Registration Dossier

Guidance on Safe Use

Guidance on Safe Use

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Administrative data

First-aid measures

Inhalation:
If breathed in, move person into fresh air. Oxygen or artificial respiration if needed. Consult a physician after significant exposure.

Skin Contact:
Take off contaminated clothing and shoes immediately. Wash off immediately with plenty of water for at least 15 minutes. Obtain medical attention.

Eye Contact:
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses. Obtain medical attention.

Ingestion:
Rinse mouth, ingest activated charcoal. Drink 1 or 2 glasses of water. Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Obtain medical attention.

Fire-fighting measures

Flammable properties:
Flash point:
125 °C. Method: Tested according to Directive 92/69/EEC.

Protective equipment and precautions for firefighters:
Suitable extinguishing media:
Water mist
Dry powder
Carbon Dioxide (CO2)
Foam

Hazardous decomposition products:
Tin oxide fumes.
Gaseous hydrogen chloride (HCI)
Carbon oxides

Thermal decomposition:
>210 °C

Further information:
Use water spray to cool unopened containers.
Collect contaminated fire extinguishing water separately. This must not be discharged into drains.

Special protective equipment for fire-fighters:
Wear self contained breathing apparatus for fire fighting if necessary.

Accidental release measures

Personal precautions:
Evacuate personnel to safe areas.
Wear suitable protective equipment.

Environmental precautions:
Retain and dispose of contaminated wash water.

Methods for containment/Methods for cleaning up:
Contain spillage, soak up with non-combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local / national regulations.

Handling and storage

Advice on safe handling:
Avoid contact with skin and eyes.
Avoid inhalation of vapour or mist.

Requirements for storage areas and containers:
Keep containers tightly closed in a dry, cool and well-ventilated place.

Transport information

Land transport (ADR/RID)

UN number:
3265
Proper shipping name and description:
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Chemical name:
Monobutyltin Trichloride
Language:
English
Class:
8
Classification code:
II
Packaging group:
C3
Labels:
8
Remarks:
Hazard identification number: 80

Inland waterway transport (ADN(R))

UN number:
3265
Proper shipping name and description:
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Chemical name:
Monobutyltin Trichloride
Language:
English
Class:
8
Classification code:
II
Packaging group:
C3
Labels:
8
Remarks
Hazard identification number: 80

Marine transport (IMDG)

UN number:
3265
Proper shipping name and description:
CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Chemical name:
Monobutyltin Trichloride
Class:
8
Packaging group:
II
EmS code:
EmS Number 1: F-A
EmS Number 2: S-B
Labels:
8
Remarksopen allclose all

Air transport ICAO/IATA

UN number:
3265
Proper shipping name and description:
Corrosive liquid, acidic, organic, n.o.s.
Chemical name:
Monobutyltin Trichloride
Class:
8
Packaging group:
II
Labels:
8
Remarks
Packing instruction (cargo aircraft) : 812

Packing instruction (passenger aircraft) : 808

Packing instruction (passenger aircraft) : Y808
SpecialProvisionsopen allclose all

Exposure controls / personal protection

- Exposure limits:
1118-46-3, n-butyltin trichloride
TWA ; GB EH40, 2005-04-06
0.1 mg/m3
Sk: Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. As Sn

1118-46-3, n-butyltin trichloride
STEL ; GB EI-140, 2005-04-06
0.2 mg/m3
Sk: Can be absorbed through skin. The assigned substances are those for which there are concerns that dermal absorption will lead to systemic toxicity. As Sn

- Personal protective equipment:
Eye protection:
Safety glasses with side-shields

Hand Protection:
Impervious gloves
Rubber or plastic gloves
The selected protective gloves have to satisfy the specifications of Eli Directive 89/686/EEC and the standard EN 374 derived from it.
Gloves should be discarded and replaced if there is any indication of degradation or chemical breakthrough.

Skin and body protection:
Impervious clothing

Respiratory protection:
Respirator with a vapour filter (EN 141)

Hygiene measures:
Handle in accordance with good industrial hygiene and safety practice.
Ensure adequate ventilation, especially in confined areas.

Stability and reactivity

Conditions to avoid:
Extremes of temperature and direct sunlight
Exposure to moisture.

Materials to avoid:
Strong acids and strong bases
Strong oxidising agents

Hazardous decomposition products:
Tin oxide fumes
Gaseous hydrogen chloride (HCI)
Carbon oxides

Thermal decomposition:
>210 ºC

Note:
Stable under normal conditions

Disposal considerations

Dispose of in accordance with the European Directives on waste and hazardous waste. Send to a licensed waste management company.