Summary of Classification and Labelling
Harmonised classification - Annex VI of Regulation (EC) No 1272/2008 (CLP Regulation)
General Information
Index Number EC / List no. CAS Number International Chemical Identification
607-014-00-1 203-481-7 107-31-3 methyl formate

ATP Inserted / Updated: CLP00
CLP Classification (Table 3)
Classification Labelling Specific Concentration limits, M-Factors, Acute Toxicity Estimates (ATE) Notes
Hazard Class and Category Code(s) Hazard Statement Code(s) Hazard Statement Code(s) Supplementary Hazard Statement Code(s) Pictograms, Signal Word Code(s)
Flam. Liq. 1 H224 H224 GHS02
GHS07
Dgr
Acute Tox. 4 * H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 * H332 H332
STOT SE 3 H335 H335

Signal Words Pictograms
Danger
GHS02
Flame
GHS07
Exclamation mark
Seveso III Data
Disclaimer: Please note that some of the substances covered by the Seveso Directive can belong to more than one Seveso categories. It will be up to the users to decide whether their substance or mixture fall in one or in more of these classification categories depending on the tonnage bands and the concentrations.
Please also note that ECHA is not an authority for the Seveso Directive and that the Seveso categorisation below is provided for information only. The Seveso III Directive (Directive 2012/18/EU repealing Directive 96/82/EC (Seveso II) from 1 June 2015) is the only authentic legal reference and that the information in this inventory does not constitute legal advice. For further information on Seveso, please ask your national authority.

Seveso Data
Seveso Substance Seveso Categories
Oui P5a
Notified classification and labelling
General Information
EC / List no.
Name CAS Number
203-481-7 Methyl formate 107-31-3

Notified classification and labelling according to CLP criteria
Classification Labelling Specific Concentration limits, M-Factors Notes Classification affected by Impurities / Additives

Additional Notified Information

Number of Notifiers

Joint Entries

Hazard Class and Category Code(s) Hazard Statement Code(s) Hazard Statement Code(s) Supplementary Hazard Statement Code(s) Pictograms, Signal Word Code(s)
Flam. Liq. 1 H224 H224 GHS02
GHS08
GHS06
Dgr
State/Form
4 yes View details
Acute Tox. 3 H301 H301
Acute Tox. 3 H311 H311
Eye Irrit. 2A H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:respirato...) H335
STOT SE 1 H370 (other:optical n...) H370
Flam. Liq. 1 H224 H224 GHS02
GHS07
Dgr
State/Form
4 yes View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:respirato...) H335
Flam. Liq. 1 H224 H224 GHS08
GHS02
GHS06
Dgr
State/Form
2 yes View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:Respirato...) H335
STOT SE 2 H371 (other:n.a.) H371
Flam. Liq. 1 H224 H224 GHS07
GHS02
Dgr
State/Form
259 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:respirato...) H335
Flam. Liq. 1 H224 H224 GHS07
GHS02
Dgr
State/Form
91 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 H335
STOT SE 3 H335 (other:-) H335
Flam. Liq. 1 H224 H224 GHS08
GHS02
GHS06
Dgr
STOT SE 1; : C ≥ 10 %
STOT SE 2; : 3 % ≤ C < 10 %
87 View details
Acute Tox. 3 H301  
  H301+H311+H331
Acute Tox. 3 H311  
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331  
STOT SE 3 H335 (other:Respirato...) H335
STOT SE 1 H370 (other:Central n...) H370 (Causes damage t...)
Flam. Liq. 1 H224 H224 GHS07
GHS02
Dgr
State/Form
82 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 H335
Flam. Liq. 1 H224 H224 GHS08
GHS02
GHS07
GHS06
Dgr
55 View details
Acute Tox. 3 H301 H301
Acute Tox. 3 H311 H311
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 (other:-) H335
STOT SE 1 H370 (other:optic ner...) H370
Flam. Liq. 1 H224 H224 GHS02
GHS07
Dgr
State/Form
47 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (not specified) H335
Flam. Liq. 1 H224 H224 GHS02
GHS08
GHS06
Dgr
37 View details
Acute Tox. 3 H301  
  H301+H311+H331
Acute Tox. 3 H311  
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331  
STOT SE 3 H335 H335
STOT SE 1 H370 (Zentralnervensy...) (inhalation,oral) H370
Flam. Liq. 1 H224 H224 GHS02
GHS07
Dgr
36 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (Not applicable) H335
STOT SE 3 H335 (other:Not appli...) H335
Flam. Liq. 1 H224 H224 GHS07
GHS02
Dgr
28 View details
Acute Tox. 4 H302  
  H302+H332
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332  
STOT SE 3 H335 (other:Respirato...) H335
Flam. Liq. 1 H224 H224 GHS02
GHS07
Dgr
State/Form
4 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
  H335
Flam. Liq. 1 H224 H224 GHS02
GHS07
Dgr
State/Form
4 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:-) H335
Flam. Liq. 1 H224 H224 GHS02
GHS07
Dgr
1 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:RTI) H335
STOT SE 3 H335 (RTI) H335
Flam. Liq. 1 H224 H224 GHS02
GHS07
Dgr
1 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:Not avail...) H335
STOT SE 3 H335 (Not available) H335
Flam. Liq. 1 H224 H224 GHS07
GHS02
Dgr
State/Form
1 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2 H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:organs) H335
STOT SE 3 H335 (organs) H335
Flam. Liq. 1 H224 H224 GHS07
GHS02
GHS08
GHS06
Dgr
1 View details
Acute Tox. 3 H301 H301
Acute Tox. 3 H311 H311
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
STOT SE 3 H335 H335
STOT SE 1 H370 (optical nerve, ...) (oral) H370
Flam. Liq. 1 H224 H224 GHS08
GHS02
GHS07
GHS06
Dgr
State/Form
1 View details
Acute Tox. 3 H301 H301
Acute Tox. 3 H311 H311
Eye Irrit. 2 H319 H319
Acute Tox. 3 H331 H331
  H335
STOT SE 1 H370 (other:-) H370
Flam. Liq. 1 H224 H224 GHS07
GHS02
Dgr
State/Form
1 View details
Acute Tox. 4 H302 H302
Eye Irrit. 2A H319 H319
Acute Tox. 4 H332 H332
STOT SE 3 H335 (other:Respirato...) (inhalation) H335

Number of Aggregated Notifications: 20