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EC number: 269-145-7 | CAS number: 68188-19-2
- Life Cycle description
- Uses advised against
- Endpoint summary
- Appearance / physical state / colour
- Melting point / freezing point
- Boiling point
- Density
- Particle size distribution (Granulometry)
- Vapour pressure
- Partition coefficient
- Water solubility
- Solubility in organic solvents / fat solubility
- Surface tension
- Flash point
- Auto flammability
- Flammability
- Explosiveness
- Oxidising properties
- Oxidation reduction potential
- Stability in organic solvents and identity of relevant degradation products
- Storage stability and reactivity towards container material
- Stability: thermal, sunlight, metals
- pH
- Dissociation constant
- Viscosity
- Additional physico-chemical information
- Additional physico-chemical properties of nanomaterials
- Nanomaterial agglomeration / aggregation
- Nanomaterial crystalline phase
- Nanomaterial crystallite and grain size
- Nanomaterial aspect ratio / shape
- Nanomaterial specific surface area
- Nanomaterial Zeta potential
- Nanomaterial surface chemistry
- Nanomaterial dustiness
- Nanomaterial porosity
- Nanomaterial pour density
- Nanomaterial photocatalytic activity
- Nanomaterial radical formation potential
- Nanomaterial catalytic activity
- Endpoint summary
- Stability
- Biodegradation
- Bioaccumulation
- Transport and distribution
- Environmental data
- Additional information on environmental fate and behaviour
- Ecotoxicological Summary
- Aquatic toxicity
- Endpoint summary
- Short-term toxicity to fish
- Long-term toxicity to fish
- Short-term toxicity to aquatic invertebrates
- Long-term toxicity to aquatic invertebrates
- Toxicity to aquatic algae and cyanobacteria
- Toxicity to aquatic plants other than algae
- Toxicity to microorganisms
- Endocrine disrupter testing in aquatic vertebrates – in vivo
- Toxicity to other aquatic organisms
- Sediment toxicity
- Terrestrial toxicity
- Biological effects monitoring
- Biotransformation and kinetics
- Additional ecotoxological information
- Toxicological Summary
- Toxicokinetics, metabolism and distribution
- Acute Toxicity
- Irritation / corrosion
- Sensitisation
- Repeated dose toxicity
- Genetic toxicity
- Carcinogenicity
- Toxicity to reproduction
- Specific investigations
- Exposure related observations in humans
- Toxic effects on livestock and pets
- Additional toxicological data
Vapour pressure
Administrative data
- Endpoint:
- vapour pressure
- Type of information:
- experimental study
- Adequacy of study:
- key study
- Study period:
- Testing was conducted between 15 April 2010 and 07 May 2010.
- Reliability:
- 1 (reliable without restriction)
- Rationale for reliability incl. deficiencies:
- other: see 'Remark'
- Remarks:
- Study conducted in compliance with agreed protocols, with no or minor deviations from standard test guidelines and/or minor methodological deficiencies, which do not affect the quality of the relevant results. The study report was conclusive, done to a valid guideline and the study was conducted under GLP conditions.
Data source
Reference
- Reference Type:
- study report
- Title:
- Unnamed
- Year:
- 2 010
- Report date:
- 2010
Materials and methods
Test guideline
- Qualifier:
- according to guideline
- Guideline:
- EU Method A.4 (Vapour Pressure)
- Deviations:
- no
- GLP compliance:
- yes (incl. QA statement)
- Type of method:
- effusion method: vapour pressure balance
Test material
- Reference substance name:
- SULFOCLOR LF 1013
- IUPAC Name:
- SULFOCLOR LF 1013
- Reference substance name:
- Paraffin waxes and Hydrocarbon waxes, chloro, sulfochlorinated
