Registration Dossier
Registration Dossier
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EC number: 224-518-3 | CAS number: 4394-85-8
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Remove contaminated clothing.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Wash thoroughly with soap and water
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open.
On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.
Symptoms:Information, i.e. additional information on symptoms and effects may be included in the GHS labeling phrases available in Section 2 and in the Toxicological assessments available in Section 11.
Indication of any immediate medical attention and special treatment needed
Treatment:Treat according to symptoms (decontamination, vital functions), no known specific antidote.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media:
water spray, dry powder, carbon dioxide
Special hazards arising from the substance or mixture
Carbon monoxide,Carbon dioxide,Hydrogen cyanide,nitrogen oxides
Traces of the substances/groups of substances mentioned can be released in case of fire or upon excessive heat.
Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Dispose of fire debris and contaminated extinguishing water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use personal protective clothing. Information regarding personal protective measures, see section 8. Avoid inhalation. Avoid contact with the skin, eyes and clothing.
Environmental precautions
Do not discharge into drains/surface waters/groundwater.
Methods and material for containment and cleaning up
For small amounts: Pick up with suitable appliance and dispose of.
For large amounts: Pick up with suitable appliance and dispose of.
Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Collect waste in suitable containers, which can be labeled and sealed. Incinerate or take to a special waste disposal site in accordance with local authority regulations.
Handling and storage
Precautions for safe handling
Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.
Protection against fire and explosion:
Take precautionary measures against static discharges. Keep away from sources of ignition - No smoking.
Conditions for safe storage, including any incompatibilities
Further information on storage conditions: Keep container dry.
Storage stability:
Storage temperature: 20 °C
Storage duration: 24 Months
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Components with occupational exposure limits
110-91-8: Morpholine
Exposure controls
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)
Hand protection:
Chemical resistant protective gloves (EN ISO 374-1)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN ISO 374-1):
butyl rubber (butyl) - 0.7 mm coating thickness
fluoroelastomer (FKM) - 0.7 mm coating thickness
polyvinylchloride (PVC) - 0.7 mm coating thickness
nitrile rubber (NBR) - 0.4 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.
Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).
General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Avoid inhalation. Avoid contact with the skin, eyes and clothing. When using, do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). Take off immediately all contaminated clothing. Wash contaminated clothing before reuse. Store work clothing separately.
Stability and reactivity
Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.
Corrosion to metals:
No corrosive effect on metal. In the presence of water or moisture metal corrosion cannot be excluded.
Formation of flammable gases:
Remarks:
Forms no flammable gases in the presence of water.
Chemical stability
The product is stable if stored and handled as prescribed/indicated.
Possibility of hazardous reactions
No hazardous reactions known.
Conditions to avoid
Avoid extreme heat.
Incompatible materials
Substances to avoid:
acids, acid chlorides, isocyanates, oxidizing agents, nitrosating agents
Hazardous decomposition products
Hazardous decomposition products:
Hydrogen cyanide
nitrogen oxides, carbon oxides
Disposal considerations
Waste treatment methods
Incinerate in suitable incineration plant, observing local authority regulations.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
