Registration Dossier
Registration Dossier
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EC number: 206-534-2 | CAS number: 353-50-4
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
*In case of inhalation
- In case of accident by inhalation: remove casualty to fresh air and keep at rest.
- Oxygen or artificial respiration if needed.
- Victim to lie down in the recovery position, cover and keep him warm.
- Call a physician immediately.
- Take victim immediately to hospital.
*In case of skin contact
- Call a physician immediately.
- Take victim immediately to hospital.
- Take off contaminated clothing and shoes immediately.
- Wash off with plenty of water.
- First treatment with calcium gluconate paste.
*In case of eye contact
- Immediate medical attention is required.
- Take victim immediately to hospital.
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine).
- Calcium gluconate solution.
*In case of ingestion
- Not applicable: gas
Most important symptoms and effects, both acute and delayed
*In case of inhalation
Effects
- Inhalation of vapours is irritating to the respiratory system, may cause throat pain and cough.
- Aspiration may cause pulmonary oedema and pneumonitis. Effects may be delayed.
- risk of hypocalcemia with nervous problems (tetany) and cardiac arrhythmia
Symptoms:
- Breathing difficulties
- sore throat
- Nose bleeding
Effects:
Repeated or prolonged exposure
- Risk of chronic bronchitis
*In case of skin contact
Effects:
- Skin irritation
Symptoms:
- Irritation
- Redness
- Swelling of tissue
*In case of eye contact
Effects:
- Severe eye irritation
Symptoms:
- Lachrymation
- Redness
- Swelling of tissue
- In case of accident by inhalation: remove casualty to fresh air and keep at rest.
- Oxygen or artificial respiration if needed.
- Victim to lie down in the recovery position, cover and keep him warm.
- Call a physician immediately.
- Take victim immediately to hospital.
*In case of skin contact
- Call a physician immediately.
- Take victim immediately to hospital.
- Take off contaminated clothing and shoes immediately.
- Wash off with plenty of water.
- First treatment with calcium gluconate paste.
*In case of eye contact
- Immediate medical attention is required.
- Take victim immediately to hospital.
- Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
- In the case of difficulty of opening the lids, administer an analgesic eye wash (oxybuprocaine).
- Calcium gluconate solution.
*In case of ingestion
- Not applicable: gas
Most important symptoms and effects, both acute and delayed
*In case of inhalation
Effects
- Inhalation of vapours is irritating to the respiratory system, may cause throat pain and cough.
- Aspiration may cause pulmonary oedema and pneumonitis. Effects may be delayed.
- risk of hypocalcemia with nervous problems (tetany) and cardiac arrhythmia
Symptoms:
- Breathing difficulties
- sore throat
- Nose bleeding
Effects:
Repeated or prolonged exposure
- Risk of chronic bronchitis
*In case of skin contact
Effects:
- Skin irritation
Symptoms:
- Irritation
- Redness
- Swelling of tissue
*In case of eye contact
Effects:
- Severe eye irritation
Symptoms:
- Lachrymation
- Redness
- Swelling of tissue
Fire-fighting measures
*Extinguishing media
Suitable extinguishing media
- Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
- Water may be ineffective.
*Special hazards arising from the substance or mixture
- The product is not flammable.
- Not combustible.
- Reacts violently with water.
- Hazardous decomposition products formed under fire conditions.
*Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- Wear chemical resistant oversuit
- Special protective actions for fire-fighters
- In case of fire, use water spray.
- Keep product and empty container away from heat and sources of ignition.
*Further information
- Cool containers/tanks with water spray.
- Keep from any possible contact with water.
- Approach from upwind.
- Suppress (knock down) gases/vapours/mists with a water spray jet.
Suitable extinguishing media
- Use extinguishing measures that are appropriate to local circumstances and the surrounding environment.
Unsuitable extinguishing media
- Water may be ineffective.
*Special hazards arising from the substance or mixture
- The product is not flammable.
- Not combustible.
- Reacts violently with water.
- Hazardous decomposition products formed under fire conditions.
*Advice for firefighters
Special protective equipment for firefighters
- Wear self-contained breathing apparatus and protective suit.
- Wear chemical resistant oversuit
- Special protective actions for fire-fighters
- In case of fire, use water spray.
- Keep product and empty container away from heat and sources of ignition.
*Further information
- Cool containers/tanks with water spray.
- Keep from any possible contact with water.
- Approach from upwind.
- Suppress (knock down) gases/vapours/mists with a water spray jet.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
*Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
- Keep away from incompatible products
*Advice for emergency responders
- Immediately evacuate personnel to safe areas.
- Keep people away from and upwind of spill/leak.
- Wear self-contained breathing apparatus and protective suit.
- Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.
- Suppress (knock down) gases/vapours/mists with a water spray jet.
- Avoid spraying the leak source.
- Ventilate the area.
*Environmental precautions
- Should not be released into the environment.
- If the product contaminates rivers and lakes or drains inform respective authorities.
*Methods and materials for containment and cleaning up
- Prevent product from entering sewage system.
- Contact waste disposal services.
*Advice for non-emergency personnel
- Prevent further leakage or spillage if safe to do so.
- Keep away from incompatible products
*Advice for emergency responders
- Immediately evacuate personnel to safe areas.
- Keep people away from and upwind of spill/leak.
- Wear self-contained breathing apparatus and protective suit.
- Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.
- Suppress (knock down) gases/vapours/mists with a water spray jet.
- Avoid spraying the leak source.
- Ventilate the area.
*Environmental precautions
- Should not be released into the environment.
- If the product contaminates rivers and lakes or drains inform respective authorities.
*Methods and materials for containment and cleaning up
- Prevent product from entering sewage system.
- Contact waste disposal services.
Handling and storage
*Precautions for safe handling
- Use only in well-ventilated areas.
