Registration Dossier

Administrative data

First-aid measures

· General information
Symptoms of poisoning may even occur after several hours; therefore medical observation for at
least 48 hours after the accident.
· After inhalation Supply fresh air; consult doctor in case of symptoms.
· After skin contact
Immediately wash with water and soap and rinse thoroughly.
If skin irritation continues, consult a doctor.
· After eye contact
Rinse opened eye for several minutes under running water. If symptoms persist, consult doctor
· After swallowing In case of persistent symptoms consult doctor.

Fire-fighting measures

· Suitable extinguishing agents
Foam, carbon dioxide, dry powder, water spray.
Use fire fighting measures that suit the environment.
· Special hazards caused by the material, its products of combustion or resulting gases:
In case of fire harmful gases can be released.
· Protective equipment: Wear self-contained breathing apparatus.

Accidental release measures

· Person-related safety precautions: Not required.
· Measures for environmental protection:
Inform respective authorities in case product reaches water or sewage system.
· Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose of contaminated material as waste according to item Disposal considerations.
Ensure adequate ventilation.

Handling and storage

· Handling
· Information for safe handling:
Keep away from heat and direct sunlight.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires: No special measures required.
· Storage
· Requirements to be met by storerooms and containers: No special requirements.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions: Keep container tightly sealed.

Transport information

Land transport (ADR/RID)

UN number:
2278
Proper shipping name and description:
ORGANOTIN COMPOUND, LIQUID, N.O.S.
Chemical name:
(bis(pentane-2,4-
dionato)tin)
Language:
English
Class:
6.1
Classification code:
T3
Packaging group:
III
Labels:
6.1 + Symbol (fish and tree)
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
2278
Shippingopen allclose all
Class:
6.1
Classification code:
T3
Packaging group:
III
Labels:
6.1 + Symbol (fish and tree)
Remarksopen allclose all

Marine transport (IMDG)

UN number:
2278
Proper shipping name and description:
ORGANOTIN COMPOUND, LIQUID, N.O.S.
Chemical name:
(bis(pentane-2,4-dionato)
Class:
6.1
Packaging group:
III
EmS code:
F-A,S-A
Labels:
6.1 + Symbol (fish and tree)
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
2278
Proper shipping name and description:
ORGANOTIN COMPOUND, LIQUID, N.O.S.
Chemical name:
(bis(pentane-2,4-dionato)
tin)
Class:
6.1
Packaging group:
III
Labels:
6.1 + Symbol (fish and tree)
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

· Handling
· Information for safe handling:
Keep away from heat and direct sunlight.
Store in cool, dry place in tightly closed containers.
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
· Information about protection against explosions and fires: No special measures required.
· Storage
· Requirements to be met by storerooms and containers: No special requirements.
· Information about storage in one common storage facility: Store away from foodstuffs.
· Further information about storage conditions: Keep container tightly sealed.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
· Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or
longer exposure use breathing apparatus that is independent of circulating air.
· Protection of hands:
Protective gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
· Material of gloves
Plastic gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks
of quality and varies from manufacturer to manufacturer. As the product is a preparation of several
substances, the resistance of the glove material can not be calculated in advance and has therefore
to be checked prior to the application.
· Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and
has to be observed.
· Eye protection: Tightly sealed safety glasses.
· Body protection: Protective work clothing.

Stability and reactivity

· Thermal decomposition / conditions to be avoided: ca. 170 °C
· Materials to be avoided:
· Dangerous reactions No dangerous reactions known
· Dangerous products of decomposition: No dangerous decomposition products known

Disposal considerations

· Product:
· Recommendation Must be specially treated under adherence to official regulations.
· Uncleaned packagings:
· Recommendation: Disposal must be made according to official regulations