Distillation residue, butyl alcohols production, rectification

GHS

General Information

Name:

Self classification of distillation residue, butyl alcohols production, rectification

Implementation:

EU

Remarks:

The classification of this UVCB-substance is done based on the experimental results of this target substance and based on the properties of surrogate substance 2-ethylhexanol which is present in this UVCB-substance at concentration range of 20-30 w-%. Acute oral and dermal fixed dose studies indicated no toxicity at 2000 mg/kg bw. Taken together with low expected exposure for human, this substance does not constitute the classification for category 5.

Related composition

Related composition:

Distillation residue, butyl alcohols production, rectification

Classification

Physical hazards

Explosives

Reason for no classification:

data conclusive but not sufficient for classification

Flammable gases and chemically unstable gases

Reason for no classification:

data conclusive but not sufficient for classification

Aerosols

Reason for no classification:

data conclusive but not sufficient for classification

Reason for no classification:

hazard class not assessed

Oxidising gases

Reason for no classification:

data conclusive but not sufficient for classification

Gases under pressure

Reason for no classification:

data conclusive but not sufficient for classification

Flammable liquids

Reason for no classification:

data conclusive but not sufficient for classification

Flammable solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-reactive substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric liquids

Reason for no classification:

data conclusive but not sufficient for classification

Pyrophoric solids

Reason for no classification:

data conclusive but not sufficient for classification

Self-heating substances and mixtures

Reason for no classification:

data conclusive but not sufficient for classification

Substances and mixtures which in contact with water emit flammable gases

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising liquids

Reason for no classification:

data conclusive but not sufficient for classification

Oxidising solids

Reason for no classification:

data conclusive but not sufficient for classification

Organic peroxides

Reason for no classification:

data conclusive but not sufficient for classification

Corrosive to metals

Reason for no classification:

data conclusive but not sufficient for classification

Desensitized explosives

Reason for no classification:

data lacking

Health hazards

Acute toxicity - oral

Reason for no classification:

data conclusive but not sufficient for classification

Acute toxicity - dermal

Reason for no classification:

data conclusive but not sufficient for classification

Acute toxicity - inhalation

Reason for no classification:

data conclusive but not sufficient for classification

Skin corrosion / irritation

Hazard category:

Skin Irrit. 2

Hazard statement:

H315: Causes skin irritation.

Serious eye damage / eye irritation

Hazard category:

Eye Irrit. 2

Hazard statement:

H320: Causes eye irritation.

Respiratory sensitisation

Reason for no classification:

data conclusive but not sufficient for classification

Skin sensitisation

Hazard category:

Skin Sens. 1

Hazard statement:

H317: May cause an allergic skin reaction.

Aspiration hazard

Hazard category:

Asp. Tox. 1

Hazard statement:

H304: May be fatal if swallowed and enters airways.

Reproductive toxicity

Reason for no classification:

data lacking

Effects on or via lactation

Reason for no classification:

data lacking

Germ cell mutagenicity

Reason for no classification:

data conclusive but not sufficient for classification

Carcinogenicity

Reason for no classification:

data lacking

1. Specific target organ toxicity - single (STOT-SE)

Hazard category:

STOT Single Exp. 3

Hazard statement:

H335: May cause respiratory irritation.

Affected organs:

other: respiratory tract

Route of exposure:

inhalation

1. Specific target organ toxicity - repeated (STOT-RE)

Reason for no classification:

data lacking

Environmental hazards

Hazardous to the aquatic environment (acute / short-term)

Reason for no classification:

data lacking

Hazardous to the aquatic environment (long-term)

Hazard category:

Aquatic Chronic 3

Hazard statement:

H412: Harmful to aquatic life with long lasting effects.

Hazardous to the ozone layer

Reason for no classification:

data conclusive but not sufficient for classification

Labelling

Signal word:

Danger

Hazard pictogram

GHS07: exclamation mark

GHS08: health hazard

Hazard statements

H304: May be fatal if swallowed and enters airways.

H315+H320: Causes skin and eye irritation.

H317: May cause an allergic skin reaction.

can be considered as rare allergen

H335: May cause respiratory irritation.

H412: Harmful to aquatic life with long lasting effects.

Precautionary statements

P273: Avoid release to the environment.

P280: Wear protective gloves/protective clothing/eye protection/face protection/hearing protection/...

P301+P310: IF SWALLOWED: Immediately call a POISON CENTER/doctor/…

P302+P352: IF ON SKIN: Wash with plenty of water/…

P331: Do NOT induce vomiting.

P333+P313: If skin irritation or rash occurs: Get medical advice/attention.

P362: Take off contaminated clothing.

P501: Dispose of contents/container to ...

Dispose of contents according to the national and/or local waste regulations