Registration Dossier

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Please be aware that this old REACH registration data factsheet is no longer maintained; it remains frozen as of 19th May 2023.

The new ECHA CHEM database has been released by ECHA, and it now contains all REACH registration data. There are more details on the transition of ECHA's published data to ECHA CHEM here.

Diss Factsheets

Environmental fate & pathways

Endpoint summary

Administrative data

Description of key information

Additional information

Hexachlorodisilane hydrolyses very rapidly to give hexahydroxydisilane and HCl. Further hydrolysis of the Si-Si bonds in hexahydroxydisilane is expected to happen rapidly and produces monosilicic acid.

Monosilicic acid exists only in dilute aqueous solutions and readily condenses at concentrations above approximately 100 -150 mg/l as SiO2 to give a dynamic equilibrium between monomer, oligomers and insoluble amorphous polysilicic acid.

Hexahydroxydisilane is also likely to form condensation products (polyhydroxy-polysilanes).

These hydrolysis products are inorganic substances which are ubiquitous in the environment and are expected to

enter natural biogeochemical cycles.

A comparison of the total flux of dissolved silica into rivers can be compared with the input from manufacture and use of hexachlorodisilane (refer to Section 9), and indicates that the input is considered negligible in comparison with the natural flux of silica/silicic acid in the environment.

Therefore, it is not appropriate to calculate Predicted Environmental Concentrations (PECs) for the ultimate silanol hydrolysis product, monosilicic acid.