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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
vapour pressure
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2017
Report date:
2018

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
OECD Guideline 104 (Vapour Pressure Curve)
Qualifier:
according to guideline
Guideline:
EU Method A.4 (Vapour Pressure)
Qualifier:
according to guideline
Guideline:
EPA OPPTS 830.7950 (Vapor Pressure)
GLP compliance:
yes
Type of method:
effusion method: isothermal thermogravimetry

Test material

Constituent 1
Chemical structure
Reference substance name:
Mercaptamine
EC Number:
200-463-0
EC Name:
Mercaptamine
Cas Number:
60-23-1
Molecular formula:
C2H7NS
IUPAC Name:
mercaptamine
Test material form:
solid: particulate/powder

Results and discussion

Vapour pressureopen allclose all
Test no.:
#1
Temp.:
20 °C
Vapour pressure:
12 Pa
Test no.:
#2
Temp.:
25 °C
Vapour pressure:
26 Pa

Any other information on results incl. tables

Table 1: Results of the Vapour pressure Isothermal TGA Analysis

Temperature
[°C]

Weight loss
[µg/min]

νT
[g/cm2/h]

logνT

logPT

PT
[Pa]

30

20.0912

2.40´10-3

-2.62

1.78

61

 

15.6240

1.86´10-3

-2.73

1.64

44

40

59.9978

7.16´10-3

-2.14

2.39

250

 

49.8077

5.95´10-3

-2.23

2.29

190

50

168.329

2.01´10-2

-1.70

2.96

920

 

144.428

1.72´10-2

-1.76

2.88

760

60

383.315

4.58´10-2

-1.34

3.42

2600

 

355.919

4.25´10-2

-1.37

3.38

2400

 

Table 2 : Vapour Pressure of the Test Item

Temperature
[°C]

logPT

PT
[Pa]

PT
[mm Hg]

20

1.09

12

9.1´10-2

Applicant's summary and conclusion

Conclusions:
The vapour pressure of mercaptamine at 20°C (293K) and 25°C (298K) was 12 and 26 Pa, respectively.