Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
mode of degradation in actual use
Type of information:
experimental study
Adequacy of study:
key study
Reliability:
2 (reliable with restrictions)
Rationale for reliability incl. deficiencies:
other: Review article in handbook giving basic information about reaction process during vulcanisation

Data source

Reference
Reference Type:
review article or handbook
Title:
Unnamed
Year:
1965

Materials and methods

Principles of method if other than guideline:
no guideline followed
GLP compliance:
no
Type of study / information:
Published company information

Test material

Constituent 1
Reference substance name:
10591-84-2
IUPAC Name:
10591-84-2
Constituent 2
Reference substance name:
N, N'-Dimethyl-N,N'-diphenylthiuramdisulfide
IUPAC Name:
N, N'-Dimethyl-N,N'-diphenylthiuramdisulfide
Constituent 3
Reference substance name:
Vulkacit I
IUPAC Name:
Vulkacit I
Test material form:
solid: particulate/powder
Remarks:
migrated information: powder
Details on test material:
Purity is not specified

Results and discussion

Applicant's summary and conclusion

Conclusions:
The substance is used as an accelerator used in rubber industry. The first step during the curing process is the symmetrical cleavage of the substance in 2 radicals: R2 N-CO-S-S-CO-NR2 --> 2 R2N-CO-S*
This radical is able to react with aliphatic chains contained in the rubber matrix.(e.g. isobutylene groups). The radicals are reactive species which are added to double bonds. Thus, the substance is consumed during the vulcanisation step. As isobutylene groups are available in great excess it is most likely that practically no unreacted substance is still present in rubber after vulcanisation
Executive summary:

The substance is used as an accelerator used in rubber industry. The first step during the curing process is the symmetrical cleavage of the substance in 2 radicals:

R2 N-CO-S-S-CO-NR2 --> 2 R2N-CO-S*

This radical is able to react with aliphatic chains contained in the rubber matrix.(e.g. isobutylene groups). The radicals are reactive species which are added to double bonds. Thus, the substance is consumed during the vulcanisation step. As isobutylene groups are available in great excess it is most likely that practically no unreacted substance is still present in rubber after vulcanisation