6-chloropyridazin-3-amine

Guidance on Safe Use

First-aid measures

4.1 Description of first aid measures

- General information Instantly remove any clothing soiled by the product.

- After inhalation

Call a doctor immediately.

Supply fresh air. Apply mouth-to mouth resuscitation or mechanical ventilation if necessary.

In case of unconsciousness bring patient into stable side position for transport.

- After skin contact Instantly rinse with water.

- After eye contact

Rinse opened eye for several minutes (10 - 15) under running water. Then consult doctor.

Use eye protection.

- After swallowing Instantly call for doctor.

Fire-fighting measures

Suitable extinguishing agents

CO2, extinguishing powder or water jet. Fight larger fire with alcohol-resistant foam.

Use fire fighting measures that suit the environment.

- 5.2 Special hazards arising from the substance or mixture

Hydrogen chloride (HCl)

Nitrogen oxides (NOx)

Carbon monoxide (CO), carbon dioxide (CO2)

- 5.3 Advice for firefighters

- Protective equipment:

Wear self-contained breathing apparatus.

Do not inhale explosion gases or combustion gases.

Wear full protective suit.

- Additional information

Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

Avoid causing dust.

Do not inhale dust.

Avoid contact with substance.

Evacuate the danger area, observe emergency procedures, consult an expert.

- 6.2 Environmental precautions: Do not allow product to reach sewage system or water bodies.

- 6.3 Methods and material for containment and cleaning up:

Dispose of contaminated material as waste according to item 13.

Collect mechanically.

Ensure adequate ventilation.

Send for recovery or disposal in suitable containers.

Transport information

Shipping

SpecialProvisions

Shipping

Remarks

Marine transport (UN RTDG/IMDG)

Shipping

Remarks

Shipping

Remarks

SpecialProvisions

Exposure controls / personal protection

- 8.2 Exposure controls

- Personal protective equipment

- General protective and hygienic measures

The usual precautionary measures should be adhered to general rules for handling chemicals.

Keep away from foodstuffs, beverages and food.

Take off immediately all contaminated clothing

Wash hands during breaks and at the end of the work.

Avoid contact with the eyes and skin.

Do not eat, drink or smoke while working.

Do not inhale dust

- Breathing equipment: Use breathing protection only if dust is formed.

- Recommended filter device for short term use:

Filter P3

The entrepreneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are

carried out according to the instructions of the manufacturer. These measures have to be properly

documented.

- Protection of hands:

Protective gloves (EN 374).

The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.

Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/

the chemical mixture.

To avoid skin problems reduce the wearing of gloves to the required minimum.

Selection of the glove material on consideration of the penetration times, rates of diffusion and the

degradation

- Material of gloves

The selection of the suitable gloves does not only depend on the material, but also on further marks of quality

and varies from manufacturer to manufacturer.

- Penetration time of glove material

The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be

observed.

The times listed are suggested by measurements taken at 22 degree C and constant contact. Temperatures

raised by warmed substances, body heat, etc. and a weakening of the effective layer thickness caused by

expansion can lead to a significantly shorter breakthrough time.

In case of doubt contact the gloves' manufacturer.

A 1.5-times increase / decrease in the layer thickness doubles / halves the breakthrough time. This data only

applies to the pure substance. Transferred to mixtures of substances, these figures should only be taken as an

aid to orientation.

- For the permanent contact gloves made of the following materials are suitable:

Nitrile rubber, NBR

Thickness of the material: 0.11 mm

Penetration time: > 480 min.

- As protection from splashes gloves made of the following materials are suitable:

Nitrile rubber, NBR

Thickness of the material: 0.11 mm

Penetration time: > 480 min.

- Remark:

This recommendation applies only to the product stated in the safety data sheet. When dissolving in or mixing

this substance with other substances and under conditions deviating from those stated in EN 374, please

contact the supplier of CE –approved gloves.

- Eye protection:

Tightly sealed safety glasses.

- Body protection:

Protective work clothing.

Protective clothing should be selected specifically for the working place, depending on concentration and

quantity of the hazardous substances handeld. The resistance of the protective clothing to chemicals should

be ascertained with the respective supplier.

Stability and reactivity

10.4 Conditions to avoid No further relevant information available.

- 10.5 Incompatible materials:

Reducing agents

Oxidizing agents

Disposal considerations

Recommendation

Hand over to disposers of hazardous waste.

Chemicals must be disposed of in compliance with restrictive national regulations.

- Uncleaned packagings:

- Recommendation:

Disposal must be made according to official regulations.

Packaging must be disposed of in compliance with country-specific regulations or must be passed to a

packaging return system.