Registration Dossier

Administrative data

First-aid measures

Description of first aid measures
If inhaled : fresh air. Call in physician.
In case of skin contact : Take off immediately all contaminated clothing. Rinse skin with water/ shower.
In case of eye contact : rinse out with plenty of water. Remove contact lenses.
If swallowed : immediately make victim drink water (two glasses at most). Consult a physician.

Most important symptoms and effects, both acute and delayed
Symptoms :somnolence, Drowsiness, Nausea, Vomiting, CNS disorders, narcosis

Indication of any immediate medical attention and special treatment needed
Treatment : No information available.

Fire-fighting measures

Extinguishing media
Suitable extinguishing media : Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media : For this substance/mixture no limitations of extinguishing agents are given.

Special hazards arising from the substance or mixture
Specific hazards during firefighting : Combustible.
Vapours are heavier than air and may spread along floors. Forms explosive mixtures with air at elevated temperatures. Development of hazardous combustion gases or vapours possible in the event of fire.
Fire may cause evolution of: Sulphur oxides Hydrogen fluoride

Advice for firefighters
Special protective equipment for firefighters : Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further information : Cool closed containers exposed to fire with water spray. Suppress (knock down) gases/vapours/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Personal precautions : Advice for non-emergency personnel: Do not breathe vapours, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert.

Environmental precautions
Environmental precautions : Do not flush into surface water or sanitary sewer system. Risk of explosion.

Methods and material for containment and cleaning up
Methods for cleaning up : Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions. Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area.

Handling and storage

Precautions for safe handling
Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms. Do not inhale substance/mixture.Avoid generation of vapours/aerosols. Observe label precautions.
Advice on protection against fire and explosion : Keep away from open flames, hot surfaces and sources of ignition. Take precautionary measures against static discharge.
Hygiene measures : Change contaminated clothing. Wash hands after working with substance.

Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers : Store in original container.
Further information on storage conditions : Keep container tightly closed in a dry and well-ventilated place. Keep away from heat and sources of ignition. Protected from light.
Recommended storage temperature : Recommended storage temperature see product label.

Transport information

Land transport (ADR/RID)

UN number:
UN 3092
Proper shipping name and description:
1-Methoxy-2-propanol solution
Chemical name:
1-Methoxy-2-propanol solution
Language:
English
Class:
3
Classification code:
III
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3092
Proper shipping name and description:
1-METHOXY-2-PROPANOL SOLUTION
Class:
3
Classification code:
III
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3092
Proper shipping name and description:
1-METHOXY-2-PROPANOL SOLUTION
Class:
3
Packaging group:
III
EmS code:
F-E, S-D
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 3092
Proper shipping name and description:
1-Methoxy-2-propanol solution
Class:
3
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls
Engineering measures
Technical measures and appropriate working operations should be given priority over the use of personal protective equipment.

Personal protective equipment
Protective clothing needs to be selected specifically for the workplace, depending on concentrations and quantities of the hazardous substances handled and must meet the specifications of a standard EN/ISO/DIN. The chemical resistance of the protective equipment should be enquired at the respective supplier.

Eye protection: Safety glasses

Hand protection : splash contact
Glove material : Nitrile rubber
Glove thickness : 0,4 mm
Break through time : 10 min

The protective gloves to be used must comply with the specifications of EC Directive 89/686/EEC and the related standard EN374, for example:KCL 730 Camatril® -Velours(splash contact);.
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de).

Protective measures : Flame retardant antistatic protective clothing.
Respiratory protection : required when vapours/aerosols are generated.
Recommended Filter type: ABEK-filter

The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.

Environmental exposure controls
General advice : Do not flush into surface water or sanitary sewer system. Risk of explosion.

Stability and reactivity

Reactivity
Vapour/air-mixtures are explosive at intense warming.
Formation of peroxides possible.

Chemical stability
Sensitivity to light Sensitive to air.

Possibility of hazardous reactions
Hazardous reactions : Generates dangerous gases or fumes in contact with: hydrides (generation of hydrogen) Violent reactions possible with: Strong oxidizing agents acid halides Acid anhydrides Acid chlorides

Conditions to avoid
Conditions to avoid : Heating.

Incompatible materials
Materials to avoid :no information available

Hazardous decomposition products
Peroxides

Disposal considerations

Waste treatment methods
Product : See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.