- EC Number:
- 269-145-7
- EC Name:
- Paraffin waxes and Hydrocarbon waxes, chloro, sulfochlorinated
- Cas Number:
- 68188-19-2
- Molecular formula:
- CnHxCly(SO2Cl)z n= 14 - 17 or n=17 - 30 ; x=2n+2-y-z
- IUPAC Name:
- Paraffin waxes and Hydrocarbon waxes, chloro, sulfochlorinated
- Details on test material:
- Sponsor's identification: SULFOCLOR LF 1013
CAS No : 68188-19-2
Description : pale yellow slightly viscous liquid
Purity : >99%
Batch number: None supplied
Label : Sulfoclor LF 1013 TANQUE 25.09.2009
Date received: 05 February 2010
Expiry date : 23 September 2010
Storage conditions: room temperature in the dark
Constituent 1
Constituent 2
Results and discussion
Vapour pressure
- Temp.:
- 25 °C
- Vapour pressure:
- 0.001 Pa
Transition / decomposition
- Transition / decomposition:
- no
Any other information on results incl. tables
Results
Run1
Temperature (ºC) |
Temperature (K) |
Reciprocal Temperature (K-1) |
Mass Difference (µg) |
Mass Difference (kg) |
Vapour Pressure (Pa) |
Log10Vp |
66 |
339.15 |
0.002948548 |
69.89 |
6.989E-08 |
0.097025226 |
-1.013115338 |
67 |
340.15 |
0.002939879 |
74.88 |
7.488E-08 |
0.103952624 |
-0.983164543 |
68 |
341.15 |
0.002931262 |
80.67 |
8.067E-08 |
0.111990628 |
-0.950818322 |
69 |
342.15 |
0.002922695 |
88.06 |
8.806E-08 |
0.122249841 |
-0.912751698 |
70 |
343.15 |
0.002914177 |
97.75 |
9.775E-08 |
0.135702043 |
-0.867413613 |
71 |
344.15 |
0.002905710 |
105.93 |
1.059E-07 |
0.147057979 |
-0.832511406 |
72 |
345.15 |
0.002897291 |
116.82 |
1.168E-07 |
0.162176089 |
-0.790013177 |
73 |
346.15 |
0.002888921 |
133.89 |
1.339E-07 |
0.185873622 |
-0.730782237 |
74 |
347.15 |
0.002880599 |
140.88 |
1.409E-07 |
0.195577533 |
-0.708681036 |
75 |
348.15 |
0.002872325 |
155.76 |
1.558E-07 |
0.216234785 |
-0.665074440 |
A plot of Log10(vapour pressure (Pa)) versus reciprocal temperature (1/T(K)) for Run 1 gives the following statistical data using an unweighted least squares treatment.
Slope
-4691.089
Standard deviation in slope 113.046
Intercept 12.806
Standard deviation in intercept 0.329
The results obtained indicate the following vapour pressure relationship:
Log10(Vp (Pa)) = -4691.089 /temp(K) + 12.086
The above yields a vapour pressure (Pa) at 298.15 K with a common logarithm of -2.928.
Run 2
Temperature (ºC) |
Temperature (K) |
Reciprocal Temperature (K-1) |
Mass Difference (µg) |
Mass Difference (kg) |
Vapour Pressure (Pa) |
Log10Vp |
66 |
339.15 |
0.002948548 |
68.89 |
6.889E-08 |
0.095636970 |
-1.019374194 |
67 |
340.15 |
0.002939879 |
76.48 |
7.648E-08 |
0.106173834 |
-0.973982499 |
68 |
341.15 |
0.002931262 |
80.37 |
8.037E-08 |
0.111574151 |
-0.952436410 |
69 |
342.15 |
0.002922695 |
86.76 |
8.676E-08 |
0.120445108 |
-0.919210835 |
70 |
343.15 |
0.002914177 |
95.35 |
9.535E-08 |
0.132370229 |
-0.878209681 |
71 |
344.15 |
0.002905710 |
107.63 |
1.076E-07 |
0.149418015 |
-0.825597038 |
72 |
345.15 |
0.002897291 |
121.41 |
1.214E-07 |
0.168548185 |
-0.773275920 |
73 |
346.15 |
0.002888921 |
127.50 |
1.275E-07 |
0.177002665 |
-0.752020194 |
74 |
347.15 |
0.002880599 |
138.88 |
1.389E-07 |
0.192801021 |
-0.714890671 |
75 |
348.15 |
0.002872325 |
150.96 |
1.510E-07 |
0.209571156 |
-0.678668492 |
A plot of Log10(vapour pressure (Pa)) versus reciprocal temperature (1/T(K)) for Run 2 gives the following statistical data using an unweighted least squares treatment.
Slope -4559.896
Standard deviation in slope 128.286
Intercept 12.421
Standard deviation in intercept 0.373
The results obtained indicate the following vapour pressure relationship:
Log10(Vp (Pa)) = -4559.896 /temp(K) + 12.421
The above yields a vapour pressure (Pa) at 298.15 K with a common logarithm of -2.873.
