Registration Dossier
Registration Dossier
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EC number: 220-599-4 | CAS number: 2832-30-6
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention if symptoms occur.
Ingestion: Wash out mouth with water. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Do not induce vomiting
unless directed to do so by medical personnel. Get medical attention if symptoms
occur.
Skin contact: Wash skin immediately with plenty of water and soap. Remove contaminated
clothing and shoes. Get medical attention if irritation occurs. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for breathing.
Get medical attention if symptoms occur.
Ingestion: Wash out mouth with water. Remove victim to fresh air and keep at rest in a
position comfortable for breathing. If material has been swallowed and the exposed
person is conscious, give small quantities of water to drink. Do not induce vomiting
unless directed to do so by medical personnel. Get medical attention if symptoms
occur.
Skin contact: Wash skin immediately with plenty of water and soap. Remove contaminated
clothing and shoes. Get medical attention if irritation occurs. Wash clothing before
reuse. Clean shoes thoroughly before reuse.
Eye contact: Immediately flush eyes with plenty of water, occasionally lifting the upper and lower
eyelids. Check for and remove any contact lenses. Get medical attention if irritation
occurs.
Fire-fighting measures
Extinguishing media
Suitable extinguishing media: Use dry chemical powder
Unsuitable extinguishing media: Do not use water jet
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: In a fire, hazardous decomposition products may be produced.
Hazardous thermal decomposition products: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
sulfur oxides
metal oxide/oxides
Advice for firefighters
Special protective actions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.
Suitable extinguishing media: Use dry chemical powder
Unsuitable extinguishing media: Do not use water jet
Special hazards arising from the substance or mixture
Hazards from the substance or mixture: In a fire, hazardous decomposition products may be produced.
Hazardous thermal decomposition products: Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
sulfur oxides
metal oxide/oxides
Advice for firefighters
Special protective actions for fire-fighters: Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without
suitable training. Move containers from fire area if this can be done without risk.
Use water spray to keep fire-exposed containers cool.
Special protective equipment for fire-fighters: Fire-fighters should wear appropriate protective equipment and self-contained breathing apparatus (SCBA) with a full face-piece operated in positive pressure
mode. Clothing for fire-fighters (including helmets, protective boots and gloves) conforming to European standard EN 469 will provide a basic level of protection for chemical incidents.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training.
Keep unnecessary and unprotected personnel from entering. Do not touch or walk
through spilt material. Shut off all ignition sources. No flares, smoking or flames in
hazard area. Avoid breathing dust. Put on appropriate personal protective equipment.
For emergency responders: If specialised clothing is required to deal with the spillage, take note of any
information in Section Exposure controls on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up
Small spill: Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
Large spill: Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Vacuum or sweep up material and place in a designated, labelled waste container. Avoid creating dusty conditions and prevent wind dispersal. Dispose of via a licensed waste disposal contractor.
Reference to other
sections
See Section Exposure controls for information on appropriate personal protective equipment.
See Section Disposal consideration for additional waste treatment information
For non-emergency personnel: No action shall be taken involving any personal risk or without suitable training.
Keep unnecessary and unprotected personnel from entering. Do not touch or walk
through spilt material. Shut off all ignition sources. No flares, smoking or flames in
hazard area. Avoid breathing dust. Put on appropriate personal protective equipment.
For emergency responders: If specialised clothing is required to deal with the spillage, take note of any
information in Section Exposure controls on suitable and unsuitable materials. See also the
information in "For non-emergency personnel".
Environmental precautions: Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental pollution (sewers, waterways, soil or air).
Methods and material for containment and cleaning up
Small spill: Move containers from spill area. Use spark-proof tools and explosion-proof equipment. Vacuum or sweep up material and place in a designated, labelled waste container. Dispose of via a licensed waste disposal contractor.
Large spill: Move containers from spill area. Prevent entry into sewers, water courses, basements or confined areas. Use spark-proof tools and explosion-proof equipment. Approach the release from upwind. Vacuum or sweep up material and place in a designated, labelled waste container. Avoid creating dusty conditions and prevent wind dispersal. Dispose of via a licensed waste disposal contractor.
Reference to other
sections
See Section Exposure controls for information on appropriate personal protective equipment.
See Section Disposal consideration for additional waste treatment information
Handling and storage
Precautions for safe handling
Protective measures: Put on appropriate personal protective equipment (see Section 8). Avoid breathing
dust. Avoid the creation of dust when handling and avoid all possible sources of
ignition (spark or flame). Prevent dust accumulation. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Electrical
equipment and lighting should be protected to appropriate standards to prevent dust
coming into contact with hot surfaces, sparks or other ignition sources. Take
precautionary measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by earthing and bonding containers and
equipment before transferring material.
Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas. See also Section Exposure controls for additional information on hygiene measures.
Conditions for safe storage, including any incompatibilities
Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and wellventilated
area, away from incompatible materials (see Section 10) and food and
drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Specific end use(s)
Recommendations: Not available
Industrial sector specific solutions: Not available
Protective measures: Put on appropriate personal protective equipment (see Section 8). Avoid breathing
dust. Avoid the creation of dust when handling and avoid all possible sources of
ignition (spark or flame). Prevent dust accumulation. Use only with adequate
ventilation. Wear appropriate respirator when ventilation is inadequate. Electrical
equipment and lighting should be protected to appropriate standards to prevent dust
coming into contact with hot surfaces, sparks or other ignition sources. Take
precautionary measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by earthing and bonding containers and
equipment before transferring material.
Advice on general occupational hygiene: Eating, drinking and smoking should be prohibited in areas where this material is
handled, stored and processed. Workers should wash hands and face before eating,
drinking and smoking. Remove contaminated clothing and protective equipment
before entering eating areas. See also Section Exposure controls for additional information on hygiene measures.
Conditions for safe storage, including any incompatibilities
Conditions for safe storage, including any incompatibilities: Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and wellventilated
area, away from incompatible materials (see Section 10) and food and
drink. Eliminate all ignition sources. Separate from oxidizing materials. Keep
container tightly closed and sealed until ready for use. Containers that have been
opened must be carefully resealed and kept upright to prevent leakage. Do not store in unlabelled containers. Use appropriate containment to avoid environmental contamination.
Specific end use(s)
Recommendations: Not available
Industrial sector specific solutions: Not available
Transport information
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Marine transport (UN RTDG/IMDG)
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Exposure controls / personal protection
Control parameters
Exposure limit values : Not available.
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.
Exposure controls
Appropriate engineering controls: Use only with adequate ventilation. If user operations generate dust, fumes, gas,
vapour or mist, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapour or dust concentrations below any lower explosive limits. The assessment of
potential dust hazards must be carried out based on handling and quantity.
Safeguards according relevant regulations must be applied.
Individual protection measures
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields. If operating conditions cause high dust concentrations to be produced,
use dust goggles.
Recommended: safety glasses with side-shields.
Skin protection
Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. After contamination with product change the gloves immediately
and dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) polyvinyl chloride (PVC) , Nitrile rubber - NBR
Other skin protection: Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Recommended: Wear protective clothing.
Respiratory protection: Use a properly fitted, particulate filter respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator.
Recommended: In case of dust formation particle filter.
Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Exposure limit values : Not available.
Recommended monitoring procedures: If this product contains ingredients with exposure limits, personal,
workplace atmosphere or biological monitoring may be required to
determine the effectiveness of the ventilation or other control
measures and/or the necessity to use respiratory protective
equipment. Reference should be made to monitoring standards,
such as the following: European Standard EN 689 (Workplace
atmospheres - Guidance for the assessment of exposure by
inhalation to chemical agents for comparison with limit values and
measurement strategy) European Standard EN 14042 (Workplace
atmospheres - Guide for the application and use of procedures for
the assessment of exposure to chemical and biological agents)
European Standard EN 482 (Workplace atmospheres - General
requirements for the performance of procedures for the
measurement of chemical agents) Reference to national guidance
documents for methods for the determination of hazardous
substances will also be required.
