Registration Dossier
Registration Dossier
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EC number: 608-895-5 | CAS number: 33582-68-2
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
General:
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance.
Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Description of first aid measures:
Inhalation:
Inhalation is possible if aerosols, mists, dusts, or smoke form.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin Contact:
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
In case of persistent discomfort: Consult an ophthalmologist.
Ingestion:
Rinse mouth.
Immediately give large quantities of water to drink.
Obtain medical attention.
Most important symptoms and effects, both acute and delayed:
None known.
Indication of any immediate medical attention and special treatment needed:
Hazards: Other dangerous properties can not be excluded.
Treatment:
This product has not been completely analyzed yet and all health hazards might not be known.
Pay attention to self-protection.
Remove victims from hazardous area.
Immediately remove soiled or soaked clothing and remove it to a safe distance.
Keep victim warm, in a stabilized position and covered.
Do not leave victims unattended.
If the casualty is unconscious: Place the victim in the recovery position.
Description of first aid measures:
Inhalation:
Inhalation is possible if aerosols, mists, dusts, or smoke form.
Move victims into fresh air.
With labored breathing: Provide with oxygen.
Consult a doctor.
If the casualty is not breathing: Perform mouth-to-mouth resuscitation, notify emergency physician immediately.
Skin Contact:
Wash off affected area immediately with plenty of water for at least 15 minutes.
If symptoms persist, consult a physician for treatment.
Eye contact:
With eye held open, thoroughly rinse immediately with plenty of water for at least 10 minutes.
In case of persistent discomfort: Consult an ophthalmologist.
Ingestion:
Rinse mouth.
Immediately give large quantities of water to drink.
Obtain medical attention.
Most important symptoms and effects, both acute and delayed:
None known.
Indication of any immediate medical attention and special treatment needed:
Hazards: Other dangerous properties can not be excluded.
Treatment:
This product has not been completely analyzed yet and all health hazards might not be known.
Fire-fighting measures
Extinguishing media:
Suitable extinguishing media:
- water
- water vapour
- extinguishing powder
- extinguishing foam.
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
In the case of fire, the following hazardous smoke fumes may be produced:
- carbon monoxide
- carbon dioxide
- sulphur oxides.
Under certain fire conditions, traces of other toxic products may occur.
Advice for fire fighters:
Special fire fighting procedures:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
Use water spray to cool unopened containers.
Fire residues should be disposed of in accordance with the regulations.
Pay attention to self-protection.
Keep out unprotected persons.
Special protective equipment for fire-fighters:
In case of fire:
Full protective suit and wear a self contained respiratory apparatus.
Suitable extinguishing media:
- water
- water vapour
- extinguishing powder
- extinguishing foam.
Unsuitable extinguishing media:
Do not use a solid water stream as it may scatter and spread fire.
Special hazards arising from the substance or mixture:
In the case of fire, the following hazardous smoke fumes may be produced:
- carbon monoxide
- carbon dioxide
- sulphur oxides.
Under certain fire conditions, traces of other toxic products may occur.
Advice for fire fighters:
Special fire fighting procedures:
Contaminated extinguishing water must be treated at a suitable disposal plant in accordance with waste management laws.
Water used to extinguish fire should not enter drainage systems, soil or stretches of water.
In case of fire, remove the endangered containers and bring to a safe place, if this can be done safely.
Use water spray to cool unopened containers.
Fire residues should be disposed of in accordance with the regulations.
Pay attention to self-protection.
Keep out unprotected persons.
Special protective equipment for fire-fighters:
In case of fire:
Full protective suit and wear a self contained respiratory apparatus.
Accidental release measures
Personal precautions, protective equipment and emergency procedures:
Keep unauthorized personnel away.
Environmental Precautions:
Observe regulations on prevention of water pollution (check, dam up, cover up).
Do not allow entrance in sewage water, soil, stretches of water, drainage systems, surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Pack and label wastes like the pure substance.
