Heavy gas oil fraction, waste plastic derived, hydrothermal conversion

Guidance on Safe Use

First-aid measures

General notes

Self-protection of the first aider.

Remove affected person from the danger area and lay down.

Do not leave affected person unattended.

In all cases of doubt, or when symptoms persist, seek medical advice.

Following inhalation

Provide fresh air.

Mouth to mouth resuscitation should be avoided. Use alternative methods, preferably with oxygen or

compressed air driven apparatus.

If breathing is irregular or stopped, immediately seek medical assistance and start first aid actions.

Following skin contact

Take off contaminated clothing.

Wash with plenty of soap and water.

If skin irritation occurs: Get medical advice/attention.

Following eye contact

Rinse cautiously with water for several minutes.

Remove contact lenses, if present and easy to do. Continue rinsing.

If eye irritation persists: Get medical advice/attention.

Following ingestion

Rinse mouth. Do not induce vomiting.

In case of unconsciousness place person in the recovery position. Never give anything by mouth.

Call a physician immediately.

Most important symptoms and effects, both acute and delayed

Death following aspiration.

Harmful if inhaled.

Indication of any immediate medical attention and special treatment needed

Symptoms may develop several hours following exposure; medical observation therefore necessary

for at least 48 hours.

Subsequent observance for pneumonia and pulmonary oedema.

Fire-fighting measures

Extinguishing media

Suitable extinguishing media

water spray, alcohol resistant foam, fire extinguishing powder, carbon dioxide (CO2)

Unsuitable extinguishing media

water jet

Special hazards arising from the substance or mixture

In case of insufficient ventilation and/or in use, may form flammable/explosive vapour-air mixture.

Solvent vapours are heavier than air and may spread along floors.

Hazardous combustion products

carbon monoxide (CO), carbon dioxide (CO2), pyrolysis products, toxic

Advice for firefighters

In case of fire and/or explosion do not breathe fumes.

Co-ordinate firefighting measures to the fire surroundings.

Do not allow firefighting water to enter drains or water courses.

Collect contaminated firefighting water separately.

Fight fire with normal precautions from a reasonable distance.

Special protective equipment for firefighters

use suitable breathing apparatus, chemical protection suit

Accidental release measures

Personal precautions, protective equipment and emergency procedures

For non-emergency personnel

Remove persons to safety.

Ventilate affected area.

Do not get in eyes, on skin, or on clothing.

Do not breathe gas/vapour/spray.

Wearing of suitable protective equipment (including personal protective equipment referred to under

Section 8 of the safety data sheet) to prevent any contamination of skin, eyes and personal clothing.

For emergency responders

Wear breathing apparatus if exposed to vapours/dust/spray/gases.

Environmental precautions

Keep away from drains, surface and ground water.

Retain contaminated washing water and dispose of it.

If substance has entered a water course or sewer, inform the responsible authority.

Methods and material for containment and cleaning up

Advice on how to clean up a spill

Collect spillage.

Absorbent material (e.g. sand, diatomaceous earth, acid binder, universal binder, sawdust, etc.).

Remove from the water surface (e.g. skimming, sucking).

Appropriate containment techniques

Use of adsorbent materials.

Other information relating to spills and releases

Place in appropriate containers for disposal.

Ventilate affected area.

Keep away from sources of ignition - No smoking.

Handling and storage

Precautions for safe handling

Provision of sufficient ventilation.

Avoid contact with skin and eyes.

Do not breathe vapour/spray.

Measures to prevent fire as well as aerosol and dust generation

Use local and general ventilation.

Keep away from sources of ignition - No smoking.

Take precautionary measures against static discharge.

Measures to protect the environment

Avoid release to the environment.

Advice on general occupational hygiene

Do not eat, drink and smoke in work areas.

Wash hands after use.

Preventive skin protection (barrier creams/ointments) is recommended.

Remove contaminated clothing and protective equipment before entering eating areas.

Take off immediately all contaminated clothing and wash it before reuse.

Conditions for safe storage, including any incompatibilities

Protect against external exposure, such as

heat

Consideration of other advice

Keep away from food, drink and animal feeding stuffs.

Ventilation requirements

Keep any substance that emits harmful vapours or gases in a place that allows these to be permanently

extracted.

Provision of sufficient ventilation.

Specific designs for storage rooms or vessels

Keep container tightly closed.

