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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Phototransformation in air

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Administrative data

Endpoint:
phototransformation in air
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Experimental result cited in the Journal of Phys Chem Reference Data and US EPA's EPIWIN database and SRC. Compatible with QSAR estimated value
Cross-reference
Reason / purpose for cross-reference:
reference to same study

Data source

Reference
Reference Type:
publication
Title:
Flash photolysis study of spectra of CH3O2 and C(CH3)O2 radicals and the kinetics of their mutual reactions with NO
Author:
Anastasi C., I.W.M. Smit and D.A. Parker
Year:
1978
Bibliographic source:
Chem. Soc. Faraday Trans. I, 74: 1693-1701

Materials and methods

Principles of method if other than guideline:
Full experimental details not available
GLP compliance:
not specified

Test material

Constituent 1
Reference substance name:
TBHP
IUPAC Name:
TBHP
Constituent 2
Chemical structure
Reference substance name:
tert-butyl hydroperoxide
EC Number:
200-915-7
EC Name:
tert-butyl hydroperoxide
Cas Number:
75-91-2
Molecular formula:
C4H10O2
IUPAC Name:
2-methylpropane-2-peroxol
Details on test material:
Test conducted on TBHP-pure; for the purposes of this dossier TBHP-pure is considered equivalent to the identity in Section 1

Study design

Light source:
not specified
Details on light source:
details not available

Results and discussion

Any other information on results incl. tables

Atmospheric OH reaction rate constant 3E-12 cm3/molecule-sec

Applicant's summary and conclusion

Conclusions:
Atmospheric OH reaction rate constant 3E-12 cm3/molecule-sec