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Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

4.1. Description of first aid measures

General advice:

First aider needs to protect himself.Take off all contaminated clothing immediately. Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.

Inhalation:

Move subject to fresh air and keep him calm. In case of discomfort: Supply with medical care.

Skin contact:

If skin irritation occurs consult a physician. Wash off immediately with soap and water.

Eye contact:

Flush eyes thoroughly with a large amount of water and consult a physician.

Ingestion:

Do not induce vomiting. Get medical attention immediately.

4.2. Most important symptoms and effects, both acute and delayed

Skin irritation Serious eye irritation cough, sneezing. sensitising effects

4.3. Indication of any immediate medical attention and special treatment needed

Treat symptomatically.

Fire-fighting measures

5.1. Extinguishing media

Suitable extinguishing media:

foam

dry chemical

carbon dioxide

Unsuitable extinguishing media:

High volume water jet

5.2. Special hazards arising from the substance or mixture

May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.

5.3. Advice for firefighters

Special fire fighting procedures:

Keep away from sources of ignition - No smoking. Take action to prevent static discharges. In the event of fire, cool the endangered containers with

water. Vapors are heavier than air and may spread along floors. When heated above the flash point and/or during spraying (atomizing), ignitible

mixtures may form in air.

Special protective equipment for fire-fighters: Wear self-contained breathing apparatus.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures

Assure sufficient ventilation.

Use personal protective clothing.

Keep away sources of ignition.

Use breathing apparatus if exposed to vapours/dust/mist/aerosol.

Do not breathe vapours or spray mist.

Do not eat, drink or smoke when using this product.

6.2. Environmental precautions

Do not discharge into the drains/surface waters/groundwater.

6.3. Methods and material for containment and cleaning up

Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment!

Smaller quantities and/or residues:

Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust).

Dispose of contaminated material in accordance  as prescribed

6.4. Reference to other sections

For personal protection see section 8.

For disposal considerations see section 13.

Handling and storage

7.1. Precautions for safe handling

Technical measures (e.g. Local and general ventilation):

For monitoring procedures refer for instance to "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health

Safe handling advice:

Do not breathe vapors. Avoid contact with skin and eyes. Do not eat, drink or smoke during use.Keep away from sources of ignition - No smoking.

Take action to prevent static discharges. In the event of fire, cool the endangered containers with water. Vapors are heavier than air and may

spread along floors. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air.Keep container

tightly closed. Ensure there is good room ventilation.

7.2. Conditions for safe storage, including any incompatibilities

Safe storage conditions: Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability. Keep only in the original container at a temperature not exceeding 30 °C. Can polymerize with intense heat

release. Protect from the action of light.

7.3. Specific end use(s)

We are unaware of any specific end uses which go beyond the data reported in Section 1.

Transport information

Land transport (UN RTDG/ADR/RID)

UN number:
UN 3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., STABILIZED (isobornyl acrylate), 9, III, (E)
Hazard no. 90
Chemical name:
Isobornyl acrylate
Packing group:
Packing group III: Substances presenting low danger
SpecialProvisionsopen allclose all

Inland waterway transport (UN RTDG/ADN(R))

UN number:
UN 3082
Shippingopen allclose all
Remarksopen allclose all

Marine transport (UN RTDG/IMDG)

UN number:
3082
Shipping information
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S., STABILIZED (isobornyl acrylate)
Chemical name:
isobornyl acrylate
Packing group:
Packing group III: Substances presenting low danger
Marine pollutant
Remarksopen allclose all

Air transport (UN RTDG/ICAO/IATA)

UN number:
3082
Shipping information
Proper shipping name and description:
Environmentally hazardous substance, liquid, n.o.s., STABILIZED (isobornyl acrylate)
Chemical name:
isobornyl acrylate
Packing group:
Packing group III: Substances presenting low danger
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters

see section 8.2.

