Registration Dossier

Administrative data

First-aid measures

4.1. Description of first aid measures
Remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention.

On skin contact:
Wash thoroughly with soap and water.

On contact with eyes:
Wash affected eyes for at least 15 minutes under running water with eyelids held open. If irritation develops, seek medical attention.

On ingestion:
Rinse mouth immediately and then drink plenty of water, seek medical attention.

4.2. Most important symptoms and effects, both acute and delayed
Symptoms: No significant reaction of the human body to the product known.

4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, carbon dioxide

5.2. Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.

5.3. Advice for fire-fighters
Special protective equipment:
Wear a self-contained breathing apparatus.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Handle in accordance with good industrial hygiene and safety practice.

6.2. Environmental precautions
Discharge into the environment must be avoided.

6.3. Methods and material for containment and cleaning up
For large amounts: Pump off product.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.

6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas.

Protection against fire and explosion:
Prevent electrostatic charge - sources of ignition should be kept well clear - fire extinguishers should be kept handy.

7.2. Conditions for safe storage, including any incompatibilities
Segregate from oxidants. Segregate from strong acids.
Further information on storage conditions: Containers should be stored tightly sealed in a dry place.

Storage stability:
Storage duration: 24 Months
May yellow after lengthy storage.
From the data on storage duration in this safety data sheet no agreed statement regarding the warrantee of application properties can be deduced.

7.3. Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

Transport information

Shippingopen allclose all
SpecialProvisionsopen allclose all
Shippingopen allclose all
Remarksopen allclose all

Marine transport (IMDG)

Remarksopen allclose all
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters

Components with occupational exposure limits

No occupational exposure limits known.

PNEC
freshwater: 0,1 mg/l

marine water: 0,01 mg/l

intermittent release: 1 mg/l

STP: 10 mg/l

sediment (freshwater): 0,372 mg/kg
sediment (marine water): 0,0372 mg/kg

soil: 0,0158 mg/kg

oral (secondary poisoning):
No PNEC oral derived, as accumulation in organisms is not to be expect.


8.2. Exposure controls
Personal protective equipment
Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.
Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:
Safety glasses with side-shields (frame goggles) (e.g. EN 166)

General safety and hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wearing of closed work clothing is required additionally to the stated personal protection equipment.

Stability and reactivity

10.1. Reactivity
No hazardous reactions if stored and handled as prescribed/indicated.

Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.


10.2. Chemical stability
The product is stable if stored and handled as prescribed/indicated.

10.3. Possibility of hazardous reactions
Evolution of heat under influence of acids.


10.4. Conditions to avoid
> 400 °C
Avoid all sources of ignition: heat, sparks, open flame.

10.5. Incompatible materials

Substances to avoid:
oxidizing agents, strong acids

10.6. Hazardous decomposition products

No hazardous decomposition products if stored and handled as prescribed/indicated.

Disposal considerations

13.1. Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.


Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.