Registration Dossier

Administrative data

First-aid measures

4.1. Description of first aid measures
First aid personnel should pay attention to their own safety. If the patient is likely to become unconscious, place and transport in stable sideways position (recovery position). Immediately remove contaminated clothing.

If inhaled:
Keep patient calm, remove to fresh air, seek medical attention. Immediately administer a corticosteroid from a controlled/metered dose inhaler.

On skin contact:
Immediately wash thoroughly with plenty of water, apply sterile dressings, consult a skin specialist.

On contact with eyes:
Immediately wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist.

On ingestion:
Immediately rinse mouth and then drink 200-300 ml of water, seek medical attention.


4.2. Most important symptoms and effects, both acute and delayed
Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and/or in section 11., Further symptoms are possible


4.3. Indication of any immediate medical attention and special treatment needed
Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote.

Fire-fighting measures

5.1. Extinguishing media
Suitable extinguishing media:
water spray, dry powder, foam, carbon dioxide

5.2. Special hazards arising from the substance or mixture
nitrogen oxides, carbon oxides
The substances/groups of substances mentioned can be released in case of fire. Under certain conditions in case of fire other hazardous combustion products may be generated.

5.3. Advice for fire-fighters
Special protective equipment:
Wear self-contained breathing apparatus and chemical-protective clothing.

Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.

Accidental release measures

6.1. Personal precautions, protective equipment and emergency procedures
Breathing protection required. Avoid contact with the skin, eyes and clothing.

6.2. Environmental precautions
Do not empty into drains.

6.3. Methods and material for containment and cleaning up
For large amounts: Pump off product. Rinse with plenty of water.
For residues: Pick up with suitable absorbent material (e.g. sand, sawdust, general-purpose binder, kieselguhr). Dispose of absorbed material in accordance with regulations.
Cleaning operations should be carried out only while wearing breathing apparatus. Collect waste in suitable containers, which can be labeled and sealed. Clean contaminated floors and objects thoroughly with water and detergents, observing environmental regulations. Incinerate or take to a special waste disposal site in accordance with local authority regulations.

6.4. Reference to other sections
Information regarding exposure controls/personal protection and disposal considerations can be found in section 8 and 13.

Handling and storage

7.1. Precautions for safe handling
Ensure thorough ventilation of stores and work areas. When using do not eat, drink or smoke. Hands and/or face should be washed before breaks and at the end of the shift.

Protection against fire and explosion:
Take precautionary measures against static discharges. Keep away from sources of ignition - No smoking.

7.2. Conditions for safe storage, including any incompatibilities
Segregate from alkalies and alkalizing substances.
Further information on storage conditions: Keep container tightly closed in a cool, well-ventilated place.

7.3. Specific end use(s)
For the relevant identified use(s) listed in Section 1 the advice mentioned in this section 7 is to be observed.

Transport information

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Marine transport (IMDG)

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Exposure controls / personal protection

8.1. Control parameters

Components with occupational exposure limits


107-13-1: acrylonitrile
124-40-3: di-methylamine
TWA value 3.8 mg/m3 ; 2 ppm (OEL (EU))
indicative
STEL value 9.4 mg/m3 ; 5 ppm (OEL (EU))
indicative
1738-25-6: 3-Dimethylaminopropiononitrile
124-40-3: di-methylamine...%
TWA value 3.8 mg/m3 ; 2 ppm (OEL (EU))
indicative
STEL value 9.4 mg/m3 ; 5 ppm (OEL (EU))
indicative

PNEC
freshwater: 0.5 mg/l

marine water: 0.05 mg/l

intermittent release: 5 mg/l

STP: 3432 mg/l

sediment (freshwater): 1.54 mg/kg

soil: 0.251 mg/kg


8.2. Exposure controls
Personal protective equipment
Respiratory protection:
Respiratory protection in case of vapour/aerosol release. Gas filter for gases/vapours of organic compounds (boiling point >65 °C, e. g. EN 14387 Type A)

Hand protection:
Chemical resistant protective gloves (EN 374)
Suitable materials also with prolonged, direct contact (Recommended: Protective index 6, corresponding > 480 minutes of permeation time according to EN 374):
butyl rubber (butyl) - 0.7 mm coating thickness
Manufacturer's directions for use should be observed because of great diversity of types.

Supplementary note: The specifications are based on tests, literature data and information of glove manufacturers or are derived from similar substances by analogy. Due to many conditions (e.g. temperature) it must be considered, that the practical usage of a chemical-protective glove in practice may be much shorter than the permeation time determined through testing.

Eye protection:
Tightly fitting safety goggles (splash goggles) (e.g. EN 166)

Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. apron, protecting boots, chemical-protection suit (according to EN 14605 in case of splashes or EN ISO 13982 in case of dust).

General safety and hygiene measures
Avoid contact with the skin, eyes and clothing. Do not breathe vapour/spray. Wearing of closed work clothing is required additionally to the stated personal protection equipment. Take off immediately all contaminated clothing. Store work clothing separately.

Stability and reactivity

10.1. Reactivity
Formation of flammable gases: Remarks: Forms no flammable gases in the presence of water.


10.2. Chemical stability
The product is chemically stable.

10.3. Possibility of hazardous reactions
No hazardous reactions if stored and handled as prescribed/indicated.


10.4. Conditions to avoid
Avoid all sources of ignition: heat, sparks, open flame. Avoid extreme heat. See MSDS section 7 - Handling and storage.

10.5. Incompatible materials

Substances to avoid:
nitrosating agents

10.6. Hazardous decomposition products

Possible thermal decomposition products:
carbon oxides, nitrogen oxides

Disposal considerations

13.1. Waste treatment methods

Incinerate in suitable incineration plant, observing local authority regulations.

A waste code in accordance with the European waste catalog (EWC) cannot be specified, due to dependence on the usage.
The waste code in accordance with the European waste catalog (EWC) must be specified in cooperation with disposal agency/manufacturer/authorities.


Contaminated packaging:
Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned.