Registration Dossier
Registration Dossier
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The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.
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EC number: 203-401-0 | CAS number: 106-47-8
Guidance on Safe Use
Administrative data
First-aid measures
Skin contact: Remove all contaminated clothes and footwear immediately unless stuck to skin. Wash
immediately with plenty of soap and water. Contaminated clothes should be washed
before re-use or disposed of. Consult a doctor.
Eye contact: Bathe the eye with running water for 15 minutes. Transfer to hospital for specialist
examination.
Ingestion: If conscious, give half a litre of water to drink immediately. Never give anything by mouth
to an unconscious person. If unconscious, check for breathing and apply artificial
respiration if necessary. If unconscious and breathing is OK, place in the recovery
position. Transfer to hospital as soon as possible.
Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. If
unconscious and breathing is OK, place in the recovery position. If unconscious, check
for breathing and apply artificial respiration if necessary. Transfer to hospital as soon as
possible
Fire-fighting measures
Extinguishing media: Water spray. Water fog. Alcohol resistant foam. Dry chemical powder. Do not use full
water jet.
Exposure hazards: Toxic. In combustion emits toxic fumes of carbon dioxide / carbon monoxide. In
combustion emits toxic fumes of nitrogen oxides. In combustion emits toxic fumes of
hydrogen chloride.
Advice for fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact
with skin and eyes.
Accidental release measures
Personal precautions: Mark out the contaminated area
with signs and prevent access to unauthorised personnel. Eliminate all sources of
ignition. Do not create dust.
Environmental precautions: Do not discharge into drains or rivers.
Clean-up procedures: Transfer to a suitable container. Avoid creating dust. Use a dust suppressing sweeping
aid if necessary. Wash the spillage site with large amounts of water. Retain washings
as contaminated waste.
Handling and storage
Handling requirements: Ensure there is sufficient ventilation of the area. Avoid direct contact with the substance.
Earth any equipment used in handling. Avoid the formation or spread of dust in the air.
Smoking is forbidden. Use non-sparking tools.
Storage conditions: Store in cool, well ventilated area. Keep away from direct sunlight. Keep away from
sources of ignition. Keep container tightly closed.
Suitable packaging: Must only be kept in original packaging.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN2018
Shipping information
- Proper shipping name and description:
- CHLOROANILINES, SOLID
- Chemical name:
- 4-CHLOROANILINE
- Language:
- English
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Engineering measures: Ensure there is sufficient ventilation of the area. In the laboratory, handle in a chemical
fume hood.
Respiratory protection: Air supplied breathing apparatus will be required if closed systems or effective local
exhaust ventilation cannot be provided. Self-contained breathing apparatus must be
available in case of emergency.
Hand protection: Butyl gloves. PVA gloves.
Eye protection: Safety glasses with side-shields.
Skin protection: Impermeable protective clothing.
Stability and reactivity
Chemical stability: Stable under normal conditions.
Conditions to avoid: Heat. Sources of ignition.
Materials to avoid: Oxidising agents. Strong acids. Acid chlorides. Acid anhydrides. Chloroformates.
Haz. decomp. products: In combustion, emits toxic fumes of carbon monoxide / dioxide, nitrogen oxides, nitrogen
and hydrogen chloride.
Disposal considerations
Disposal operations: Incineration on land.
Disposal of packaging: Empty containers are still hazardous and should be decontaminated and disposed of in
accordance with local regulations.
NB: The user's attention is drawn to the possible existence of regional or national
regulations regarding disposal.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
