Registration Dossier

Administrative data

First-aid measures

*4. First aid measures
4.1 General information:
Remove contaminated clothing.
4.2 Inhalation:
Fresh air.
4.3 Skin contact:
Immediately wash thoroughly with soap and water, subsequently apply hand cream.
If skin irritation persists, seek medical attention.
4.4 Eye contact:
Immediately flush with flowing water for at least 10 minutes, holding the eyelid open.
If eye irritation persists, seek eye specialist advice.
4.5 Swallowing:
Flush mouth with water. Do not induce vomiting, seek medical advice.
4.6 Self-protection of first-aider:
Avoid contact with the product.
4.7 Advice to physician (symptoms, risks, treatment): Symptomatic treatment.

Fire-fighting measures

*5. Fire-fighting measures
5.1 Extinguishing media:
Water spray jet, foam, CO2, extinguishing powder.
5.2 Extinguishing media that must not be used for safety reasons: Full water jet
5.3 Special hazards arising from the substance or mixture, its combustion products or generated
gases:
The following substances may be released in case of fire: Carbon monoxide, carbon dioxide, organic
decomposition products and nitrogen oxides.
Traces of other toxic products cannot be excluded under certain fire conditions.
5.4 Advice for fire-fighters
Keep available/wear respiratory protective devices.
5.5 Additional information: none

Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures:
Provide adequate ventilation. Remove uninvolved persons.
Avoid contact with skin, eyes and clothing.
Wear personal protection equipment; see Chapter 8.
6.2 Environmental precautions:
Keep away from sewerage systems, waterways and soil.
6.3 Methods and material for containment and cleaning up:
Take up spilled product mechanically, avoid dust formation.
Store in marked, tightly closed containers.
Dispose in compliance with regulations.
6.4 Additional information: none

Handling and storage

7. Handling and storage
7.1 Handling:
7.1.1 Precautions for safe handling:
Wear personal protection equipment (see Chapter 8).
Provide adequate ventilation or air extraction.
Prevent dust formation and inhalation.
Avoid contact with skin, eyes and clothing.
Do not eat, drink and smoke during work. Wash hands after work.
Keep away from sources of ignition and heat.
Protective measures:
Technical measures:
Observe normal safety precautions associated with the handling of chemicals.
Avoid eye and skin contact.
Provide adequate ventilation or air extraction.
Specific requirements or handling precautions:
7.1.2 Fire and explosion protection information:
Adopt typical preventive fire protection measures.
7.1.3 Further information:
none
7.2 Storage:
7.2.1 Technical measures and storage conditions:
Store in tightly sealed containers.
7.2.5 Further information relating to storage conditions:
Store in tightly sealed original containers in a dry, cool and well ventilated place, avoid exposure to sunlight
and moisture.
Avoid contact with acids and bases.
Keep away from foods, beverages and feeds.
Keep out of reach of children.
Storage class (VCI): 11 - Flammable solid
7.3 Specified end use: see Chapter 1.

Transport information

Land transport (ADR/RID)

UN number:
3077
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Class:
9 / 9.1
Classification code:
ADR / RID / IMDG-Code / ICAO-TI / IATA-DGR
Packaging group:
III
Labels:
Labelling of environmentally hazardous substances
ADR/ RID / IMDG-Code: 9.1
ICAO-TI / IATA-DGR: 9.1
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Marine transport (IMDG)

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Exposure controls / personal protection

8. Exposure controls/personal protection (continued)
Personal protection equipment:
Respiratory protection:
Respiratory protection usually not required. In case of insufficient ventilation, heating of product or
occurrence of aerosols, mists and smokes, use self-contained breathing apparatus or breathing ,
apparatus with particle filter P 3 according to EN 141.
Hand protection:
Glove material: Nitrile rubber (Dermatril)
Material thickness 0.1 mm; Penetration time > 480 min
Eye protection:
Protective goggles
Body protection:
Protective clothing.
Remove soiled or soaked clothing immediately.
8.2.2 Control and monitoring of environmental exposure:
Avoid release to the environment.
Technical measures to avoid exposure:
Provide adequate ventilation.
8.2.3 Control and monitoring of user exposure
Measures related to use of the substance (as such or in preparations) by user:
Avoid eye and skin contact. Customary safety precautions associated with the handling of chemicals
should be observed.

Stability and reactivity

10. Stability and reactivity
10.1 Reactivity
Stable under normal conditions.
10.2 Chemical stability
Stable under supplier-specified storage conditions.
10.3 Possibility of hazardous reactions
No hazardous reactions when properly stored and handled.
Dust can combine with air to form an explosive mixture.
10.4 Conditions to avoid
Decomposition starts at ca. 185°C.
10.5 Incompatible materials
Store only in original containers.
10.6 Hazardous decomposition products
Decomposition products after fire, chemical or thermal decomposition:
Carbon monoxide, carbon dioxide, nitrogen oxides.

Disposal considerations

13. Disposal considerations
13.1 Disposal / waste (product):
- Product: Disposal, e.g., to incineration plant under consideration of local authority regulations.
13.2 EAK/AVV waste code:
Waste disposal index No. EU:
020105 Wastes from chemicals for agriculture
070499 Waste n.o.s. from production, preparation, sale and application of organic plant
protective agents, wood protective agent and other biocides
The waste disposal index numbers are recommendations. Other numbers may also be assigned due
to other specific product applications.
13.3. Packaging:
Used packaging shall be optimally emptied and disposed of in the same manner as the product.