Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

Currently viewing:

Administrative data

First-aid measures

General advice:
Immediately remove contaminated clothing. If danger of loss of consciousness, place patient in
recovery position and transport accordingly. Apply artificial respiration if necessary. First aid personnel
should pay attention to their own safety.
If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.
On skin contact:
Wash thoroughly with soap and water.
On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation
develops, seek medical attention.
On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.

Fire-fighting measures

Suitable extinguishing media:
dry powder, foam, carbon dioxide, water spray
Specific hazards:
carbon monoxide, carbon dioxide, irritant gases/vapours
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.
Further information:
Cool endangered containers with water-spray. Collect contaminated extinguishing water separately,
do not allow to reach sewage or effluent systems.

Accidental release measures

Personal precautions:
Breathing protection required. Avoid contact with the skin, eyes and clothing.
Environmental precautions:
Do not discharge into drains/surface waters/groundwater.
Methods for cleaning up or taking up:
For small amounts: Rinse away with water.
For large amounts: Dike spillage. Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder,
kieselguhr). Dispose of absorbed material in accordance with regulations.
Cleaning operations should be carried out only while wearing breathing apparatus.

Handling and storage

Handling
Ensure thorough ventilation of stores and work areas. Handle under dry inert gas.
Protection against fire and explosion:
Vapours may form explosive mixture with air. Prevent electrostatic charge - sources of ignition should
be kept well clear - fire extinguishers should be kept handy.
Storage
Segregate from foods and animal feeds.
Further information on storage conditions: Avoid all sources of ignition: heat, sparks, open flame. Keep
container tightly closed in a cool, well-ventilated place. Keep under nitrogen.
Storage stability:
Storage temperature: 20 °C
Storage duration: 6 Months
Keep under nitrogen.
From the data on storage duration in this safety data sheet no agreed statement regarding the
warrantee of application properties can be deduced.
Protect from temperatures below: 13 °C

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

Remarksopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Components with workplace control parameters
123-91-1: 1,4-dioxane
Personal protective equipment
Respiratory protection:
Wear respiratory protection if ventilation is inadequate. Self-contained breathing apparatus.
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6,
corresponding > 480 minutes of permeation time according to EN 374):
Manufacturer's directions for use should be observed because of great diversity of types.
butyl rubber (butyl) - 0.7 mm coating thickness
Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting
boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of
dust).
General safety and hygiene measures:
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work
clothing is required additionally to the stated personal protection equipment. Avoid contact with the
skin, eyes and clothing. Do not inhale gases/vapours/aerosols. Take off immediately all contaminated
clothing. Store work clothing separately.

Stability and reactivity

Conditions to avoid:
Avoid heat.
Substances to avoid:
strong oxidizing agents
Hazardous reactions:
Evolution of explosive gases/vapours.
Possible thermal decomposition products:
carbon monoxide
irritant gases/vapours

Disposal considerations

Incinerate in suitable incineration plant, observing local authority regulations.
Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling
after being thoroughly cleaned.