Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

First-aid measures

Description of first aid measures


General advice: Show this safety data sheet to the doctor in attendance. Consult a physician.


If inhaled: Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get immediate medical advice/ attention.


In case of skin contact: Wash off immediately with plenty of water for at least 15 minutes. Take off all contaminated clothing immediately. Call a physician or poison control centre immediately.


In case of eye contact: Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue
rinsing. If eye irritation persists: Get medical advice/ attention.


If swallowed: Call a physician or poison control centre immediately. Clean mouth with water and drink afterwards plenty of water. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person.


 


Most important symptoms and effects, both acute and delayed


Symptoms: Irregular cardiac activity, Dermatitis, Eczema, Headache, Nausea, Shortness of breath. May produce an allergic reaction. Health injuries may be delayed.



More severe effects if alcohol is consumed.


Indication of any immediate medical attention and special treatment needed


Treatment: General advice for dithiocarbamates. Biomonitoring possible at chronical exposure: determination of TTCA in the urine at the end of the workday/week. Bloodtesting for delayed effects: livertests, kidney function, thyroid function.

Fire-fighting measures

Extinguishing media


Suitable extinguishing media: Use water spray to extinguish. Carbon dioxide (CO2), Alcohol-resistant foam


Unsuitable extinguishing media: Do NOT use water jet.


 


Special hazards arising from the substance or mixture


Specific hazards during firefighting: Avoid generating dust; fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source is a potential dust explosion hazard.


 


Hazardous combustion products: Carbon monoxide, Nitrogen oxides (NOx), Sulphur oxides


 


Advice for firefighters


Special protective equipment for firefighters: Wear an approved positive pressure self-contained breathing apparatus in addition to standard fire fighting gear.


Further information: Take precautionary measures against static discharges.

Accidental release measures

Personal precautions, protective equipment and emergency procedures


Personal precautions: Wear appropriate personal protective equipment. Local authorities should be advised if significant spillages cannot be contained.


 


Environmental precautions: Avoid release to the environment.


 


Methods and material for containment and cleaning up


Methods for cleaning up: Sweep up or vacuum up spillage and collect in suitable container for disposal. Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations.

Handling and storage

Precautions for safe handling


Advice on safe handling: Avoid breathing dust. Do not get on skin or clothing. Do not get in eyes. Do not swallow. Ensure adequate ventilation. Wash thoroughly after handling.


Advice on protection against fire and explosion: Minimize dust generation and accumulation. Keep product and empty container away from heat and sources of ignition.


Hygiene measures: Handle in accordance with good industrial hygiene and safety practice.


 


Conditions for safe storage, including any incompatibilities


Requirements for storage areas and containers: Keep tightly closed. Keep in a dry, cool and well-ventilated place. Keep away from direct sunlight. Use only explosion proof equipment.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Thiram)
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
9
Special provisions / remarks
Special provisions:
Classification Code : M7
Hazard Identification Number : 90
Tunnel restriction code : (-)
Environmentally hazardous : yes

Inland waterway transport (UN RTDG/ADN(R))

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Thiram)
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
9
Special provisions / remarks
Special provisions:
Classification Code : M7
Hazard Identification Number : 90

Marine transport (UN RTDG/IMDG)

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Thiram)
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
EmS code:
F-A
S-F
Labels:
9
Marine pollutant
Special provisions / remarks
Special provisions:
Environmentally hazardous : yes

Air transport (UN RTDG/ICAO/IATA)

UN number:
3077
Shipping information
Proper shipping name and description:
Environmentally hazardous substance, solid, n.o.s.
(Thiram)
Class or division:
Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances
Packing group:
Packing group III: Substances presenting low danger
Labels:
Miscellaneous
Special provisions / remarks
Special provisions:
Packing instruction (cargo aircraft) : 956
Packing instruction (LQ) : Y956
Packing instruction (passenger aircraft): 956

Additional transport information

Additional information
Special provisions / remarks / other:
Shipping in package sizes of less than 5 L (liquids) or 5 KG (solids) may lead to a non-regulated classification.

Exposure controls / personal protection

Control parameters
Derived No Effect Level (DNEL) according to Regulation (EC) No. 1907/2006:


 









































Substance name



End Use



Exposure routes



Potential health ef
fects



Value



 



Workers



Dermal



Acute effects



10 mg/kg
bw/day



 



Workers



Inhalation



Acute effects



0.564 mg/m3



 



Workers



Dermal



Long-term systemic
effects



1.6 mg/kg
bw/day



 



Workers



Inhalation



Long-term systemic
effects



0.118 mg/m3



 


Predicted No Effect Concentration (PNEC) according to Regulation (EC) No. 1907/2006:









































Substance name



Environmental Compartment



Value



 



Fresh water



0.00046 mg/l



 



Fresh water sediment



0.047 mg/kg



 



Marine water



0.000046 mg/l



 



Marine sediment



0.0047 mg/kg



 



Soil



0.00912 mg/kg



 



Sewage treatment plant



0.0311 mg/l



 


Exposure controls
Engineering measures
Good general ventilation (typically 10 air changes per hour) should be used. Ventilation rates should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level.


 


Personal protective equipment


Eye protection: Wear safety glasses with side shields (or goggles). Face-shield Always wear eye protection when the potential for inadvertent eye contact with the product cannot be excluded.


 


Hand protection remarks: Rubber gloves Neoprene gloves The data about break through time/strength of material are standard values! The exact break through time/strength of material has to be ob tained from the producer of the protective glove.


 


Skin and body protection: Complete suit protecting against chemicals.


 


Respiratory protection: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure assessment demonstrates that exposures are within recommended exposure guidelines. Effective dust mask.


 


Protective measures: Remove respiratory and skin/eye protection only after vapours have been cleared from the area. Ensure that eye flushing systems and safety showers are located close to the working place. Use personal protective equipment as required.


 

Stability and reactivity

Reactivity: None reasonably foreseeable.


Chemical stability: Stable under normal conditions.


Possibility of hazardous reactions


Hazardous reactions: Hazardous decomposition products formed under fire conditions. Dust can form an explosive mixture in air.


Conditions to avoid: Avoid dust formation. Heat, flames and sparks.


Incompatible materials


Materials to avoid: Strong oxidizing agents Strong acids


Hazardous decomposition products


Carbon monoxide
Carbon dioxide (CO2)
Nitrogen oxides (NOx)
Sulphur oxides

Disposal considerations

Waste treatment methods


Product: Dispose of in accordance with local regulations.


Contaminated packaging:


Empty containers should be taken to an approved waste handling site for recycling or disposal.