
Respiratory protection:
Accidental release measures
use respiratory equipment with suitable filter (filter type P3) or wear a self contained respiratory apparatus
Note time limit for wearing respiratory protective equipment.
Hand protection:
Glove material Nitrile, for example, Dermatril 740, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.11 mm
Method: DIN EN 374
Accidental release measures:
Glove material Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.65 mm
Method: DIN EN 374
Eye protection:
Safety glasses with side-shields conforming to EN166
Accidental release measures:
close-fitting protective goggles (e.g. closed goggles)
Skin and body protection:
suitable protective clothing - Use disposable clothing if appropriate.
Hygiene measures:
Avoid contact with skin, eyes and clothing.
Wash contact areas after handling.
Take off clothing and shoes contaminated with product. Clean before reuse.
Do not eat, drink, smoke, or sniff while at work. Wash your hands and/or face before breaks and before termination of work.
Protective measures:
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.
All precautionary measures indicated have to be observed.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Regular safety training is a must.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
Environmental exposure controls:
In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease emissions to acceptable values.
Other information:
Contains no substances with occupational exposure limit values.
DNEL/DMEL values:
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.
PNEC values:
Remarks: No substance-related safety assessment is necessary / has been conducted for this product.
Exposure controls:
Engineering measures:
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Do not lead exhaust air back to workplace areas unfiltered.
Exhaust filter or scrubber.
exhaust air filter (HEPA-filter)
Do not add wastewater to a biological wastewater treatment plant
In case of dissolved solids:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation
of vapours.
Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a
manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).
All precautionary measures indicated have to be observed.
Exposure controls:
Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation
of vapours.
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.
Personal protective equipment:
Respiratory protection:
Accidental release measures
use respiratory equipment with suitable filter (filter type P3) or wear a self contained respiratory apparatus
Note time limit for wearing respiratory protective equipment.
Hand protection:
Glove material Nitrile, for example, Dermatril 740, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.11 mm
Method: DIN EN 374
Accidental release measures:
Glove material Nitrile/Chloroprene, for example, Nitopren 717, Kächele-Cama Latex GmbH (KCL), Germany
Material thickness: 0.65 mm
Method: DIN EN 374
Eye protection:
Safety glasses with side-shields conforming to EN166
Accidental release measures:
close-fitting protective goggles (e.g. closed goggles)
Skin and body protection:
suitable protective clothing - Use disposable clothing if appropriate.
Hygiene measures:
Avoid contact with skin, eyes and clothing.
Wash contact areas after handling.
Take off clothing and shoes contaminated with product. Clean before reuse.
Do not eat, drink, smoke, or sniff while at work. Wash your hands and/or face before breaks and before termination of work.
Protective measures:
The personal protective equipment used must meet the requirements of directive 89/686/EEC and amendments (CE certification).
It should be defined in the work place in the form of a risk analysis according to directive 89/686/EEC and amendments.
All precautionary measures indicated have to be observed.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Regular safety training is a must.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
Environmental exposure controls:
In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease emissions to acceptable values.
Stability and reactivity
Reactivity:
No further information available
Chemical stability:
No further information available
Possibility of hazardous reactions:
Possibility of hazardous reactions: No hazardous reactions are known if properly handled and stored.
Conditions to avoid:
humidity
sun rays, heat, heat effect
Incompatible materials:
Strong oxidizing agents
Hazardous decomposition products:
Decomposition products in combustion and thermal decomposition:
Carbon monoxide
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
No further information available
Chemical stability:
No further information available
Possibility of hazardous reactions:
Possibility of hazardous reactions: No hazardous reactions are known if properly handled and stored.
Conditions to avoid:
humidity
sun rays, heat, heat effect
Incompatible materials:
Strong oxidizing agents
Hazardous decomposition products:
Decomposition products in combustion and thermal decomposition:
Carbon monoxide
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Disposal considerations
Waste treatment methods:
Product:
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Do not add wastewater to a biological wastewater treatment plant.
Bring wastewater containing AOX for professional disposal.
Bring used exhaust air filter for incineration
Disposal according to local authority regulations.
Uncleaned packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Waste Key Number:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Product:
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Do not add wastewater to a biological wastewater treatment plant.
Bring wastewater containing AOX for professional disposal.
Bring used exhaust air filter for incineration
Disposal according to local authority regulations.
Uncleaned packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Waste Key Number:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