- Used in closed system
- Use only clean and dry utensils.
- Keep away from water.
- Preferably transfer by pump or gravity.
- Do not attempt to regulate flow rate or pressure from the cylinder valve; use a suitable regulating device.
- Keep away from incompatible products
*Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Take off contaminated clothing and shoes immediately.
- Wash contaminated clothing before re-use.
- May not get in touch with:
- Leather
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice
Conditions for safe storage, including any incompatibilities
*Technical measures/Storage conditions
- Keep container tightly closed.
- Keep in a cool, well-ventilated place.
- Keep away from heat.
- Keep in a bunded area.
- Electrical equipment should be protected to the appropriate standard.
- Keep away from incompatible products
*Packaging material
Suitable material
- Steel drum
- Use only in well-ventilated areas.
- Used in closed system
- Use only clean and dry utensils.
- Keep away from water.
- Preferably transfer by pump or gravity.
- Do not attempt to regulate flow rate or pressure from the cylinder valve; use a suitable regulating device.
- Keep away from incompatible products
*Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Take off contaminated clothing and shoes immediately.
- Wash contaminated clothing before re-use.
- May not get in touch with:
- Leather
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice
Conditions for safe storage, including any incompatibilities
*Technical measures/Storage conditions
- Keep container tightly closed.
- Keep in a cool, well-ventilated place.
- Keep away from heat.
- Keep in a bunded area.
- Electrical equipment should be protected to the appropriate standard.
- Keep away from incompatible products
*Packaging material
Suitable material
- Steel drum
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN 2417
Shipping information
- Proper shipping name and description:
- CARBONYL FLUORIDE
- Chemical name:
- CARBONYL FLUORIDE
- Language:
- English
- Labels:
- 2.3 (8)
Special provisions / remarks
- Special provisions:
- Hazard Identification Number: 268
Tunnel restriction code (C/D)
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN 2417
Shipping information
- Proper shipping name and description:
- CARBONYL FLUORIDE
- Chemical name:
- CARBONYL FLUORIDE
- Language:
- English
- Labels:
- 2.3 (8)
Special provisions / remarks
- Remarks:
- Hazard Identification Number: 268
Marine transport (UN RTDG/IMDG)
- UN number:
- UN 2417
Shipping information
- Proper shipping name and description:
- CARBONYL FLUORIDE
- Chemical name:
- CARBONYL FLUORIDE
- Labels:
- 2.3 (8)
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN 2417
Shipping information
- Proper shipping name and description:
- Not permitted for air transport
Special provisions / remarks
- Remarks:
- Not permitted for air transport
SpecialProvisionsopen allclose all
Exposure controls / personal protection
1. Technical protection measures
Engineering measures
- Use only with adequate ventilation and in closed systems.
- Apply technical measures to comply with the occupational exposure limits.
2. Organisational protection measures
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Take off contaminated clothing and shoes immediately.
- Wash contaminated clothing before re-use.
- May not get in touch with Leather
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice
3. Hand protection
- Heat insulating gloves
- Impervious gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Suitable material
- Fluoroelastomer
4. Feet protection
- Boots
- Do not wear leather shoes.
5. Body protection
- Complete suit protecting against chemicals
6. Eye protection
- Chemical resistant goggles must be worn.
7. Respiratory protection
- Respirator with a full face mask
- Recommended Filter type: E-P3
- In case of decomposition (see section 10), face mask with combined type B-P3 cartridge.
- Self-contained breathing apparatus in confined spaces/insufficient oxygen/in case of large uncontrolled emissions/in all circumstances when the mask and cartridge do not give adequate protection.
Engineering measures
- Use only with adequate ventilation and in closed systems.
- Apply technical measures to comply with the occupational exposure limits.
2. Organisational protection measures
Hygiene measures
- Ensure that eyewash stations and safety showers are close to the workstation location.
- Take off contaminated clothing and shoes immediately.
- Wash contaminated clothing before re-use.
- May not get in touch with Leather
- Wash hands before breaks and at the end of workday.
- Handle in accordance with good industrial hygiene and safety practice
3. Hand protection
- Heat insulating gloves
- Impervious gloves
- Take note of the information given by the producer concerning permeability and break through times, and of special workplace conditions (mechanical strain, duration of contact).
Suitable material
- Fluoroelastomer
4. Feet protection
- Boots
- Do not wear leather shoes.
5. Body protection
- Complete suit protecting against chemicals
6. Eye protection
- Chemical resistant goggles must be worn.
7. Respiratory protection
- Respirator with a full face mask
- Recommended Filter type: E-P3
- In case of decomposition (see section 10), face mask with combined type B-P3 cartridge.
- Self-contained breathing apparatus in confined spaces/insufficient oxygen/in case of large uncontrolled emissions/in all circumstances when the mask and cartridge do not give adequate protection.
Stability and reactivity
* Reactivity
- Risk of violent reaction.
- Risk of explosion.
* Chemical stability
- Stable under recommended storage conditions.
* Possibility of hazardous reactions
- Reacts violently with water. May be corrosive to metals.
* Conditions to avoid
- Exposure to moisture
* Incompatible materials
- Water
- Bases
- Oxidizing agents
*Hazardous decomposition products
- Hydrogen fluoride
- Carbon monoxide
- Risk of violent reaction.
- Risk of explosion.
* Chemical stability
- Stable under recommended storage conditions.
* Possibility of hazardous reactions
- Reacts violently with water. May be corrosive to metals.
* Conditions to avoid
- Exposure to moisture
* Incompatible materials
- Water
- Bases
- Oxidizing agents
*Hazardous decomposition products
- Hydrogen fluoride
- Carbon monoxide
Disposal considerations
Dispose of rinse water in accordance with local and national regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
