Registration Dossier

Administrative data

First-aid measures

General advice
Move out of dangerous area. Place and transport victim in stable position (lying sideways).
Remove contaminated clothing immediately and dispose of safely.

Inhalation
Move to fresh air. Keep patient warm and at rest. Call a physician or poison control center immediately.

Skin contact
Wash off thoroughly with plenty of soap and water, if available with polyethyleneglycol 400, subsequently rinse with water. If symptoms persist, call a physician.

Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Get medical attention if irritation develops and persists.

Ingestion
Rinse mouth. Do NOT induce vomiting. Call a physician or poison control center immediately.

Notes to physician
Treatment
Treat symptomatically.
In case of ingestion gastric lavage should be considered in cases of significant ingestions
only within the first 2 hours. However, the application of activated charcoal and sodium
sulphate is always advisable.

Fire-fighting measures

Suitable extinguishing media: Water spray, Carbon dioxide (CO2), Foam, Sand

Specific hazards during fire fighting
In the event of fire the following may be released: Hydrogen cyanide (hydrocyanic acid), Carbon monoxide (CO), nitrogen oxides (NOx)

Special protective equipment for fire-fighters
In the event of fire and/or explosion do not breathe fumes.
In the event of fire, wear self-contained breathing apparatus.

Further information
Contain the spread of the fire-fighting media.
Do not allow run-off from fire fighting to enter drains or water courses.

Accidental release measures

Personal precautions:
Avoid contact with spilled product or contaminated surfaces.
Use personal protective equipment.
Remove all sources of ignition.

Environmental precautions:
Do not allow to get into surface water, drains and ground water.

Methods for cleaning up:
Use mechanical handling equipment.
Clean contaminated floors and objects thoroughly, observing environmental regulations.
Keep in suitable, closed containers for disposal.

Handling and storage

Handling

Advice on safe handling:
Use only in area provided with appropriate exhaust ventilation.
Advice on protection against fire and explosion
Dust may form explosive mixture in air.
Keep away from heat and sources of ignition.

Storage

Requirements for storage areas and containers:
Store in original container.
Keep containers tightly closed in a dry, cool and well-ventilated place.
Store in a place accessible by authorized persons only.

Advice on common storage
Keep away from food, drink and animal feedingstuffs.

Temperature tolerance min. -10 °C max. 40 °C

Transport information

Land transport (ADR/RID)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(ISOXADIFEN-ETHYL)
Chemical name:
Ethyl 5,5-diphenyl-2-isoxazoline-3-carboxylate
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9, E1
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(ISOXADIFEN-ETHYL)
Chemical name:
Ethyl 5,5-diphenyl-2-isoxazoline-3-carboxylate
Language:
English
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9, E1
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(ISOXADIFEN-ETHYL)
Chemical name:
Ethyl 5,5-diphenyl-2-isoxazoline-3-carboxylate
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Labels:
9, P
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3077
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(ISOXADIFEN-ETHYL)
Chemical name:
Ethyl 5,5-diphenyl-2-isoxazoline-3-carboxylate
Class:
9
Packaging group:
III
Labels:
9, E1
Remarks
Transport code: UN-Nr. 3077
Transport: Der innerbetriebliche Transport sollte in dichtschließenden,
bruchsicheren und vorschriftsmäßig gekennzeichneten
Behältern erfolgen, die gegen Verrutschen und Herabfallen
gesichert sind.

Weitere Transportcodes:

ADR/RID/ADNR: Kl. 9 Ziff. 12c

"ENGLISH"

For inplant transport use tightly sealable, unbreakable and
in accordance to the regulations labelled drums, stored
against falling and slipping.

More transport codes:

ADR/RID/ADNR: cl. 9 no. 12c
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Respiratory protection:
If product is handled while not enclosed, and if contact may occur: Wear respirator with a particle filter mask (protection factor 10)
conforming to European Norm EN149FFP2 or EN140P2 or equivalent.

Hand protection: Wear CE Marked (or equivalent) nitrile rubber gloves (minimum thickness 0,40 mm). Wash when contaminated. Dispose of when contaminated inside, when perforated or when contamination outside cannot be removed. Wash hands always before eating, drinking, smoking or using the toilet.

Eye protection: Wear goggles conforming to EN166 (Field of Use 5 or equivalent). Skin and body protection Wear standard coverall and type 3 suit. Wear two layers of clothing wherever possible. Polyester/cotton or cotton overalls should be worn under chemical protection suit and should be professionally laundered frequently. If chemical protection suit is splashed, sprayed or significantly contaminated, decontaminate as far as possible, then carefully remove and dispose of as advised by manufacturer.

Hygiene measures
Avoid contact with skin, eyes and clothing.
Keep working clothes separately.
Wash hands immediately after work, if necessary take a shower.
Remove soiled clothing immediately and clean thoroughly before using again.
Garments that cannot be cleaned must be destroyed (burnt).

Protective measures
If product is handled while not enclosed, and if contact may occur:
Complete suit protecting against chemicals

Stability and reactivity

Thermal decomposition from 290 °C. Exothermic decomposition.

Hazardous reactions No hazardous reactions when stored and handled according to
prescribed instructions.

Stable under recommended storage conditions.

May cause dust explosion

Disposal considerations

Industry - Possibility of recovery/recycling: Keine

"ENGLISH"

none

Industry - Possibility of neutralisation: Wirkstoff hydrolysiert mit Wasser

"ENGLISH"

substance hydrolyses with water

Industry - Possibility of destruction: controlled discharge: Verunreingte Behälter werden gemäß EU-Verordnung
zurückgenommen.

"ENGLISH"

contaminated drums will be taken back according to
EU-directive

Public at large - Possibility of recovery/recycling: Produkt wird nicht an die Allgemeinheit abgegeben.

"ENGLISH"

substance is not given to public domain