Registration Dossier

Administrative data

First-aid measures

Inhalation:
Remove person to fresh air. If you feel unwell, get medical attention.

Skin Contact:
Wash with soap and water. If you feel unwell, get medical attention.

Eye Contact:
No need for first aid is anticipated.

If Swallowed:
Rinse mouth. If you feel unwell, get medical attention.

Most important symptoms and effects, both acute and delayed
See SDS section 11.1. Information on toxicological effects.

Indication of any immediate medical attention and special treatment required
Not applicable

Fire-fighting measures

Suitable extinguishing media
In case of fire: Use a fire fighting agent suitable for ordinary combustible material such as water or foam to extinguish.

Special hazards arising from the substance or mixture
Exposure to extreme heat can give rise to thermal decomposition.

Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
Hydrogen Fluoride During Combustion
Toxic Vapor, Gas, Particulate During Combustion

Special protective actions for fire-fighters
When fire fighting conditions are severe and total thermal decomposition of the product is possible, wear full protective clothing, including helmet, self-contained, positive pressure or pressure demand breathing apparatus, bunker coat and pants, bands around arms, waist and legs, face mask, and protective covering for exposed areas of the head.

Accidental release measures

Personal precautions, protective equipment and emergency procedures
Evacuate area. Ventilate the area with fresh air. Refer to other sections of the SDS for information regarding physical and health hazards, respiratory protection, ventilation, and personal protective equipment.

Environmental precautions
Avoid release to the environment.

Methods and material for containment and cleaning up
Collect as much of the spilled material as possible. Place in a closed container approved for transportation by appropriate authorities. Clean up residue. Seal the container. Dispose of collected material as soon as possible.

Handling and storage

Precautions for safe handling
Do not breathe thermal decomposition products. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapors/spray. Do not get in eyes, on skin, or on clothing. Do not eat, drink or smoke when using this product. Wash thoroughly after handling. Avoid release to the environment. Keep away from reactive metals (e.g. aluminium, zinc etc.) to avoid the formation of hydrogen gas that could create an explosion hazard. Use personal protective equipment (gloves, respirators, etc.) as required.

Conditions for safe storage including any incompatibilities
No special storage requirements.

Transport information

Land transport (ADR/RID)

UN number:
UN 3077
Shippingopen allclose all
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9 + env. hazardous substance Mark (Dead fish and tree)
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3077
Shippingopen allclose all
Class:
9
Classification code:
M7
Packaging group:
III
Labels:
9 + env. hazardous substance Mark (Dead fish and tree)
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3077
Proper shipping name and description:
Environmentally hazardous substance , solid , n.o.s.
Chemical name:
1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-Nonafluoro N-(2-Hydroxyethyl)-N-methyL-
Class:
9
Packaging group:
III
EmS code:
F-A ,S-F
Labels:
9 + env. hazardous substance Mark (Dead fish and tree)
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
UN 3077
Proper shipping name and description:
Environmentally hazardous substance , solid , n.o.s.
Chemical name:
1-Butanesulfonamide, 1,1,2,2,3,3,4,4,4-Nonafluoro N-(2-Hydroxyethyl)-N-methyL-
Class:
9
Packaging group:
III
Labels:
9 + env. hazardous substance Mark (Dead fish and tree)
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Control parameters

Occupational exposure limits

Ingredient 1-BUTANESULFONAMIDE, 1,1,2,2,3,3,4,4,4-NONAFLUORO-n-(2-HYDROXYETHYL)-N-METHYL-
C.A.S. No. 34454-97-2
Agency Manufacturer determined
Limit type TWA:1 mg/m3(0.07 ppm)
Additional Comments Skin Notation

ACGIH : American Conference of Governmental Industrial Hygienists
AIHA : American Industrial Hygiene Association
CMRG : Chemical Manufacturer's Recommended Guidelines
OSHA : United States Department of Labor - Occupational Safety and Health Administration
TWA: Time-Weighted-Average
STEL: Short Term Exposure Limit
CEIL: Ceiling

Exposure controls

Engineering controls
For those situations where the material might be exposed to extreme overheating due to misuse or equipment failure, use with appropriate local exhaust ventilation sufficient to maintain levels of thermal decomposition products below their exposure guidelines. Use general dilution ventilation and/or local exhaust ventilation to control airborne exposures to below relevant Exposure Limits and/or control dust/fume/gas/mist/vapors/spray. If ventilation is not adequate, use respiratory protection equipment.

Personal protective equipment (PPE)

Eye/face protection
Eye protection not required.

Skin/hand protection
Select and use gloves and/or protective clothing approved to relevant local standards to prevent skin contact based on the results of an exposure assessment. Selection should be based on use factors such as exposure levels, concentration of the substance or mixture, frequency and duration, physical challenges such as temperature extremes, and other use conditions. Consult with your glove and/or protective clothing manufacturer for selection of appropriate compatible gloves/protective clothing. Note: Nitrile gloves may be worn over polymer laminate gloves to improve dexterity.
Gloves made from the following material(s) are recommended: Polymer laminate

Respiratory protection
During heating:
Use a positive pressure supplied-air respirator if there is a potential for over exposure from an uncontrolled release, exposure levels are not known, or under any other circumstances where air-purifying respirators may not provide adequate protection.

Stability and reactivity

Reactivity
This material may be reactive with certain agents under certain conditions - see the remaining headings in this section.
Chemical stability
Stable.

Possibility of hazardous reactions
Hazardous polymerization will not occur.

Conditions to avoid
Not determined

Incompatible materials
Al or Mg powder and high/shear temperature conditions
Alkali and alkaline earth metals
Finely divided active metals
Metal powder
Reactions with metals in powder form occur from 370 degrees C onwards.
Reactive metals

Hazardous decomposition products
Substance Condition
None known.

Refer to SDS section 5.2 for hazardous decomposition products during combustion.

If the product is exposed to extreme condition of heat from misuse or equipment failure, toxic decomposition products that include hydrogen fluoride and perfluoroisobutylene can occur. Extreme heat arising from situations such as misuse or equipment failure can generate hydrogen fluoride as a decomposition product.

Disposal considerations

Disposal methods
Dispose of contents/ container in accordance with the local/regional/national/international regulations.

Dispose of waste product in a permitted industrial waste facility. As a disposal alternative, incinerate in a permitted waste incineration facility. Proper destruction may require the use of additional fuel during incineration processes. Combustion products will include halogen acid (HCl/HF/HBr). Facility must be capable of handling halogenated materials. Empty drums/barrels/containers used for transporting and handling hazardous chemicals (chemical substances/mixtures/preparations classified as Hazardous as per applicable regulations) shall be considered, stored, treated & disposed of as hazardous wastes unless otherwise defined by applicable waste regulations. Consult with the respective regulating authorities to determine the available treatment and disposal facilities.

EPA Hazardous Waste Number (RCRA): Not regulated