Run 3
Temperature (ºC) |
Temperature (K) |
Reciprocal Temperature (K-1) |
Mass Difference (µg) |
Mass Difference (kg) |
Vapour Pressure (Pa) |
Log10Vp |
66 |
339.15 |
0.002948548 |
64.70 |
6.470E-08 |
0.089820176 |
-1.046626098 |
67 |
340.15 |
0.002939879 |
68.69 |
6.869E-08 |
0.095359318 |
-1.020636862 |
68 |
341.15 |
0.002931262 |
73.88 |
7.388E-08 |
0.102564368 |
-0.989003492 |
69 |
342.15 |
0.002922695 |
80.47 |
8.047E-08 |
0.111712976 |
-0.951896377 |
70 |
343.15 |
0.002914177 |
89.46 |
8.946E-08 |
0.124193400 |
-0.905901485 |
71 |
344.15 |
0.002905710 |
96.45 |
9.645E-08 |
0.133897310 |
-0.873228147 |
72 |
345.15 |
0.002897291 |
106.23 |
1.062E-07 |
0.147474456 |
-0.831283197 |
73 |
346.15 |
0.002888921 |
116.32 |
1.163E-07 |
0.161481961 |
-0.791875985 |
74 |
347.15 |
0.002880599 |
130.20 |
1.302E-07 |
0.180750957 |
-0.742919394 |
75 |
348.15 |
0.002872325 |
140.68 |
1.407E-07 |
0.195299882 |
-0.709298019 |
A plot of Log10(vapour pressure (Pa)) versus reciprocal temperature (1/T(K)) for Run 3 gives the following statistical data using an unweighted least squares treatment.
Slope -4549.776
Standard deviation in slope 102.515
Intercept 12.354
Standard deviation in intercept 0.298
The results obtained indicate the following vapour pressure relationship:
Log10(Vp (Pa)) = -4549.776 /temp(K) + 12.354
The above yields a vapour pressure (Pa) at 298.15 K with a common logarithm of -2.906.
Run 4
Temperature (ºC) |
Temperature (K) |
Reciprocal Temperature (K-1) |
Mass Difference (µg) |
Mass Difference (kg) |
Vapour Pressure (Pa) |
Log10Vp |
66 |
339.15 |
0.002948548 |
63.20 |
6.320E-08 |
0.087737792 |
-1.056813300 |
67 |
340.15 |
0.002939879 |
67.19 |
6.719E-08 |
0.093276934 |
-1.030225738 |
68 |
341.15 |
0.002931262 |
71.99 |
7.199E-08 |
0.099940564 |
-1.000258205 |
69 |
342.15 |
0.002922695 |
77.48 |
7.748E-08 |
0.107562090 |
-0.968340767 |
70 |
343.15 |
0.002914177 |
84.77 |
8.477E-08 |
0.117682478 |
-0.929288196 |
71 |
344.15 |
0.002905710 |
98.15 |
9.815E-08 |
0.136257346 |
-0.865640075 |
72 |
345.15 |
0.002897291 |
102.34 |
1.023E-07 |
0.142074139 |
-0.847484966 |
73 |
346.15 |
0.002888921 |
113.92 |
1.139E-07 |
0.158150146 |
-0.800930402 |
74 |
347.15 |
0.002880599 |
122.51 |
1.225E-07 |
0.170075267 |
-0.769358839 |
75 |
348.15 |
0.002872325 |
139.28 |
1.393E-07 |
0.193356323 |
-0.713641621 |
A plot of Log10(vapour pressure (Pa)) versus reciprocal temperature (1/T(K)) for Run 4 gives the following statistical data using an unweighted least squares treatment.
Slope -4533.377
Standard deviation in slope 148.081
Intercept 12.295
Standard deviation in intercept 0.431
The results obtained indicate the following vapour pressure relationship:
Log10(Vp (Pa)) = -4533.377 /temp(K) + 12.295
The above yields a vapour pressure (Pa) at 298.15 K with a common logarithm of -2.910.
Run 5
Temperature (ºC) |
Temperature (K) |
Reciprocal Temperature (K-1) |
Mass Difference (µg) |
Mass Difference (kg) |
Vapour Pressure (Pa) |
Log10Vp |
66 |
339.15 |
0.002948548 |
60.01 |
6.001E-08 |
0.083309254 |
-1.079306752 |
67 |
340.15 |
0.002939879 |
64.50 |
6.450E-08 |
0.089542525 |
-1.047970664 |
68 |
341.15 |
0.002931262 |
69.69 |
6.969E-08 |
0.096747574 |
-1.014359914 |
69 |
342.15 |
0.002922695 |
75.58 |
7.558E-08 |
0.104924403 |
-0.979123491 |
70 |
343.15 |
0.002914177 |
82.37 |
8.237E-08 |
0.114350663 |
-0.941761313 |
71 |
344.15 |
0.002905710 |
90.86 |
9.086E-08 |
0.126136958 |
-0.899157646 |
72 |
345.15 |
0.002897291 |
99.74 |
9.974E-08 |
0.138464673 |
-0.858661015 |
73 |
346.15 |
0.002888921 |
109.83 |
1.098E-07 |
0.152472178 |
-0.816809395 |
74 |
347.15 |
0.002880599 |
119.81 |
1.198E-07 |
0.166326975 |
-0.779037311 |
75 |
348.15 |
0.002872325 |
132.29 |
1.323E-07 |
0.183652413 |
-0.736003362 |
A plot of Log10(vapour pressure (Pa)) versus reciprocal temperature (1/T(K)) for Run 5 gives the following statistical data using an unweighted least squares treatment.
