Registration Dossier

Administrative data

First-aid measures

General advice: Take off all contaminated clothing immediately.

If inhaled: Take the person into the fresh air and keep him warm, let him rest; if there is difficulty in breathing, medical advice is required.

In case of skin contact: In case of skin contact wash affected areas thoroughly with soap and plenty of water. Consult a doctor in the event of a skin reaction.

In case of eye contact: Hold the eyes open and rinse with preferably lukewarm water for a sufficiently long period of time (at least 10 minutes). Contact an ophthalmologist.

If swallowed: DO NOT induce the patient to vomit, medical advice is required.

Fire-fighting measures

Suitable extinguishing media: Carbon dioxide (CO2), Foam, extinguishing powder, in cases of larger fires, water spray should be used.

Unsuitable extinguishing media: High volume water jet

Special hazards arising from the substance or mixture:
Burning releases carbon monoxide, carbon dioxide, oxides of nitrogen, isocyanate vapors and traces of hydrogen cyanide. In the event of fire and/or explosion do not breathe fumes.

Advice for fire-fighters:
During fire-fighting respirator with independent air-supply and airtight garment is required.
Do not allow contaminated extinguishing water to enter the soil, ground-water or surface waters.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Put on protective equipment (see section 8). Keep away from sources of ignition. Ensure adequate ventilation/exhaust extraction. Keep unauthorized persons away.

Environment related measures
Do not allow to escape into waterways, wastewater or soil.

Methods and material for containment and cleaning up
Remove mechanically; cover the remainder with wet, absorbent material (e.g. sawdust, chemical binder based on calcium silicate hydrate, sand). After approx. one hour transfer to waste container and do not seal (evolution of CO2!). Keep damp in a safe ventilated area for several days.

Handling and storage

Precautions for safe handling
Provide sufficient air exchange and/or exhaust in work rooms. Exhaust ventilation necessary if product is sprayed.

The threshold limit values must be monitored. In all areas where isocyanate aerosols and/or vapor concentrations are produced in elevated concentrations, exhaust ventilation must be provided in such a way that the workplace exposure limits (WEL) is not exceeded. The air should be drawn away from the personnel handling the product.

The personal protective measures must be observed. The precautions required in the handling of isocyanates must be taken. Avoid contact with skin and eyes and the inhalation of vapor.

Keep away from foodstuffs, drinks and tobacco. Wash hands before breaks and at end of work and use skin-protecting ointment. Keep working clothes separately. Take off all contaminated clothing immediately.

Conditions for safe storage, including any incompatibilities
Keep container dry and tightly closed in a cool and well ventilated place.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Respiratory protection:
Respiratory protection required in insufficiently ventilated working areas and during spraying. An air-fed mask, or for short periods of work, a combination of charcoal filter and particulate filter is recommended.
Further recommendations regarding respiratory protection can be found in the individual exposure scenarios in the appendix.
In case of hypersensitivity of the respiratory tract and skin (e.g. asthmatics and those who suffer from chronic bronchitis and chronic skin complaint) it is inadvisable to work with the product.
Hand protection:
Suitable materials for safety gloves; EN 374:
Butyl rubber - IIR: thickness >=0,5mm; breakthrough time >=480min.
Recommendation: contaminated gloves should be disposed of.
Eye protection:
Wear eye/face protection.
Skin and body protection:
Wear suitable protective clothing.

Stability and reactivity

Possibility of hazardous reactions: Exothermic reaction with amines and alcohols; reacts slowly with water forming CO2, in closed containers risk of bursting owing to increase of pressure.
Hazardous decomposition products: On drying of the coating / hardening release of neutralising agent.

Disposal considerations

Dispose in accordance with applicable international, national and local laws, ordinances and statutes. For disposal within the EC, the appropriate code according to the European Waste Catalogue (EWC) should be used.
Waste treatment methods
After final product withdrawal, all residues must be removed from containers (drip-free, powder-free or paste-free). Once the product residues adhering to the walls of the containers have been rendered harmless, the product and hazard labels must be invalidated. These containers can be returned for recycling to the appropriate centres set up within the framework of the existing take-back scheme of the chemical industry. Containers must be recycled in compliance with national legislation and environmental regulations.
None disposal into waste water.