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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Additional advice

Do not give victim anything to drink if he is unconscious.

Inhalation

If inhaled, remove to fresh air. Keep the patient warm and at rest. Perform artificial respiration if breathing has

stopped. Get medical attention immediately.

Skin contact

Promptly remove soiled clothing. Wash contaminated skin with plenty of soap and water. Wash soiled clothes

before reuse.

Eye contact

Flush with water at least 15 minutes. Get medical attention if eye irritation develops or persists.

Ingestion

Flush mouth with water. Get medical attention immediately.

Fire-fighting measures

Suitable extinguishing media

Water, Carbon dioxide, dry chemical or foam.

Specific hazards

Fire can generate toxic or irritating fumes, e.g. oxides of sulphur.

Special protective equipment for firefighters

Appropriate protective equipment and self-contained breathing apparatus

Specific methods

Keep storage containers cool with water spray.

Accidental release measures

Personal precautions

Use in areas of adequate ventilation. Avoid breathing vapours Avoid contact with skin and eyes. See section 8

for personal protection measures.

Environmental precautions

Prevent entry into sewers and waterways. Prevent entry into soil.

Methods for cleaning up

Sweep up and place in suitable containers. See section 13 for waste management measures

Handling and storage

Handling

Use in areas of adequate ventilation. Avoid breathing of vapours. Eating, drinking and smoking should be

prohibited in areas where this material is handled, stored and processed. Ensure that the current occupational

safety and health act legislation is followed. See section 8 for personal protection equipment.

Storage

To be stored in a dry and well ventilated place protected from moisture and warmth. Keep the containers tightly

closed.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
3077
Shippingopen allclose all
Labels:
9
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
3077
Shippingopen allclose all
Labels:
9
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Nickel sulfide)
Chemical name:
Nickel sulfide
Labels:
9
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
3077
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, SOLID, N.O.S.
(Nickel sulphide)
Chemical name:
Nickel sulphide
Labels:
9
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure Limit Values

Threshold limits

16812-54-7 0,1 mg/m3 (8 h)

Ni

1317-42-6 0,05 mg/m3 (8 h)

Co

Nickel (II) sulfide

Cobalt sulfide

Limit values in other countries

Nickel sulfide:

Austria: 0,5 mg/m3 (8 h), 2 mg/m3 (15 min), inhalated as aerosols

France: 1 mg/m3 (8 h)

Hungary: 0,1 mg/m3 (15 min)

Spain: 0,1 mg/m3 (8 h)

Exposure controls

Occupational exposure controls

Ensure adequate ventilation. if possible use local exhaust extraction and efficient exhaust ventilation. Avoid

breathing of fumes and dust. Avoid contact with skin and eyes. Avoid repeated exposure. Use personal

protection. Eating, drinking and smoking prohibited. Wash thorougly after work. Store working clothes separated

from other clothes.

Ensure that the current occupational safety and health act legislation is followed. Pregnant women should

contact occupational health care.

Respiratory protection

Use respiratory protection (e.g. filter P3).

Hand protection

Use chemical resistant gloves (PVC, butyl rubber, rubber, neoprene).

Eye protection

Safety goggles

Skin and body protection

Wear appropriate boots and coveralls or other protective clothing.

Environmental exposure controls

Prevent contamination to soil, waterway and sewer systems. Observe the requirements of IPPC directive.

Stability and reactivity

Materials to avoid

Oxidizing agents.

Hazardous decomposition products

Thermal decomposition and burning may produce: oxides of sulphur.

Disposal considerations

Hazardous waste.

Waste code 11 02 07*: wastes from non-ferrous hydrometallurgical processes;other wastes containing

dangerous substances.

Empty containers should be disposed of in accordance with local regulations.

Contaminated packaging

Hazardous waste.