Slope -4552.739
Standard deviation in slope 82.290
Intercept 12.334
Standard deviation in intercept 0.293
The results obtained indicate the following vapour pressure relationship:
Log10(Vp (Pa)) = -4552.739 /temp(K) + 12.334
The above yields a vapour pressure (Pa) at 298.15 K with a common logarithm of -2.936.
Run 6
Temperature (ºC) |
Temperature (K) |
Reciprocal Temperature (K-1) |
Mass Difference (µg) |
Mass Difference (kg) |
Vapour Pressure (Pa) |
Log10Vp |
66 |
339.15 |
0.002948548 |
59.01 |
5.901E-08 |
0.081920998 |
-1.086604764 |
67 |
340.15 |
0.002939879 |
62.80 |
6.280E-08 |
0.087182489 |
-1.059570735 |
68 |
341.15 |
0.002931262 |
67.59 |
6.759E-08 |
0.093832236 |
-1.027647932 |
69 |
342.15 |
0.002922695 |
74.18 |
7.418E-08 |
0.102980845 |
-0.987243550 |
70 |
343.15 |
0.002914177 |
80.77 |
8.077E-08 |
0.112129453 |
-0.950280296 |
71 |
344.15 |
0.002905710 |
91.56 |
9.156E-08 |
0.127108738 |
-0.895824595 |
72 |
345.15 |
0.002897291 |
95.85 |
9.585E-08 |
0.133064357 |
-0.875938262 |
73 |
346.15 |
0.002888921 |
111.62 |
1.116E-07 |
0.154957157 |
-0.809788361 |
74 |
347.15 |
0.002880599 |
119.91 |
1.199E-07 |
0.166465801 |
-0.778674976 |
75 |
348.15 |
0.002872325 |
129.00 |
1.290E-07 |
0.179085050 |
-0.746940668 |
A plot of Log10(vapour pressure (Pa)) versus reciprocal temperature (1/T(K)) for Run 6 gives the following statistical data using an unweighted least squares treatment.
Slope -4650.943
Standard deviation in slope 132.149
Intercept 12.613
Standard deviation in intercept 0.385
The results obtained indicate the following vapour pressure relationship:
Log10(Vp (Pa)) = -4650.943 /temp(K) + 12.613
The above yields a vapour pressure (Pa) at 298.15 K with a common logarithm of -2.986.
Please see Attachment 3 for Graphs of Log10 Vapour Pressure vs Reciprocal Temperature Runs 1 - 6
Summary of Results
Run |
Log10[Vp(25ºC)] |
1 |
-2.928 |
2 |
-2.873 |
3 |
-2.906 |
4 |
-2.910 |
5 |
-2.936 |
6 |
-2.986 |
Mean |
-2.923 |
Vapour Pressure |
1.2 x 10-3Pa |
The test item did not change in appearance under the conditions used in the determination.
Applicant's summary and conclusion
- Conclusions:
- The vapour pressure of Sulfoclor LF 1013 has been determined to be 1.2 x 10E-3 Pa at 25ºC
- Executive summary:
The hazardous physico-chemical properties of Sulfoclor LF 1013 have been determined. Methods employed were compatible with those detailed in Commission Regulation (EC) No 440/2008 of 30 May 2008, Part A: Methods for the determination of physico-chemical properties.
Method
The vapour pressure was determined using a vapour pressure balance, with measurents being made at several temperatures and linear regression analysis used to calculate the vapour pressure at 25°C. The method employed was designed to be compatible with Method A4 Vapour Pressure of Commission Regulation (EC) No 440/2008 of 30 May 2008.Conclusion
The vapour pressure of Sulfoclor LF 1013 has been determined to be 1.2 x 10-3 Pa at 25ºC.
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