8.2. Exposure controls

For monitoring procedures refer to for instance "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health

DNEL-Values

Critical component       Type              Route of Exposure       Health Warnings              Remarks

isobornyl acrylate       Workers              Inhalation              Systemic, long-term; 4.9 mg/m3       Repeated dose toxicity

             General population       Inhalation              Systemic, long-term; 1.45 mg/m3       Repeated dose toxicity

             General population       Dermal              Systemic, long-term; 0.83 mg/kg       Repeated dose toxicity

             General population       Oral              Systemic, long-term; 0.83 mg/kg       Repeated dose toxicity

             Workers              Dermal              Systemic, long-term; 1.39 mg/kg       Repeated dose toxicity

             General population       Eyes              Local effects;              No hazard identified

             Workers              Eyes              Local effects;              No hazard identified

Remarks: DNEL-Values

Critical component       Type              Route of Exposure       Health Warnings              Remarks

isobornyl acrylate       Workers              Inhalation              Systemic, long-term; 4.9 mg/m3       Repeated dose toxicity

             General population       Inhalation              Systemic, long-term; 1.45 mg/m3       Repeated dose toxicity

             General population       Dermal              Systemic, long-term; 0.83 mg/kg       Repeated dose toxicity

             General population       Oral              Systemic, long-term; 0.83 mg/kg       Repeated dose toxicity

             Workers              Dermal              Systemic, long-term; 1.39 mg/kg       Repeated dose toxicity

             General population       Eyes              Local effects;              No hazard identified

             Workers              Eyes              Local effects;              No hazard identified

PNEC-Values

Critical component       Environmental compartment       PNEC-Values       Remarks

isobornyl acrylate       Soil                     0.029 mg/kg

             Sewage treatment plant              2 mg/l

             marine water sediment              0.015 mg/kg

             freshwater                     0.001 mg/l

             marine water              0 mg/l

             freshwater sediment              0.145 mg/kg

Remarks: PNEC-Values

Critical component       Environmental compartment       PNEC-Values       Remarks

isobornyl acrylate       Soil                     0.029 mg/kg

             Sewage treatment plant              2 mg/l

             marine water sediment              0.015 mg/kg

             freshwater                     0.001 mg/l

             marine water              0 mg/l

             freshwater sediment              0.145 mg/kg

Individual protection measures, such as personal protective equipment

Eye/face protection: Tightly fitting safety goggles

Hand Protection: Material: Butyl rubber.

Break-through time: 480 min

Glove thickness: 0.3 mm

Guideline: EN 374

Additional Information: Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of

the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the

contact time., The above mentioned hand protection is based on special knowledge of the chemical and the intended handling of this product,

however, it still may not be suited for all workplaces. A qualified hazard assessment should be made prior to the onset of work in order to determine

the suitability of gloves for specific working environments and processes.,

Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Skin and Body Protection: On handling of larger quantities: face mask, chemical-resistant boots and apron

Respiratory Protection: Breathing apparatus in case of high concentrations short term: filter appliance, filter A

Hygiene measures:

Store work clothing separately. Immediately remove contaminated clothing.

Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream.

Stability and reactivity

10.1. Reactivity

No data available.

10.2. Chemical stability

No decomposition if used as directed.

10.3. Possibility of hazardous reactions

Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.

10.4. Conditions to avoid

Ultraviolet light. Avoid high temperatures and sources of ignition.The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.

10.5. Incompatible materials

Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing agents and oxidizing agents.

10.6. Hazardous decomposition products

None when used as directed.

Disposal considerations

13.1. Waste treatment methods

General information: Dispose of waste and residues in accordance with local authority requirements.

Disposal methods: Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the

disposal company in a suitable and licensed facility. Strictly controlled conditions during disposal or treatment to air, wastewater and waste. Do

not add wastewater to a biological wastewater treatment plant Bring wastewater containing AOX for professional disposal. The waste key

number must be determined as per the European Waste Types List (decision on EU Waste Types List 2000/532/EC) in cooperation with the

disposal firm / producing firm / official authority

Contaminated packaging:

Contaminated packaging should ideally be emptied; it can then be recycled after having been decontaminated.

Packaging that cannot be cleaned should be disposed of professionally.

Uncontaminated packaging may be taken for recycling.

Code of waste EWC:

07 02 08

waste from the manufacture, formulation, supply and use (MFSU) of plastics, synthetic rubber and man-made fibres - other still bottoms and reaction residues

Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities.