Registration Dossier

Administrative data

First-aid measures

Swallowing:
Give medicinal activated charcoal 10 g in 100 ml water at 20 minute intervals (5 x). In case of spontaneous vomiting ensure that vomitus can drain freely to avoid risk of suffocation. Drink water in small sips. (Diluting effect) Do not induce vomiting. In case of inconsciousness or convulsion no oral administration. Obtain medical attention immediately.
Inhalation:
Remove to fresh air. In case of irritation of respiratory system or mucous membranes or if feeling unwell or after prolonged exposure get medical attention.
Skin contact:
Wash with plenty of water or isopropanol. Do not use other organic solvents. Obtain medical attention if irritation persists.
Eye contact:
Immediately flush eyes with water and continue washing for at least 15 minutes. In case of eye irritation seek medical attention.

Fire-fighting measures

Flash point: 148 °C

Hazardous combustion products:
If handled as instructed: none

Special fire fighting procedures:
Do not release chemically contaminated water into drains, soil or surface water

Special protective equipment for firefighters:
Wear self-contained breathing apparatus

Extinguishing media:
Suitable:
water mist, foam, carbon dioxide, dry powder (ABC-powder)

Unsuitable:
high volume water jet

Unusual fire and explosion hazards:
In case of a fire aside from the major combustion products carbon dioxide and carbon monoxide other harmful gases and vapors may be formed, especially the formation of sulfur dioxide must be taken into account.

Accidental release measures

Personal precautions:
Do not breath vapors/aerosols. Eliminate sources of ignition. Avoid contact with skin and eyes.

Environmental precautions:
Prevent from entering sewer system, surface water or soil.

Methods for cleaning up:
Large quantities:
Dike spilled product with liquid absorbing material and pump off.
Small quantities:
Soak up with liquid absorbing material (sand etc.) and dispose of as instructed.

Handling and storage

Handling:
Handling precautions:
Avoid formation of vapors/aerosols. Keep away from sources of ignition - No smoking. Use only in well ventilated areas. On occurence of vapors/aerosols take technical measures for effective exhaust. Do not swallow. Avoid contact with skin and clothing. Avoid formation of vapors/aerosols. Keep away from heat, sparks and flame. Keep away from sources of ignition - No smoking. Use only in well ventilated areas. On occurence of vapors/aerosols take technical measures for effective exhaust.

Other precautions:
The material is combustible and can form ignitable, explosive air/vapor mixtures. Take precautionary measures against static discharges.

Storage:
Storage requirements:
Keep container tightly closed in a cool, well-ventilated place.

Further information on storage:
Avoid contact with oxidizing agents or strong acids/bases.

Transport information

Land transport (ADR/RID)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
Dibutyltin bis(2-ethylhexyl thioglycolate)
Language:
English
Class:
9
Classification code:
Hazard No.: M6
Packaging group:
III
Labels:
9
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
(Dibutyltin bis(2-ethylhexyl thioglycolate))
Class:
9
Packaging group:
III
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S.
Chemical name:
(Dibutyltin bis(2-ethylhexyl thioglycolate))
Class:
9
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure Limit values:

8 hours, skin = 0.1 mg/m^3
15 minutes, skin = 0.2 mg/m^3
VME = 0.1 mg/m^3
VLE = 0.2 mg/m^3

Engineering Controls:

Ventilation:
General mechanical room ventilation is satisfactory for normal handling and storage operations. If personnel exposure exceeds exposure limits, apply local exhaust ventilation. If the product is used at high temperatures or operations exist which may produce misting, local exhaust ventilation may be required.

Further information :
Provide for sufficient ventilation and/or exhaust

Personal Protection:

Respiratory protection:
Gas filter type A, if technical measures for exhaust are insufficient

Hand protection / protective gloves:
Gauntlet type gloves of nitrile rubber or butyl rubber recommended; for short time contact PVC is suitable

Eye protection:
Safety glasses

Skin protection:
Chemical resistant protective clothing. Closed footwear

Industrial hygiene measures:
When using do not eat, drink or smoke. Immediately remove contaminated clothing.


Stability and reactivity

Incompatible materials:
Oxidizing agents, acids, bases

Hazardous combustion products:
If handled as instructed: none

Disposal considerations

General:
Burn in compliance with operative regulations in a hazardous waste incinerator.

Non-cleaned packages:
Dispose of in the same way as product. Can be reused after cleaning. Dispose of washing solution in the same way as product.