Registration Dossier
Registration Dossier
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EC number: 224-246-5 | CAS number: 4264-83-9
Flammability
Administrative data
- Endpoint:
- self-heating substances / mixtures
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- 15 - 16 February 2018
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- guideline study
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 018
Materials and methods
Test guidelineopen allclose all
- Qualifier:
- according to guideline
- Guideline:
- other: UN Recommendations on the TRANSPORT OF DANGEROUS GOODS: Manual of Tests and Criteria
- Version / remarks:
- Rev. 6 (2015)
- Deviations:
- no
- Qualifier:
- according to guideline
- Guideline:
- other: VDI 2263 Sheet 1 Grewer Oven
- Version / remarks:
- 1990
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
Test material
- Reference substance name:
- Disodium 4-nitrophenyl phosphate
- EC Number:
- 224-246-5
- EC Name:
- Disodium 4-nitrophenyl phosphate
- Cas Number:
- 4264-83-9
- Molecular formula:
- C6H4NO6P.2Na
- IUPAC Name:
- disodium 4-nitrophenyl phosphate
- Reference substance name:
- Water
- EC Number:
- 231-791-2
- EC Name:
- Water
- Cas Number:
- 7732-18-5
- Molecular formula:
- H2O
- IUPAC Name:
- Oxidane
- Test material form:
- solid
- Details on test material:
- Batch Nr: 11674900
Storage: 2-8°C.
Constituent 1
impurity 1
Results and discussion
Self-heating substances / mixtures
- Key result
- Test procedure:
- other: Grewer oven
- Remarks:
- pure test item
- Max. temp. reached:
- 485
- Result:
- other: An exothermic process was observed starting at a temperature of approx. 225 °C that led to a maximum temperature of approx. 485 °C.
Any other information on results incl. tables
In the investigation of self-ignition in the Grewer Oven for the pure test item an endothermic effect was detected in the temperature range of 50 – 170 °C. An exothermic process was observed starting at a temperature of approx. 225 °C that led to a maximum temperature of approx. 485 °C (corresponding oven temperature 320 °C). After the measurement a grey residue remained in the wire basket.
Applicant's summary and conclusion
- Interpretation of results:
- not classified based on GHS criteria
- Conclusions:
- The pure test item 4-Nitrophenyl phosphate disodium salt (CAS no. 4264-83-9) indicated a self-heating at atmospheric pressure starting at a temperature of approx. 225 °C that led to a maximum temperature of approx. 485 °C (corresponding oven temperature 320 °C).
On the basis of the results of the tests on the self-ignition in the Grewer Oven, the test item is classified as follows:
UN Transport Regulation: The test item is not classified as self-heating substance in class 4, division 4.2 according to the UN Transport Regulation.
GHS / CLP Regulation EC 1272/2008 Annex 1: 2.11: The test item is not classified as self-heating substance according to GHS/CLP Regulation EC 1272/2008 Annex 1: 2.11, respectively. - Executive summary:
The pure test item 4-Nitrophenyl phosphate disodium salt (CAS no. 4264-83-9) indicated a self-heating at atmospheric pressure starting at a temperature of approx. 225 °C that led to a maximum temperature of approx. 485 °C (corresponding oven temperature 320 °C).
On the basis of the results of the tests on the self-ignition in the Grewer Oven, the test item is classified as follows:
UN Transport Regulation: The test item is not classified as self-heating substance in class 4, division 4.2 according to the UN Transport Regulation.
GHS / CLP Regulation EC 1272/2008 Annex 1: 2.11: The test item is not classified as self-heating substance according to GHS/CLP Regulation EC 1272/2008 Annex 1: 2.11, respectively.
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