Exposure controls
Appropriate engineering controls: Use only with adequate ventilation. If user operations generate dust, fumes, gas,
vapour or mist, use process enclosures, local exhaust ventilation or other
engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas,
vapour or dust concentrations below any lower explosive limits. The assessment of
potential dust hazards must be carried out based on handling and quantity.
Safeguards according relevant regulations must be applied.
Individual protection measures
Hygiene measures: Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period.
Appropriate techniques should be used to remove potentially contaminated clothing.
Wash contaminated clothing before reusing. Ensure that eyewash stations and
safety showers are close to the workstation location.
Eye/face protection: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists,
gases or dusts. If contact is possible, the following protection should be worn,
unless the assessment indicates a higher degree of protection: safety glasses with
side-shields. If operating conditions cause high dust concentrations to be produced,
use dust goggles.
Recommended: safety glasses with side-shields.
Skin protection
Hand protection: Chemical-resistant, impervious gloves complying with an approved standard should
be worn at all times when handling chemical products if a risk assessment indicates
this is necessary. After contamination with product change the gloves immediately
and dispose of them according to relevant national and local regulations
Recommended: (< 1 hour) polyvinyl chloride (PVC) , Nitrile rubber - NBR
Other skin protection: Personal protective equipment for the body should be selected based on the task
being performed and the risks involved and should be approved by a specialist
before handling this product.
Recommended: Wear protective clothing.
Respiratory protection: Use a properly fitted, particulate filter respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must
be based on known or anticipated exposure levels, the hazards of the product and
the safe working limits of the selected respirator.
Recommended: In case of dust formation particle filter.
Environmental exposure controls: Emissions from ventilation or work process equipment should be checked to ensure
they comply with the requirements of environmental protection legislation. In some
cases, fume scrubbers, filters or engineering modifications to the process
equipment will be necessary to reduce emissions to acceptable levels.
Stability and reactivity
Reactivity : No specific test data related to reactivity available for this product or its ingredients.
Chemical stability: The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid : Impact sensitivity: Not impact-sensitive.
Incompatible materials: Reactive or incompatible with the following materials: oxidizing materials.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Chemical stability: The product is stable.
Possibility of hazardous reactions: Under normal conditions of storage and use, hazardous reactions will not occur.
Conditions to avoid : Impact sensitivity: Not impact-sensitive.
Incompatible materials: Reactive or incompatible with the following materials: oxidizing materials.
Hazardous decomposition products: Under normal conditions of storage and use, hazardous decomposition products should not be produced.
Disposal considerations
Waste treatment methods
Product
Methods of disposal: The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
Hazardous waste: Within the present knowledge of the supplier, this product is not regarded as
hazardous waste, as defined by EU Directive 2008/98/EC.
Packaging
Methods of disposal: The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way. Empty containers
or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Product
Methods of disposal: The generation of waste should be avoided or minimised wherever possible.
Disposal of this product, solutions and any by-products should at all times comply
with the requirements of environmental protection and waste disposal legislation and
any regional local authority requirements. Dispose of surplus and non-recyclable
products via a licensed waste disposal contractor. Waste should not be disposed of
untreated to the sewer unless fully compliant with the requirements of all authorities
with jurisdiction.
Hazardous waste: Within the present knowledge of the supplier, this product is not regarded as
hazardous waste, as defined by EU Directive 2008/98/EC.
Packaging
Methods of disposal: The generation of waste should be avoided or minimised wherever possible. Waste
packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible.
Special precautions: This material and its container must be disposed of in a safe way. Empty containers
or liners may retain some product residues. Avoid dispersal of spilt material and runoff and contact with soil, waterways, drains and sewers.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
