Registration Dossier

Data platform availability banner - registered substances factsheets

Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Administrative data

Endpoint:
auto-ignition temperature (liquids)
Type of information:
experimental study
Adequacy of study:
key study
Study period:
11 January to 04 February 2016
Reliability:
1 (reliable without restriction)
Rationale for reliability incl. deficiencies:
guideline study

Data source

Reference
Reference Type:
study report
Title:
Unnamed
Year:
2016
Report date:
2016

Materials and methods

Test guidelineopen allclose all
Qualifier:
according to guideline
Guideline:
DIN 51794 (Testing of mineral oil hydrocarbons - Determination of ignition temperature)
Qualifier:
according to guideline
Guideline:
EU Method A.15 (Auto-Ignition Temperature (Liquids and Gases))
GLP compliance:
no

Test material

Constituent 1
Chemical structure
Reference substance name:
Ethyl 2,6,6-trimethyl-4-oxocyclohex-2-ene-1-carboxylate
EC Number:
245-410-2
EC Name:
Ethyl 2,6,6-trimethyl-4-oxocyclohex-2-ene-1-carboxylate
Cas Number:
23068-96-4
Molecular formula:
C12H18O3
IUPAC Name:
ethyl 2,6,6-trimethyl-4-oxocyclohex-2-ene-1-carboxylate
Specific details on test material used for the study:
Name (as stated in the report): Carbethoxy Isophorone
Batch: SC00015362
Appearance: Yellow liquid
Expiration date: August 14, 2017

Results and discussion

Auto-ignition temperature (liquids / gases)
Key result
Auto-ignition temperature:
425 °C
Atm. press.:
1 013 hPa

Applicant's summary and conclusion

Conclusions:
The lowest temperature giving a positive effect was 429°C. The injected volume was 100 microL, the ignition delay was 2s. At a temperature of 424°C no ignition was observed.
Therefore, after rounding off the next lower multiple of 5.0°C is 245+/- 10°C. Auto-ignition of CARBETHOXY ISOPHORONE: 245+/- 10°C.
Executive summary:

The Auto ignition temperature of CARBETHOXY ISOPHORONE was determined in a SUR BERLIN oven, equipped with a 250 mL glass ignition vessels according to the DIN 51794. The lowest temperature giving a positive effect was 429°C. The injected volume was 100 microL, the ignition delay was 2s. At a temperature of 424°C no ignition was observed. Therefore, after rounding off the next lower multiple of 5.0°C is 245+/- 10°C.

Auto-ignition of CARBETHOXY ISOPHORONE: 245+/- 10°C.