Registration Dossier

Administrative data

First-aid measures

After inhalation:
Move to fresh air, keep the victim laying down and restful. If breathing has stopped, give artificial respiration. Administer oxygen in case of breathing difficulties. Seek medical advice and clearly identify substance.

After contact with the skin:
Wash with plenty of water or soap and water; immediately remove all contaminated clothing. In cases of sickness seek medical advice (show label if possible).

After contact with the eyes:
Rinse immediately with plenty of water for 10-15 minutes and seek medical advice.

After swallowing:
If conscious, give several small portions of water to drink. Do not induce vomiting. Seek medical advice immediately and produce the label or packaging.

Advice for the physician:
In case of contact with water material splits off (also in gastrointestinal tract) methanol in larger amounts; therefore consider poisoning on methanol and also observe known period of latency of several days!

Fire-fighting measures

Suitable extinguishing media:
water mist, extinguishing powder, alcohol-resistant foam, carbon dioxide, sand.

Extinguishing media which must not be used for safety reasons:
water spray, water jet.

Special exposure hazards arising from the substance or preparation itself, combustion products, resulting gases:
Hazardous combustion products: hydrogen chloride

Special protective equipment for fire fighting:
Use respiratory protection independent of recirculated air.

Accidental release measures

Personal precautions:
Wear personal protection equipment (see section 8). Keep unprotected persons away. Avoid contact with eyes and skin. Avoid inhaling mists and vapours. If material is released indicate risk of slipping.

Environmental precautions:
Prevent material from entering surface waters, drains or sewers and soil. Contain any fluid that runs out using suitable material (e.g. earth). Retain contaminated water/extinguishing water. Dispose of in prescribed marked containers.

Methods for cleaning up:
Do not flush away with water. For small amounts: Absorb with a liquid binding material such as diatomaceous earth and dispose of according to local/state/federal regulations. Contain larger amounts and pump up into suitable containers. Clean any slippery coating that remains using a detergent / soap solution or another biodegradable cleaner. Exhaust vapours.

Further information:
Eliminate all sources of ignition.

Handling and storage

General information:
Avoid exposure by technical measures or personal protective equipment.

Handling:
Precautions for safe handling:
Ensure adequate ventilation. Keep away from incompatible substances in accordance with section 10.2. Spilled substance increases risk of slipping.

Precautions against fire and explosion:
Product can separate methanol. Vapours may form in closed rooms with air mixtures, leading to explosion in the presence of sources of ignition, even in empty, uncleaned vessels. Keep away from sources of ignition and do not smoke. Take precautionary measures against electrostatic charging. Cool endangered containers with water.

Storage:
Conditions for storage rooms and vessels:
Unsuitable material for storage containers, casks and pipelines: steel , aluminum , synthetics

Advice for storage of incompatible materials:
not applicable

Further information for storage:
Protect against moisture. Keep container tightly closed and store in a cool, well ventilated place.

Transport information

Land transport (ADR/RID)

UN number:
1993
Proper shipping name and description:
Entzündbarer flüssiger Stoff, n.a.g.
Chemical name:
((Chlormethyl)trimethoxysilan)
Language:
German
Class:
3
Classification code:
F1
Packaging group:
III
Labels:
entzündbare Flüssigkeit/3
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
1993
Proper shipping name and description:
Entzündbarer flüssiger Stoff, n.a.g.
Chemical name:
((Chlormethyl)trimethoxysilan)
Language:
German
Class:
3
Classification code:
F1
Packaging group:
III
Labels:
entzündbare Flüssigkeit/3
Remarksopen allclose all

Marine transport (IMDG)

UN number:
1993
Proper shipping name and description:
Flammable liquid, n.o.s.
Chemical name:
((Chloromethyl)trimethoxysilane)
Class:
3
Packaging group:
III
Labels:
flammable liquid /3
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
1993
Proper shipping name and description:
Flammable liquid, n.o.s.
Chemical name:
((Chloromethyl)trimethoxysilane)
Class:
3
Packaging group:
III
Labels:
flammable liquid /3
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

General protection and hygiene measures:
Avoid contact with eyes and skin. Do not inhale gases/vapours/aerosols. Do not eat, drink or smoke when handling.

Personal protection equipment:
Respiratory protection:
In case of long or strong exposure: gas mask filter ABEK .

Hand protection:
Protective gloves made of butyl rubber or PVC Gloves suitable for up to 60 minutes' use.

Eye protection:
tight fitting protective goggles.

Skin protection:
protective clothing.

Exposure to the environment limited and controlled:
Prevent material from entering surface waters and soil.

Stability and reactivity

If stored and handled in accordance with standard industrial practices no hazardous reactions are known.
Conditions to avoid:
none known .

Materials to avoid:
Reacts with water, basic substances or acids. Reaction causes the formation of methanol.

Hazardous decomposition products:
If stored and handled in accordance with standard industrial practices and local regulations where applicable: none known. Under the effect of humidity, water and protic agents methanol.

Disposal considerations

Material
Recommendation:
Dispose off according to regulations by incineration in a special waste incinerator. Observe local/state/federal regulations.

Uncleaned packaging:
Recommendation:
Completely discharge containers (no tear drops, no powder rest, scraped carefully). Containers may be recycled or re-used. Observe local/state/federal regulations.