Registration Dossier
Registration Dossier
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EC number: 238-947-9 | CAS number: 14874-82-9
Flammability
Administrative data
Link to relevant study record(s)
- Endpoint:
- flammable solids
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Reliability:
- 2 (reliable with restrictions)
- Rationale for reliability incl. deficiencies:
- guideline study
- Qualifier:
- according to guideline
- Guideline:
- UN Manual of Tests and Criteria: Test N.1 (Test method for readily combustible solids)
- GLP compliance:
- no
- Test procedure:
- burning rate test with wetted zone
- Burning time:
- >= 4.8 - <= 5.8 s
- Remarks on result:
- flame passes the wetted zone
- Test procedure:
- burning rate test: preliminary screening test
- Burning time:
- 11.8 s
- Remarks on result:
- other:
- Remarks:
- The burning time for a measuring length of 200 mm
- Interpretation of results:
- Category 1 (flammable solids) based on GHS criteria
- Conclusions:
- The substance dicarbonyl(pentane-2,4-dionato-O,O')rhodium is classified under Division 4.1 "Flammable Solids", packing group II of the UN Recommendation on the Transport of Dangerous Goods and is classified in Hazard Class "Flammable Solids", category 1 according to the criteria specified in Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation).
- Executive summary:
This is a non-GLP study following UN method N1 and is considered suitable for assessment as the key study for this endpoint.
The substance dicarbonyl(pentane-2,4 -dionato-O,O')rhodium fulfils the criteria of Division 4.1 "Flammable Solids", packing group II of the UN Recommendations on the Transport of Dangerous Goods, because the burning time along the 100 mm powder train was less than 45 s and the flame passed the wetted zone. On the basis of the test results and according to the criteria specified in the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation) this substance is classified to the Hazard Class "Flammable Solids", category 1 according to the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation).
Reference
Burning rate test results for (Acetylacetonato) dicarbonyle Rhodium (I):
| Description of burning behaviour flames/glow/ashes | Burning time for a measureing section of 100 mm of length | |||||
| Test 1 | Test 2 | Test 3 | Test 4 | Test 5 | Test 6 | |
| The substance could be ignitd and a fast burning was observed | 4.8 s | 5.0 s | 5.4 s | 5.8 s | 5.4 s | 5.0 s |
| Does the wetted zone stop the propagation of the flame for at least 4 min? | No | No | No | No | No | No |
Description of key information
Dicarbonyl(pentane-2,4-dionato-O,O')rhodium is classified as a flammable substance under Division 4.1 "Flammable Solids", packing group II of the UN Recommendations on the Transport of Dangerous Goods and is classified to the Hazard Class "Flammable Solids", category 1 according to the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation).
Key value for chemical safety assessment
- Flammability:
- flammable
Additional information
Michael-Schulz (2012) is a non-GLP study following UN method N1 and is considered reliable and suitable for use as the key study for this endpoint. The substance dicarbonyl(pentane,2,4 -dionato-O,O')rhodium fulfils the criteria of Division 4.1 "Flammable Solids", packing group II of the UN Recommendations on the Transport of Dangerous Goods, because the burning time along the 100 mm powder train is less than 45 s and the flame passes the wetted zone. On the basis of the test results and according to the criteria specified in the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation) this substance is classified to the Hazard Class "Flammable Solids", category 1 according to the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation).
Justification for classification or non-classification
The substance dicarbonyl(pentane,2,4 -dionato-O,O')rhodium fulfils the criteria of Division 4.1 "Flammable Solids", packing group II of the UN Recommendations on the Transport of Dangerous Goods, because the burning time along the 100 mm powder train is less than 45 s and the flame passes the wetted zone. On the basis of the test results and according to the criteria specified in the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation) this substance is classified to the Hazard Class "Flammable Solids", category 1 according to the Regulation (EC) No 1272/2008 (CLP-/GHS-Regulation).
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