Do not detach label from the delivery containers prior to disposal.
Disposal according to local authority regulations.
Reference to other sections:
Wear personal protective equipment; see section Exposure controls/personal protection.
Keep unauthorized personnel away.
Environmental Precautions:
Observe regulations on prevention of water pollution (check, dam up, cover up).
Do not allow entrance in sewage water, soil, stretches of water, drainage systems, surface water.
If the product contaminates rivers and lakes or drains inform respective authorities.
Methods and material for containment and cleaning up:
Pack and label wastes like the pure substance.
Do not detach label from the delivery containers prior to disposal.
Disposal according to local authority regulations.
Reference to other sections:
Wear personal protective equipment; see section Exposure controls/personal protection.
Handling and storage
Precautions for safe handling:
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Ensure that apparatus and pipelines are free from leaks.
Do not ventilate into the open.
Dedicated loading/unloading stations required.
Take precautionary measures against static discharges.
Empty, clean and dry system / system components completely before maintenance and repair work is done.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
All precautionary measures indicated have to be observed.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Regular safety training is a must.
The personal protective equipment used must meet the requirements of Regulation (EU) 2016/425 and amendments (CE certification).
It should be defined in the work place in the form of a risk analysis according to Regulation (EU) 2016/425 and amendments.
Conditions for safe storage, including any incompatibilities:
Normal measures for preventive fire protection.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
Observe prohibition against storing together.
In the event of internal transportation, already-opened containers are to be kept closed in order to avoid spillage.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.
Protect from sunlight, warmth and heat.
VDI 2263 "Dust fires and dust explosions; dangers, evaluation, preventive measures."
Storage Class:
4.1 B: Flammable Solids.
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Ensure that apparatus and pipelines are free from leaks.
Do not ventilate into the open.
Dedicated loading/unloading stations required.
Take precautionary measures against static discharges.
Empty, clean and dry system / system components completely before maintenance and repair work is done.
Written approval necessary in case of non-routine jobs, e.g. maintenance activities.
All precautionary measures indicated have to be observed.
Risk assessment and risk monitoring of all work places required.
Health, Safety and Emergency Management System recommended.
Regular safety training is a must.
The personal protective equipment used must meet the requirements of Regulation (EU) 2016/425 and amendments (CE certification).
It should be defined in the work place in the form of a risk analysis according to Regulation (EU) 2016/425 and amendments.
Conditions for safe storage, including any incompatibilities:
Normal measures for preventive fire protection.
Ensure there are sufficient retaining facilities for water used to extinguish fire.
Store in the original receptacle, keeping this tightly sealed, under cool and dry conditions.
Observe prohibition against storing together.
In the event of internal transportation, already-opened containers are to be kept closed in order to avoid spillage.
In order to ensure due transportation, make certain that stacks are of the correct height, containers are securely fastened so as not to fall off, and labelled according to the regulations.
Protect from sunlight, warmth and heat.
VDI 2263 "Dust fires and dust explosions; dangers, evaluation, preventive measures."
Storage Class:
4.1 B: Flammable Solids.
Transport information
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Marine transport (UN RTDG/IMDG)
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Additional transport information
Additional information
- Special provisions / remarks / other:
- Transport prohibited.
Exposure controls / personal protection
Exposure controls:
Appropriate Engineering Controls:
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).
In case of dissolved solids: Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
All precautionary measures indicated have to be observed.
Do not add wastewater to a biological wastewater treatment plant.
Do not lead exhaust air back to workplace areas unfiltered.
Exhaust filter or scrubber.
Exhaust air filter (HEPA-filter).
Earthing of equipment.
Provide for installation of emergency shower and eye bath.
Individual protection measures, such as personal protective equipment:
Eye/face protection:
Safety glasses with side-shields conforming to EN166
or
Accidental release measures close-fitting protective goggles (e.g. closed goggles).