Keep in a cool, well-ventilated place.

Packaging compatibilities

Keep only in original container.

Additional information

This substance is handled under Strictly Controlled Conditions in accordance with REACH regulation Article 18 for transported isolated intermediates and, in case the substance is transported to other sites for further processing, the substance should be handled at these sites under the Strictly Controlled Conditions as specified in REACH regulation Article 18(4).

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:

3082

Shipping information

Proper shipping name and description:

UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (Heavy gas oil fraction, waste plastic derived, hydrothermal conversionrothermal conversion), 9, III, (-)

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

9, fish and tree

Special provisions / remarks

Special provisions:

Special provisions (SP) 274, 335, 375, 601

Remarks:

Environmental hazards Yes (hazardous to the aquatic environment)
Excepted quantities (EQ) E1
Limited quantities (LQ) 5 L
Transport category (TC) 3
Tunnel restriction code (TRC) -
Hazard identification No 90
Emergency Action Code 3Z

Inland waterway transport (UN RTDG/ADN(R))

UN number:

3082

Shipping information

Proper shipping name and description:

UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (Heavy gas oil fraction, waste plastic derived, hydrothermal conversionrothermal conversion), 9, III, (-)

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

9, fish and tree

Special provisions / remarks

Special provisions:

Special provisions (SP) 274, 335, 375, 601

Remarks:

Environmental hazards Yes (hazardous to the aquatic environment)
Excepted quantities (EQ) E1
Limited quantities (LQ) 5 L
Transport category (TC) 3
Tunnel restriction code (TRC) -
Hazard identification No 90
Emergency Action Code 3Z

Marine transport (UN RTDG/IMDG)

UN number:

3082

Shipping information

Proper shipping name and description:

UN3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., (Heavy gas oil fraction, waste plastic derived, hydrothermal conversionrothermal conversion), 9, III

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

EmS code:

F-A

S-F

Labels:

9, fish and tree

Marine pollutant

Special provisions / remarks

Special provisions:

Special provisions (SP) 274, 335, 969

Remarks:

Excepted quantities (EQ) E1
Limited quantities (LQ) 5 L
Stowage category A

Air transport (UN RTDG/ICAO/IATA)

UN number:

3082

Shipping information

Proper shipping name and description:

UN3082, Environmentally hazardous substance, liquid, n.o.s., (Heavy gas oil fraction, waste plastic derived, hydrothermal conversionrothermal conversion), 9, III

Class or division:

Class 9: Miscellaneous dangerous substances and articles, including environmentally hazardous substances

Packing group:

Packing group III: Substances presenting low danger

Labels:

9, fish and tree

Special provisions / remarks

Special provisions:

Special provisions (SP) A97, A158, A197
Excepted quantities (EQ) E1
Limited quantities (LQ) 30 kg

Remarks:

Excepted quantities (EQ) E1
Limited quantities (LQ) 30 kg

SpecialProvisions

Exposure controls / personal protection

Exposure controls

Appropriate engineering controls

General ventilation.

Individual protection measures (personal protective equipment)

Chemical protective clothing.

Eye/face protection

Wear eye/face protection.

Hand protection

Wear suitable gloves.

Check leak-tightness/impermeability prior to use.

In the case of wanting to use the gloves again, clean them before taking off and air them well.

For special purposes, it is recommended to check the resistance to chemicals of the protective gloves

mentioned above together with the supplier of these gloves.

Respiratory protection

In case of inadequate ventilation wear respiratory protection.

Environmental exposure controls

Use appropriate container to avoid environmental contamination.

Keep away from drains, surface and ground water.

Stability and reactivity

Reactivity

If heated.

Risk of ignition.

Chemical stability

The material is stable under normal ambient and anticipated storage and handling conditions of temperature

and pressure.

Possibility of hazardous reactions

No known hazardous reactions.

Conditions to avoid

Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.

Incompatible materials

oxidisers

Hazardous decomposition products

Reasonably anticipated hazardous decomposition products produced as a result of use, storage, spill

and heating are not known.

Disposal considerations

Waste treatment methods

This material and its container must be disposed of as hazardous waste.

Sewage disposal-relevant information

Do not empty into drains.

Waste treatment of containers/packagings

Completely emptied packages can be recycled.

Handle contaminated packages in the same way as the substance itself.

Remarks

Please consider the relevant national or regional provisions.