Registration Dossier

Administrative data

First-aid measures

General instructions
If health problems occur or if you suspect that your health may have been affected, contact your physician and give the information stated on this safety data sheet. It is necessary to keep the vital functions going until a physician arrives (i.e. check heartbeat, ensure artificial respiration, heart massage). If the affected person has lost consciousness or if you believe that he/she may lose consciousness, transport the person to a healthcare provider in a stabilised position, lying on his/her side.

When inhaled
Move the victim to fresh air, keep him or her in absolute repose, inhalation of oxygen. Half sitting position, prevent person from losing heat. Transport to doctor.
SYMPTOMS AND EFFECTS: headache, giddiness, nausea, airway eyes irritation

In case of contact with skin
Wash the affected area thoroughly with water and soap for 10-15 minutes.
SYMPTOMS AND EFFECTS: possible irritation, dermatitis, burn, itching, oedema

In case of contact with eyes
Wash the eye with a plenty of water or physiological solution for 10-15 minutes from inner to outer eyecorner.
If the afflicted person is wearing contact lenses, they must be removed immediately. Call for a professional medical help promptly.
SYMPTOMS AND EFFECTS: irritation, lacrimation, burn , pain, photophobia.

When swallowed
Have the victim drink approx. 2 dl of water and call for a professional medical help promptly. After ingestion possible administrate activated charcoal as a slurry (20 tablets (cca 15g) /250 ml water). Do not induce vomiting.
SYMPTOMS AND EFFECTS: irritation, burning of oesophageal or gastrointestinal tract

Fire-fighting measures

Suitable extinguishing media
Powder or snow fire extinguisher. In the case of a large-scale fire, use heavy foam with a polar foam maker, or a split water stream. Containers should be cooled with a screen of water. You should try to get them out of the fire.

Extinguishing media which shall not be used for safety reasons
Direct water stream

Special exposure hazards from the substance or preparation itself, combustion products, resulting gases
While the substance burns, it produces toxic products. Mixtures of the steam of the substance with the air are explosive.

Special protective equipment for fire-fighters
When fighting the fire in the dangerous zone, you must use an isolation breathing apparatus and a protective suit against heat of radiation.

Further data:
Temperature class: T1
Explosive group: IIA

Accidental release measures

Personal precautions
Close the place of the accident. When managing the emergency, use the personal emergency equipment described in Section 8. Remove or switch off all sources of ignition. Avoid generation of dust. Ensure supply of fresh air in enclosed room.

Environmental precautions
Prevent the substance from leaking into the sewerage system, ground and surface water or into the soil.

Method for cleaning
Collect spilled substance and incinerate everything including contaminated soil at the appropriate facility.
The contaminated material must be handled as a waste.

Handling and storage

Handling
Avoid formation of dust or possible vapours (sublimate when processing) at workplace and atmosphere – ensure sufficient ventilation and exhaustion. Use personal protective equipment according to Personal Protection Section. Avoid leakage or spillage of the product during handling operations. Avoid contact with open fire, sparks or hot surfaces.

Storage
Store under common storage conditions. Ensure sufficient ventilation. Store only in enclosed packages.
Store in dry area. Avoid exposure to weather conditions. Use protective equipment according to Personal Protection Section.

Specific use
Not determined.

This substance is handled under strictly controlled conditions in accordance with REACH regulation article 18(4) for transported isolated intermediates. Site documentation to support safe handling arrangments include the selection of engineering, administrative and personal protective equipment controls in accordance with risk-based managment systems is available at each manufacturing site.

Written confirmation of application of strictly controlled conditions has been recieved from every affected distributor or manufacturer/ downstream user of the registrant's intermediate.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

Occupational exposure controls

Collective protection measures
Plant-wide and local ventilation, effective exhaust system, automation, hermetic sealing.

Individual protection measures
The staff must wear personal protection equipment (PPE) to protect their eyes, hands and skin. This equipment must be suitable for the nature of the activities they do. Wherever the technical means do not enable obeying the exposure limits determined for the working environment or ensuring that inhaling the substance does not affect a persons’ health, the staff must use also suitable protection of the respiratory system. If the staff are to use this equipment permanently while working, it is necessary to include safety breaks, if required by the nature of the PPE. All the PPE must be kept in good condition. Any polluted or damaged equipment must be replaced immediately.

RECOMMENDED PERSONAL PROTECTION EQUIPMENT (PPE):
· Respiratory protection: In case of short-time exposure or low concentration use the respirator with filter protecting from organic vapours, in case of high concentrations and long-term exposure use selfcontained breathing apparatus.
· Eye protection: Protective shield or goggles
· Hand protection: Protective gloves: Everyday working activities (possible contact during operation or getting stained in the case of leakage - Glove material: Nitrile; Layer thickness: 0.85 mm; Penetration time: 480min.
· Skin protection: protective suit and footwear, unprotected skin must be treated with a protective lotion before beginning to work.
· General safety and hygienic measures: Follow the rules of personal hygiene. Do not eat, drink or smoke while working! Wash your hands as well as any uncovered parts of your body well with water and soap, or treat them with suitable reparation lotion after finishing work or before eating or drinking.

Environmental exposure controls
Follow the valid legal regulations governing the protection of the air and water.

Stability and reactivity

Conditions under which the product is stable
Conventional physical and chemical conditions

Conditions to avoid
High temperature, formation of explosive mixtures of substance vapours with air. Contact with open flame, hot surfaces, and sparks.

Material to avoid
Strong oxidising agents. strong acids.

Hazardous decomposition products
Toxic vapour generation in case of a fire.

Disposal considerations

Methods of substance disposal
The substance must be handled in compliance with the valid legal regulations governing the disposal of waste as well as with other environmental regulations. Leaked product must be handled in the manner described in Accidental Release Measures Section and then handed over to a person authorised to handle hazardous waste. It is recommended to dispose of this substance by making it a material that can be further used for energy
generation purposes. Contact the producer for any additional information.
Recommended classification of the waste under Decree No. 381/2001 Coll.: 07 01 99*, 07 01 99*, 16 05 08*

Methods of contaminated packaging disposal
Proceed in the same manner as when disposing of the product.
Recommended classification of the packaging waste under Decree No. 381/2001 Coll.: 15 01 10*

Legal regulations governing the disposal and handling of waste
The Czech Republic
Act No. 185/2001 Coll. on waste modifying certain other acts, in the valid wording including delegated legislative (e.g. Decree No. 381/2001 Coll. determining the Catalogue of Waste)

The European Union
EP and Council Directive 2006/12/ES on waste
Council Directive 1991/689/EHS on dangerous waste