Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Effects and symptoms : No known effects under normal conditions of use. In case of excessive ingestion, can cause nausea, diarrhea, abdominal pains.

First-Aid measures
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention.

Skin Contact : Flush contaminated skin with plenty of water. Remove contaminated clothing and shoes. Wash clothing before reuse. Get medical attention if irritation develops.

Eye Contact : In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention if irritation occurs.

Ingestion : Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical attention if symptoms appear.

Fire-fighting measures

Suitable Extinguishing Media : Use DRY chemicals, CO2, water spray or foam.

Not suitable : Do not use water jet.
Special exposure hazards : Carbon oxides (CO, CO2). When heated to decomposition it emits toxic fumes.

Protection of fire-fighters : Fire fighters should wear proper protective equipment. A self contained breathing apparatus should be used to avoid inhalation of the product.

Accidental release measures

Personal precautions : Avoid contact with eyes, skin or clothing. Avoid breathing vapors of this product. Wear suitable protective clothing, gloves and eye/face protection.

Environmental Precautions :
Small Spill : Absorb with an inert material and place in an appropriate waste disposal container. Keep out of waterways.
Large Spill : Dike spill area and do not allow product to reach sewage system and surface or ground water.
Methods for cleaning up : Absorb with DRY earth, sand or other non-combustible material. Pick up solids and put in an appropriate sealed container for later disposal

Handling and storage

Handling : Avoid contact with eyes, skin, and clothing. Avoid breathing vapors or spray mists. Use suitable protective equipment. Use with adequate ventilation. Wash thoroughly after handling.

Storage : Keep container tightly closed. Keep container in a cool, well-ventilated area. Empty containers retain product residue and can be hazardous.

Specific use(s) : Not applicable.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Occupational Exposure Limits
1) 2-ethylhexyl diphenyl phosphate
Not available

2) Triphenyl Phosphate
TWA: 3 (mg/m3) [Belgium Denmark Finland Netherlands Switzerland]
OEL: 3 STEL: 6 (mg/m3) [Ireland United Kingdom (UK)]
VME: 3 (mg/m3) [France]
TRGS 900: 3 (mg/m3) [Germany]

Occupational exposure controls

Engineering measures : Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location.
Personal Protection
Respiratory Protection : Do not breathe vapor or mist. Wear appropriate respirator when ventilation is inadequate. Seek professional advice prior to respirator selection and use.
Hand/Arm Protection : Gloves : Nitrile, Neoprene. Breakthrough time: Not determined.
Eye/Face Protection : Splash goggles. Avoid contact with eyes.
Skin Protection : Work uniform or laboratory coat.

Stability and reactivity

Stability : The product is stable.
Conditions to avoid : Not considered to be reactive.
Materials to avoid : Not known.

Hazardous Decomposition Products : Carbon oxides (CO, CO2). When heated to decomposition it emits toxic fumes.

Disposal considerations

Methods of disposal : Recycle, if possible. Incinerate waste materials. Dispose of according to all federal, state and local applicable regulations.

Contaminated packaging : Dispose of according to all federal, state and local applicable regulations.