Registration Dossier
Registration Dossier
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EC number: 212-534-3 | CAS number: 824-72-6
Guidance on Safe Use
Guidance on Safe Use
Administrative data
First-aid measures
Description of first aid measures
General information
Take affected persons out of danger area and lay down.
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
After inhalation In case of unconsciousness place patient stably in side position for transportation.
After skin contact Immediately wash with water and soap and rinse thoroughly.
After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor
Most important symptoms and effects, both acute and delayed:Coughing, Breathing difficulty, skin irritation
Danger At swallowing alternatively vomiting eliminate the danger to penetrate the lungs.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
General information
Take affected persons out of danger area and lay down.
Immediately remove any clothing soiled by the product.
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident.
After inhalation In case of unconsciousness place patient stably in side position for transportation.
After skin contact Immediately wash with water and soap and rinse thoroughly.
After eye contact Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing Drink copious amounts of water and provide fresh air. Immediately call a doctor.
Information for doctor
Most important symptoms and effects, both acute and delayed:Coughing, Breathing difficulty, skin irritation
Danger At swallowing alternatively vomiting eliminate the danger to penetrate the lungs.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
Fire-fighting measures
Extinguishing media
Suitable extinguishing agents
CO2. Do not use water.
Extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents Water.
Special hazards arising from the substance or mixture
In case of fire, the following can be released:
hydrogen chloride (HCl)
phosphorous oxides (POx)
Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Suitable extinguishing agents
CO2. Do not use water.
Extinguishing powder. Do not use water.
For safety reasons unsuitable extinguishing agents Water.
Special hazards arising from the substance or mixture
In case of fire, the following can be released:
hydrogen chloride (HCl)
phosphorous oxides (POx)
Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.
Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Accidental release measures
Personal precautions, protective equipment and emergency procedures
Use breathing protection against the effect of vapours.
Ensure adequate ventilation
Avoid contact with the eyes and skin.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Prevent seepage into sewage system, workpits and cellars.
Prevent from spreading (e.g. by damming-in or oil barriers).
Methods and material for containment and cleaning up:
Absorb with liquid-binding material.
Use neutralizing agent.
Dispose contaminated material as waste according to local, regional, national and international regulations
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Protective Action Criteria for Chemicals
PAC-1:
Substance is not listed.
PAC-2:
Substance is not listed.
PAC-3:
Substance is not listed.
Use breathing protection against the effect of vapours.
Ensure adequate ventilation
Avoid contact with the eyes and skin.
Wear protective equipment. Keep unprotected persons away.
Environmental precautions:
Prevent seepage into sewage system, workpits and cellars.
Prevent from spreading (e.g. by damming-in or oil barriers).
Methods and material for containment and cleaning up:
Absorb with liquid-binding material.
Use neutralizing agent.
Dispose contaminated material as waste according to local, regional, national and international regulations
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
Protective Action Criteria for Chemicals
PAC-1:
Substance is not listed.
PAC-2:
Substance is not listed.
PAC-3:
Substance is not listed.
Handling and storage
Handling
Precautions for safe handling
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Product is combustible
Fumes can combine with air to form an explosive mixture.
Keep away from combustible materials, open flames and all sourses of heat.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
Use only receptacles specifically permitted for this substance/product.
Information about storage in one common storage facility: Store away from oxidizing agents.
Further information about storage conditions:
Protect from humidity and water.
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Storage class 8 A
Specific end use(s) No further relevant information available.
Precautions for safe handling
Ensure good interior ventilation, especially at floor level. (Fumes are heavier than air).
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
Information about protection against explosions and fires:
Product is combustible
Fumes can combine with air to form an explosive mixture.
Keep away from combustible materials, open flames and all sourses of heat.
Conditions for safe storage, including any incompatibilities
Storage
Requirements to be met by storerooms and receptacles:
Store only in the original receptacle.
Use only receptacles specifically permitted for this substance/product.
Information about storage in one common storage facility: Store away from oxidizing agents.
Further information about storage conditions:
Protect from humidity and water.
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
Storage class 8 A
Specific end use(s) No further relevant information available.
