Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Inhalation : Leave contaminated area immediately : breathe fresh air. If coughing, difficulty in breathing or any symptoms develop, seek medical attention at once.
Eye Contact : Remove any contact lenses at once. Immediately flush eyes with plenty of water for at least 20 to 30 minutes. Seek medical attention if necessary.
Skin Contact : Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes under the water stream. Isolate contaminated clothing to prevent contact by others. Consult a physician if necessary.
Ingestion: Seek medical attention immediately.

Fire-fighting measures

EXTINGUISHING MEDIA: Water, CO2 or Foam. Fight larger fires with water spray or alcohol resistant foam.
SPECIAL FIRE FIGHTING PROCEDURES: Wear self-contained respiratory protective device.
UNUSUAL FIRE AND EXPLOSION HAZARDS: If product is exposed to fire or intense heat, toxic fumes may be generated.


Accidental release measures

Keep waste disposal equipment as close as possible to work areas involving operations where there is potential of generation of dusts. Spills should be cleaned up promptly by authorized trained personnel.
Isolate hazard area. Wet down spill with water or wet sand and transfer to properly labeled drum for disposal by suitable waste disposal contractor.
Large area clean-up can be achieved by treating with 3-4% of sodium hypochlorite solution. Wear appropriate protective equipment for solutions being handled. Treat all used protecting equipment and collected clean-up solution as contaminated waste.
For lab scale handling, decontamination of surfaces or equipment can be achieved by treating with 3-4% of sodium hypochlorite solution. Wear appropriate protective equipment for solution being handled.
Treatment, storage, transportation and disposal must be in accordance with applicable governmental and local regulations.

Handling and storage

Handling must be carried out by authorized trained personnel only.
Store the container at prescribed place after its cover is tightened. The storage area should be kept locked.
Avoid high temperature and humidity. Do not reuse the drum.

Transport information

Land transport (ADR/RID)

UN number:
3077
Proper shipping name and description:
UN 3077. Environmentally hazardous substance, solid, N.O.S (contains 4,4'-oxydianiline)
Chemical name:
4,4'-oxydianiline
Language:
English
Class:
9
Classification code:
None
Packaging group:
III
Labels:
As above.
SpecialProvisionsopen allclose all

Inland waterway transport (ADN(R))

UN number:
3077
Proper shipping name and description:
UN 3077. Environmentally hazardous substance, solid, N.O.S (contains 4,4'-oxydianiline)
Chemical name:
4,4'-oxydianiline
Language:
English
Class:
9
Classification code:
None
Packaging group:
III
Labels:
As above.
Remarksopen allclose all

Marine transport (IMDG)

UN number:
UN 3077
Proper shipping name and description:
UN 3077. Environmentally hazardous substance, solid, N.O.S (contains 4,4'-oxydianiline)
Chemical name:
4,4'-oxydianiline
Class:
9
Packaging group:
III
EmS code:
None
Labels:
As above
Marine pollutant
Remarks
Based on analogy to freshwater data, the substance can be considered as a potential marine pollutant.

Air transport ICAO/IATA

UN number:
UN 3077
Proper shipping name and description:
UN 3077. Environmentally hazardous substance, solid, N.O.S (contains 4,4'-oxydianiline)
Chemical name:
4,4'-oxydianiline
Class:
9
Packaging group:
III
Labels:
As above.
Remarksopen allclose all
SpecialProvisionsopen allclose all

Exposure controls / personal protection

Exposure controls / personal protection

- General protective and hygenic measures:
Wash hands before breaks and at the end of work.
Keep away from tobacco products.
Avoid close or long term contact with the skin.

- Personal Protective Equipment:
- Respiratory protection:
Use suitable respiratory protective device in case of insufficient ventilation.
- Protection of hands:
The glove material has to be impermeable and resistant to the substance and preparation.
Gloves should be made of synthetic rubber as a minimum standard of protection.

- Eye protection:
Goggles with side splash protection or safety glasses are recommended to be worn during refilling, to provide a minimum standard of protection.

- Body protection:
Full body impervious protective clothing should be worn as a minimum standard of protection.

Stability and reactivity

Substance is stable and not harmfully reactive under the conditions of use specified in this dossier.

Disposal considerations

Do not allow product to enter the sewerage system or aquatic environment.
Dispose of wastes and packaging containing the substance to a licensed waste disposal site/agent for disposal in accordance with local, regional and national regulations.