Hand Protection:
Material: Nitrile
Glove thickness: 0.11 mm
Guideline: DIN EN 374
Material: Nitrile/Chloroprene
Glove thickness: 0.65 mm
Guideline: DIN EN 374
Additional Information: Accidental release measures.
Skin and Body Protection:
Suitable protective clothing - Use disposable clothing if appropriate.
Respiratory Protection:
Accidental release measures use respiratory equipment with suitable filter (filter type P3) or wear a self contained respiratory apparatus.
Note time limit for wearing respiratory protective equipment.
Hygiene measures:
Do not eat, drink, smoke, or sniff while at work.
Wash your hands and/or face before breaks and before termination of work.
Take off contaminated clothing and wash it before reuse.
Preventive skin protection is recommended.
Use barrier cream regularly.
Environmental Controls:
In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease emissions to acceptable values.
Appropriate Engineering Controls:
The substance must be handled under strictly controlled conditions in accordance with Article 17/18 of the REACH regulation.
Decant and handle product in separate areas only, e.g. use glove boxes, cabinets with differential pressure switch etc.
Ensure that dust-handling systems (such as exhaust ducts, dust collectors, vessels, and processing equipment) are designed in a manner to prevent the escape of dust into the work area (i.e., there is no leakage from the equipment).
In case of dissolved solids: Minimization of emissions by means of suitable technical measures such as flanges and valves with low leakage rates, recirculation of vapours.
All precautionary measures indicated have to be observed.
Do not add wastewater to a biological wastewater treatment plant.
Do not lead exhaust air back to workplace areas unfiltered.
Exhaust filter or scrubber.
Exhaust air filter (HEPA-filter).
Earthing of equipment.
Provide for installation of emergency shower and eye bath.
Individual protection measures, such as personal protective equipment:
Eye/face protection:
Safety glasses with side-shields conforming to EN166
or
Accidental release measures close-fitting protective goggles (e.g. closed goggles).
Hand Protection:
Material: Nitrile
Glove thickness: 0.11 mm
Guideline: DIN EN 374
Material: Nitrile/Chloroprene
Glove thickness: 0.65 mm
Guideline: DIN EN 374
Additional Information: Accidental release measures.
Skin and Body Protection:
Suitable protective clothing - Use disposable clothing if appropriate.
Respiratory Protection:
Accidental release measures use respiratory equipment with suitable filter (filter type P3) or wear a self contained respiratory apparatus.
Note time limit for wearing respiratory protective equipment.
Hygiene measures:
Do not eat, drink, smoke, or sniff while at work.
Wash your hands and/or face before breaks and before termination of work.
Take off contaminated clothing and wash it before reuse.
Preventive skin protection is recommended.
Use barrier cream regularly.
Environmental Controls:
In some cases, exhaust air scrubbers, filters or technical changes to the processing plant will be required in order to decrease emissions to acceptable values.
Stability and reactivity
Reactivity: No further information available
Chemical Stability: No further information available
Possibility of hazardous reactions: No further information available
Conditions to avoid: No further information available
Incompatible Materials: No further information available
Hazardous Decomposition Products: No further information available
Chemical Stability: No further information available
Possibility of hazardous reactions: No further information available
Conditions to avoid: No further information available
Incompatible Materials: No further information available
Hazardous Decomposition Products: No further information available
Disposal considerations
General information:
No data available.
Disposal methods:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Do not add wastewater to a biological wastewater treatment plant.
Bring used exhaust air filter for incineration.
Disposal according to local authority regulations.
Contaminated Packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
No data available.
Disposal methods:
The waste key number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the disposal firm / producing firm / official authority.
Strictly controlled conditions during disposal or treatment to air, wastewater and waste.
Do not add wastewater to a biological wastewater treatment plant.
Bring used exhaust air filter for incineration.
Disposal according to local authority regulations.
Contaminated Packaging:
Do not reuse empty containers and dispose of in accordance with the regulations issued by the appropriate local authorities.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
