Registration Dossier

Administrative data

First-aid measures

FIRST AID MEASURES
General advice: Never give anything by mouth to an unconscious person. Victim to lie down in
the recovery position, cover and keep him warm. Give oxygen or artificial
respiration if needed. When symptoms persist or in all cases of doubt seek
medical advice.
Inhalation: Remove from exposure, lie down. Move to fresh air. Keep patient warm and at
rest. Artificial respiration and/or oxygen may be necessary. Consult a physician.
Skin contact: Take off all contaminated clothing immediately. Wash off with warm water. Get
medical attention.
Eye contact: In case of eye contact: Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes.
Get medical attention.
Ingestion: Do not induce vomiting without medical advice. Never give anything by mouth to
an unconscious person. Drink 1 or 2 glasses of water. If vomiting occurs, have
victim lean forward to reduce the risk of aspiration. Consult a physician.
Notes to physician
Treatment : Do not give adrenaline or similar drugs.

Fire-fighting measures

FIRE-FIGHTING MEASURES
Suitable extinguishing media : Water spray, Water mist, Dry chemical, Carbon dioxide (CO2),
Specific hazards during fire fighting: Fire or intense heat may cause violent rupture of packages.
Hazardous combustion products: Hydrogen fluoride Fluorinated hydrocarbons Carbonyl halides Carbon oxides
The product is not flammable.

Special protective equipment for fire-fighters: In the event of fire, wear self-contained breathing apparatus. Use personal
protective equipment. Wear neoprene gloves during cleaning up work after a
fire. Exposure to decomposition products may be a hazard to health.

Further information: Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. Evacuate personnel to safe areas. Cool containers /
tanks with water spray. Fire residues and contaminated fire extinguishing water
must be disposed of in accordance with local regulations.

Accidental release measures

Personal precautions: Evacuate personnel to safe areas. Ventilate area, especially low or enclosed
places where heavy vapours might collect. Refer to protective measures listed in
sections Handling and Storage / Exposure controls - Personal Protection

Environmental precautions: Prevent further leakage or spillage. Prevent spreading over a wide area (e.g. by
containment or oil barriers). Should not be released into the environment.

Methods for cleaning up: Contain spillage, and then collect with non-combustible absorbent material, (e.g.
sand, earth, diatomaceous earth, vermiculite) and place in container for disposal
according to local / national regulations

Handling and storage

Handling
Advice on safe handling : Avoid contact with skin, eyes and clothing. Avoid breathing vapours or mist. Provide sufficient air exchange and/or exhaust in work rooms.
Advice on protection against fire and explosion: Avoid any dust buildup with fluorocarbons and metal mixtures.

Storage
Requirements for storage areas and containers: Protect from contamination. Keep container tightly closed in a dry and wellventilated
place. Store in original container. Avoid freezing temperatures. If stored below -10°C (14°F), mix prior to use.
Advice on common storage: No materials to be especially mentioned.

Transport information

Land transport (ADR/RID)

UN number:
Not classified as dangerous in the meaning of transport regulations
Shippingopen allclose all
Class:
Not classified as dangerous in the meaning of transport regulations
Classification code:
Not classified as dangerous in the meaning of transport regulations
Packaging group:
Not classified as dangerous in the meaning of transport regulations
Labels:
Not classified as dangerous in the meaning of transport regulations
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
Not classified as dangerous in the meaning of transport regulations
Shippingopen allclose all
Class:
Not classified as dangerous in the meaning of transport regulations
Classification code:
Not classified as dangerous in the meaning of transport regulations
Packaging group:
Not classified as dangerous in the meaning of transport regulations
Labels:
Not classified as dangerous in the meaning of transport regulations
Remarksopen allclose all

Marine transport (IMDG)

UN number:
Not classified as dangerous in the meaning of transport regulations
Proper shipping name and description:
Not classified as dangerous in the meaning of transport regulations
Chemical name:
Not classified as dangerous in the meaning of transport regulations
Class:
Not classified as dangerous in the meaning of transport regulations
Packaging group:
Not classified as dangerous in the meaning of transport regulations
EmS code:
Not classified as dangerous in the meaning of transport regulations
Labels:
Not classified as dangerous in the meaning of transport regulations
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
Not classified as dangerous in the meaning of transport regulations
Proper shipping name and description:
Not classified as dangerous in the meaning of transport regulations
Chemical name:
Not classified as dangerous in the meaning of transport regulations
Class:
Not classified as dangerous in the meaning of transport regulations
Packaging group:
Not classified as dangerous in the meaning of transport regulations
Labels:
Not classified as dangerous in the meaning of transport regulations
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Engineering measures: Ensure adequate ventilation, especially in confined areas.

Personal protective equipment
Respiratory protection : For rescue and maintenance work in storage tanks use self-contained breathing
apparatus. Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.

Hand protection : Material: Hydrofluoric acid-resistant and solvent-resistant gloves (gloves made
of VITON (R)).
Glove thickness: 0,7 mm
Wearing time: 120 min
Please observe the instructions regarding permeability and breakthrough time
which are provided by the supplier of the gloves. Also take into consideration the
specific local conditions under which the product is used, such as the danger of
cuts, abrasion, and the contact time.

Eye protection: Safety glasses with side-shields Additionally wear a face shield where the
possibility exists for face contact due to splashing, spraying or airborne contact with this material.

Skin and body protection: Protective suit

Hygiene measures: Handle in accordance with good industrial hygiene and safety practice. When
using do not eat, drink or smoke. Do not breathe vapours or spray mist. Avoid
contact with skin, eyes and clothing. Wash hands before breaks and at the end
of workday.

Stability and reactivity

Conditions to avoid: The product is not flammable in air under ambient conditions of temperature and pressure. When pressurised with air or oxygen, the mixture may become flammable. Certain mixtures of HCFCs or HFCs with chlorine may become flammable or reactive under certain conditions.
Materials to avoid: Alkali metals, Alkaline earth metals, Powdered metals, Powdered metal salts,Strong bases
Hazardous decomposition products: Hazardous thermal decomposition products may include:, Carbon oxides,
Hydrogen fluoride, Carbonyl fluoride, Fluorocarbons
Hazardous reactions: No decomposition if stored and applied as directed.

Disposal considerations

Product: Can be used after re-conditioning. If recycling is not practicable, dispose of in
compliance with local regulations. The product should not be allowed to enter
drains, water courses or the soil.
Contaminated packaging: If recycling is not practicable, dispose of in compliance with local regulations.