Transport information
Land transport (UN RTDG/ADR/RID)
- UN number:
- UN3265
Shippingopen allclose all
SpecialProvisionsopen allclose all
Inland waterway transport (UN RTDG/ADN(R))
- UN number:
- UN3265
Shippingopen allclose all
Remarksopen allclose all
Marine transport (UN RTDG/IMDG)
- UN number:
- UN3265
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(BENZENE PHOSPHOROUS OXYDICHLORIDE -
BPOD)
- Labels:
- CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(BENZENE PHOSPHOROUS OXYDICHLORIDE -
BPOD)
8
Remarksopen allclose all
Air transport (UN RTDG/ICAO/IATA)
- UN number:
- UN3265
Shipping information
- Proper shipping name and description:
- CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
(BENZENE PHOSPHOROUS OXYDICHLORIDE -
BPOD) - Chemical name:
- BENZENE PHOSPHOROUS OXYDICHLORIDE
- Labels:
- 8
Special precautions for user Warning: Corrosive substances
Danger code (Kemler): 80
EMS Number: F-A,S-B
Segregation groups Acids
Stowage Category B
Stowage Code SW2 Clear of living quarters.
Remarksopen allclose all
SpecialProvisionsopen allclose all
Exposure controls / personal protection
Additional information about design of technical systems: No further data; see section 7.
Control parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment
General protective and hygienic measures
Do not breathe vapours and aerosols.
Do not eat, drink, smoke or sniff while working.
Keep away from foodstuffs, beverages and feed.
Instantly remove any soiled and impregnated garments.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer
exposure use breathing apparatus that is independent of circulating air.
Protection of hands:
Protective gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Full contact:
Glove thickness: ≥ 0.7 mm
Breakthrough time: ≥ 480 min
As protection from splashes gloves made of the following materials are suitable:
Nitrile rubber, NBR
Splash contact:
Glove thickness: ≥ 0.4 mm
Break through time: ≥ 30 min
Eye protection:
Tightly sealed goggles.
Body protection: Protective work clothing.
Control parameters
Components with limit values that require monitoring at the workplace: Not required.
Additional information: The lists that were valid during the creation were used as basis.
Exposure controls
Personal protective equipment
General protective and hygienic measures
Do not breathe vapours and aerosols.
Do not eat, drink, smoke or sniff while working.
Keep away from foodstuffs, beverages and feed.
Instantly remove any soiled and impregnated garments.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer
exposure use breathing apparatus that is independent of circulating air.
Protection of hands:
Protective gloves.
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the
preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of
quality and varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has
to be observed.
For the permanent contact gloves made of the following materials are suitable:
Butyl rubber, BR
Full contact:
Glove thickness: ≥ 0.7 mm
Breakthrough time: ≥ 480 min
As protection from splashes gloves made of the following materials are suitable:
Nitrile rubber, NBR
Splash contact:
Glove thickness: ≥ 0.4 mm
Break through time: ≥ 30 min
Eye protection:
Tightly sealed goggles.
Body protection: Protective work clothing.
Stability and reactivity
Reactivity No further relevant information available.
Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents.
Reacts with alcohols, amines, aqueous acids and alkalis
Contact with water releases irritant gases
Conditions to avoid heat, ignition sources
Incompatible materials:
Reacts with water to hydrolytic decomposition product.
strong oxidizing agent.
Hazardous decomposition products:
hydrogen chloride (HCl)
Phosphorus oxides (POx)
Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Possibility of hazardous reactions
Reacts with strong oxidizing agents.
Reacts with alcohols, amines, aqueous acids and alkalis
Contact with water releases irritant gases
Conditions to avoid heat, ignition sources
Incompatible materials:
Reacts with water to hydrolytic decomposition product.
strong oxidizing agent.
Hazardous decomposition products:
hydrogen chloride (HCl)
Phosphorus oxides (POx)
Disposal considerations
Waste treatment methods
Recommendation
Dispose of contents and container in accordance with local, regional, national and international
regulations
Cannot be dispose of with household garbage. Do not disposed of into drains.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Recommendation
Dispose of contents and container in accordance with local, regional, national and international
regulations
Cannot be dispose of with household garbage. Do not disposed of into drains.
Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
Information on Registered Substances comes from registration dossiers which have been assigned a registration number. The assignment of a registration number does however not guarantee that the information in the dossier is correct or that the dossier is compliant with Regulation (EC) No 1907/2006 (the REACH Regulation). This information has not been reviewed or verified by the Agency or any other authority. The content is subject to change without prior notice.
Reproduction or further distribution of this information may be subject to copyright protection. Use of the information without obtaining the permission from the owner(s) of the respective information might violate the rights of the owner.
