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Guidance on Safe Use

Guidance on Safe Use

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First-aid measures

4.1. Description of first aid measures
General advice:
First aider needs to protect himself.Take off all contaminated clothing immediately.Medical treatment is necessary if symptoms occur which are obviously caused by skin or eye contact with the product or by inhalation of its vapours.
Inhalation:
Move subject to fresh air and keep him calm. In case of complaints get medical advice.
Skin contact:
If skin irritation occurs consult a physician. Wash off immediately with soap and water.
Eye contact:
Flush eyes thoroughly with a large amount of water and consult a physician.
Ingestion:
Do not induce vomiting. Call a physician immediately.

4.2. Most important symptoms and effects, both acute and delayed
Skin irritation, Eye irritation, cough, sneezing.
sensitising effects

4.3. Indication of any immediate medical attention and special treatment needed
Treat symptomatically.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media:
foam
dry chemical
carbon dioxide
Unsuitable extinguishing media:
High volume water jet

5.2. Special hazards arising from the substance or mixture
May be released in case of fire: carbon monoxide, carbon dioxide, organic products of decomposition.

5.3. Advice for firefighters
Wear self-contained breathing apparatus.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Assure sufficient ventilation.
Use personal protective clothing.
Keep away sources of ignition.
Use breathing apparatus if exposed to vapours/dust/mist/aerosol.
Do not breathe vapours or spray mist.
Do not eat, drink or smoke when using this product.
Wash hands thoroughly with soap and water after handling.

6.2. Environmental precautions
Prevent product from getting into drains/surface water/groundwater.

6.3. Methods and material for containment and cleaning up
Larger quantities: Remove mechanically (by pumping). Use explosion-proof equipment!
Smaller quantities and/or residues:
Contain with absorbent material (e.g. sand, diatomaceous earth, acid absorbent, universal absorbent or sawdust).
Dispose of contaminated material in accordance with regulations.

6.4. Reference to other sections
For personal protection see section 8.
For disposal considerations see section 13.

Handling and storage

7.1. Precautions for safe handling
Safe handling advice:
Keep container tightly closed. Ensure there is good room ventilation.
Advice on protection against fire and explosion:
Keep away from sources of ignition --- No smoking. Take precautionary measures against static discharges. In the event of fire, cool the endangered containers with water. Vapours are heavier than air and may spread along floors. When heated above the flash point and/or during spraying (atomizing), ignitible mixtures may form in air.

7.2. Conditions for safe storage, including any incompatibilities
Requirements for storage areas and containers:
Protect from the action of light. Fill the container by approximately 90 % only as oxygen (air) is required for stabilisation. With large storage containers make sure the oxygen (air) supply is sufficient to ensure stability. Keep only in the original container at a temperature not exceeding 30 °C. Can polymerize with intense heat release.

7.3. Specific end use(s)
no

Transport information

Land transport (ADR/RID)

UN number:
UN 3082
Proper shipping name and description:
UN 3082 ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains isobornyl acrylate), 9, III, (E)
Hazard no. 90
Chemical name:
Isobornyl acrylate
Class:
9
Classification code:
(E)
Packaging group:
III
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
UN 3082
Shippingopen allclose all
Class:
9
Classification code:
(E)
Packaging group:
III
Remarksopen allclose all

Marine transport (IMDG)

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains isobornyl acrylate)
Chemical name:
isobornyl acrylate
Class:
9
Packaging group:
III
EmS code:
F-A, S-F
Marine pollutant
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3082
Proper shipping name and description:
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (contains isobornyl acrylate)
Chemical name:
isobornyl acrylate
Class:
9
Packaging group:
III
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

8.1. Control parameters
see section 8.2.

8.2. Exposure controls
For monitoring procedures refer to for instance "Empfohlene Analysenverfahren für Arbeitsplatzmessungen", Schriftenreihe der Bundesanstalt für Arbeitsschutz and "NIOSH Manual of Analytical Methods", National Institute for Occupational Safety and Health

DNEL
Critical component Routes of exposure Workers, Industry / trade Note
isobornyl acrylate dermal 1.39 mg/kg bodyweight/day Long-term - systemic effects
isobornyl acrylate inhalation 4.9 mg/m3 Long-term - systemic effects

PNEC
Critical component Routes of exposure Workers, Industry / trade Note
isobornyl acrylate Freshwater 0.00092 mg/l
isobornyl acrylate Marine water 0.000092 mg/l
isobornyl acrylate sewage treatment plant (STP) 2 mg/l
isobornyl acrylate Soil 0.0285 mg/kg dry weight
isobornyl acrylate Fresh water sediment 0.145 mg/kg dry weight
isobornyl acrylate marine water sediment 0.0145 mg/kg dry weight


Protective measures:
Do not breathe vapours. Avoid contact with eyes and skin. Do not eat, drink or smoke during use.

Hygiene measures:
Store work clothing separately. Take off all contaminated clothing immediately. Follow the usual good standards of occupational hygiene. Clean skin thoroughly after work; apply skin cream.

Respiratory protection:
Breathing apparatus in case of high concentrations, short term: filter appliance, filter A

Hand protection:
Glove material: butyl-rubber
Break through time: 480 min
Glove thickness: 0.7 mm
EN 374
The above mentioned hand protection is based on special knowledge of the chemical and the intended handling of this product, however, it still may not be suited for all workplaces. A qualified hazard assessment should be made prior to the onset of work in order to determine the suitability of gloves for specific working environments and processes.
Please observe the instructions regarding permeability and breakthrough time which are provided by the supplier of the gloves. Also take into consideration the specific local conditions under which the product is used, such as the danger of cuts, abrasion, and the contact time.
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Eye protection:
tightly fitting goggles

Skin and body protection:
On handling of larger quantities: face mask, chemical-resistant boots and apron

Stability and reactivity

10.1. Reactivity
see section 10.2.

10.2. Chemical stability
No decomposition if used as directed.

10.3. Possibility of hazardous reactions
Polymerization with heat evolution may occur in the presence of radical forming substances (e.g. peroxides), reducing substances, and/or heavy metal ions.

10.4. Conditions to avoid
Ultraviolet light.Avoid high temperatures and sources of ignition.The product is normally supplied in a stabilized form. If the permissible storage period and/or storage temperature is exceeded, the product may polymerize with heat evolution.

10.5. Incompatible materials
Peroxides, amines, sulfur compounds, heavy metal ions, alkalis, reducing agents and oxidizing agents.

10.6. Hazardous decomposition products
None when used as directed.

Disposal considerations

13.1. Waste treatment methods
Product:
Waste is hazardous. It must be disposed of in accordance with the regulations after consultation of the competent local authorities and the disposal company in a suitable and licensed facility.

Contaminated packaging:
Contaminated packaging should ideally be emptied; it can then be recycled after having been decontaminated.
Packaging that cannot be cleaned should be disposed of professionally.
Uncontaminated packaging may be taken for recycling.

Code of waste EWC:
07 02 08
waste from the manufacture, formulation, supply and use (MFSU) of plastics, synthetic rubber and man-made fibres - other still bottoms and reaction residues
Always check the given waste codes according to the actual conditions of manufacturing, formulation or use in your facilities.